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A kind of preparation method of p92 steel with al-ca composite hinge wire refining inclusions

An inclusion, al-ca technology, applied in the field of iron and steel materials, can solve the problems of CaO nano-grain refinement and inclusion, and achieve the effect of shortening the steelmaking process and reducing the cost.

Active Publication Date: 2021-11-05
UNIV OF SCI & TECH BEIJING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, Al-Ca composite hinge wire is added during the smelting process, and Al is directly generated in the melt. 2 o 3 The method of refining inclusions of CaO nanocrystals is rarely reported

Method used

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  • A kind of preparation method of p92 steel with al-ca composite hinge wire refining inclusions
  • A kind of preparation method of p92 steel with al-ca composite hinge wire refining inclusions
  • A kind of preparation method of p92 steel with al-ca composite hinge wire refining inclusions

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] (1) The chemical composition (mass percentage) of the alloy is: 0.11wt.% C, 0.4wt.% Mn, 0.2wt.% Si, 0.12wt.% P, 0.01wt.% S, 8.68wt.% Cr, 0.29wt .% Ni, 0.46wt.% Mo, 0.18wt.% V, 1.67wt.% W, 0.01wt.% Ti, 0.001wt.% B, 0.007wt.% Al, 0.001wt.% Ca, 0.03wt.% N, 0.003wt.% (equivalent to 30ppm) O, balance Fe;

[0051] (2) Use the electric furnace to carry out vacuum smelting heating method to heat and melt the alloy into molten steel. After the molten steel is completely melted, carry out alloying operation, and then overheat the temperature to 55°C until the molten steel surface is stable;

[0052] (3) if figure 2 As shown, after the refining operation of the LF furnace, the wire feeding machine is used to feed 10 wires such as figure 1 The φ0.7mm Al-Ca composite hinge wire shown;

[0053] (4) While feeding the wire, the bottom blowing inert gas forms a flow field in the melt;

[0054] (5) Measure the oxygen concentration after the wire feeding is completed, and perform VD ...

Embodiment 2

[0063] (1) The chemical composition (mass percentage) of the alloy is: 0.11wt.% C, 0.4wt.% Mn, 0.2wt.% Si, 0.12wt.% P, 0.01wt.% S, 8.68wt.% Cr, 0.29wt .% Ni, 0.46wt.% Mo, 0.18wt.% V, 1.67wt.% W, 0.01wt.% Ti, 0.001wt.% B, 0.007wt.% Al, 0.001wt.% Ca, 0.03wt.% N, 0.003wt.% (equivalent to 30ppm) O, balance Fe.

[0064] (2) Use the electric furnace to carry out vacuum smelting heating method to heat and melt the alloy into molten steel. After the molten steel is completely melted, carry out alloying operation, and then overheat the temperature to 80°C until the liquid steel surface is stable;

[0065] (3) if figure 2 As shown, after the refining operation of the LF furnace, the wire feeding machine is used to feed 12 wires such as figure 1 The φ1.5mm Al-Ca composite hinge wire shown;

[0066] (4) While feeding the wire, the bottom blowing inert gas forms a flow field in the melt;

[0067] (5) Measure the oxygen concentration after the wire feeding is completed, and perform VD ...

Embodiment 3

[0074] (1) The chemical composition (mass percentage) of the alloy is: 0.11wt.% C, 0.4wt.% Mn, 0.2wt.% Si, 0.12wt.% P, 0.01wt.% S, 8.68wt.% Cr, 0.29wt .% Ni, 0.46wt.% Mo, 0.18wt.% V, 1.67wt.% W, 0.01wt.% Ti, 0.001wt.% B, 0.007wt.% Al, 0.001wt.% Ca, 0.03wt.% N, 0.003wt.% (equivalent to 30 ppm) O, balance Fe.

[0075] (2) Use the electric furnace to carry out vacuum smelting heating method to heat and melt the alloy into molten steel. After the molten steel is completely melted, carry out alloying operation, and then overheat the temperature to 95°C until the molten steel surface is stable;

[0076] (3) if figure 2 As shown, after the refining operation of the LF furnace, the wire feeding machine is used to feed 15 wires such as figure 1 The φ2.7mm Al-Ca composite hinge wire shown;

[0077] (4) While feeding the wire, the bottom blowing inert gas forms a flow field in the melt;

[0078] (5) Measure the oxygen concentration after the wire feeding is completed, and perform VD...

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Abstract

The invention discloses a method for preparing P92 steel with Al-Ca composite hinge wire with fine inclusions, and belongs to the technical field of iron and steel materials. The method includes feeding Al-(1.5-30)wt.%Ca composite hinge wire in molten steel with an oxygen concentration of 5-100ppm by wire feeding and stirring, and blowing inert gas at the bottom A flow field is formed in the melt to obtain molten steel containing O, Al, and Ca, and then poured at a cooling rate of not less than 500K / min, and finally P92 with an inclusion grade of A+B+C+D+DS≤1.5 is obtained steel. The invention is suitable for preparing P92 steel.

Description

technical field [0001] The invention belongs to the technical field of iron and steel materials, and relates to a preparation method of P92 steel with Al-Ca composite hinge wire fine inclusions. Background technique [0002] P92 steel is a new type of steel improved and developed on the basis of T / P91 steel. It is a new type of ferritic heat-resistant alloy steel. P92 steel is widely used in superheater and reheater tubes of high-pressure boilers and thermal power stations because of its good thermal strength, welding performance and process performance, insensitivity to stress corrosion cracking and low production cost. on the main steam line. The main advantage of P92 steel is that it can further reduce the quality of power plant boilers and piping systems under the same working temperature, pressure or design life conditions. Under the same structural size, the design working temperature of the structure can be further increased, thereby improving the thermal efficiency...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21C7/00C21C7/072
CPCC21C7/0056C21C7/0006C21C7/072
Inventor 陈晓华于惠雯王自东赵思远王艳林陈凯旋
Owner UNIV OF SCI & TECH BEIJING