Calixarene-rhodamine supramolecular co-assembly as well as preparation method and application thereof
A co-assembly, supramolecular technology, applied in chemical instruments and methods, analytical materials, measurement devices, etc., can solve problems such as nucleic acid and protein hazards
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Embodiment 1
[0044] Embodiment 1: Preparation of calixarene-rhodamine co-assembly:
[0045] a. Mix rhodamine (50mg, 0.104mmol) and 4-sulfonylcalix[4]arene hydrate (225mg, 0.302mmol) into hydrochloric acid solution (6mol / L, 15mL), stir to dissolve, and obtain solution A ;
[0046] b. Transfer solution A to a stainless steel autoclave lined with 25mL polytetrafluoroethylene, keep the temperature at 100°C for 1 hour, then cool it to room temperature, transfer it to a beaker, and let it stand at room temperature for 2 days , to obtain crystal B;
[0047] c. Use the Bruker D8 VENTURE single crystal diffractometer to test the structure of crystal B to determine its molecular configuration and molecular formula. The molecular configuration is a solid triangle structure and the molecular formula is C 112 h 103 o 51 N 2 S 12 Cl, with a molecular weight of 2713.17;
[0048] d. Determination of crystal B 1 H NMR spectrum, to further determine the ratio of calixarene-rhodamine co-assembly, the...
Embodiment 2
[0050] Embodiment 2: Preparation of calixarene-rhodamine co-assembly:
[0051] 1) Rhodamine and 4-sulfonylcalix[4]arene hydrate are mixed in a ratio of less than 1:5 in the amount of substances and added to a hydrochloric acid solution with a concentration of 6mol / L, stirred to dissolve, and solution A is obtained;
[0052] 2) Add solution A into the autoclave, keep the temperature at 95°C for 1.5h, then cool it down to room temperature, let it stand for 1d to crystallize, and obtain crystal B;
[0053] 3) The crystal B described in step 2) is filtered out, and the crystal B is the calixarene-rhodamine supramolecular co-assembly.
Embodiment 3
[0054] Embodiment 3: the preparation of calixarene-rhodamine co-assembly:
[0055] 1) Rhodamine and 4-sulfonylcalix[4]arene hydrate are mixed in a ratio of less than 1:7 in terms of the amount of substances and added to a hydrochloric acid solution with a concentration of 6mol / L, stirred to dissolve, and solution A is obtained;
[0056] 2) Add solution A into the autoclave, keep the temperature at 105°C for 0.5h, then cool it down to room temperature, and let it stand for 3d to crystallize to obtain crystal B;
[0057] 3) The crystal B described in step 2) is filtered out, and the crystal B is the calixarene-rhodamine supramolecular co-assembly.
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