Preparation method of reinforced Pebax mixed matrix membrane

A technology of mixed matrix membrane and casting solution, applied in the field of membrane separation, can solve the problem that the ideal selectivity is not very high

Active Publication Date: 2021-10-26
DALIAN UNIV OF TECH PANJIN INST OF IND TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, even with mixed matrix membranes prepared from modified MOFs, CO 2 /N 2 Therefore, the preparation of MOF mixed

Method used

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  • Preparation method of reinforced Pebax mixed matrix membrane
  • Preparation method of reinforced Pebax mixed matrix membrane
  • Preparation method of reinforced Pebax mixed matrix membrane

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] In a closed autoclave, blow nitrogen; add 10g diallylamine hydrochloride, 6g 3-amino-4-mercaptoquinoline (CAS: 109543-48-8), 100g ethanol, add 3g sodium methoxide , heated and stirred to 55°C, reacted for 2 hours, evaporated to remove ethanol, and obtained synergist 1.

preparation Embodiment 2

[0043] In a closed autoclave, blow nitrogen; add 14g diallylamine hydrochloride, 8g 3-amino-4-mercaptoquinoline (CAS: 109543-48-8), 120g ethanol, add 5g sodium methoxide , heated and stirred to 62°C, reacted for 4 hours, evaporated to remove ethanol, and obtained synergist 2.

Embodiment 3

[0045] In a closed autoclave, blow nitrogen; add 17g diallylamine hydrochloride, 10g 3-amino-4-mercaptoquinoline (CAS: 109543-48-8), 130g ethanol, add 6g sodium methoxide , heated and stirred to 68°C, reacted for 5 hours, evaporated to remove ethanol, and obtained synergist 3.

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Abstract

The invention relates to the technical field of membrane separation, and in particular, relates to a preparation method of a reinforced Pebax mixed matrix membrane. According to the preparation method of the reinforced Pebax mixed matrix membrane, a metal-organic framework (MOF) material is doped into a Pebax-1657 matrix to prepare the mixed matrix membrane, the restrictive effect between permeability and selectivity of the Pebax membrane is improved, and the CO2 permeability coefficient and CO2/N2 selectivity are greatly improved.

Description

technical field [0001] The invention relates to the technical field of membrane separation, in particular to a method for preparing a strengthened Pebax mixed matrix membrane. Background technique [0002] In recent years, global CO 2 Emissions have exploded, causing a great impact on the ecological environment. Compared with conventional high energy consumption CO 2 Capture technologies, such as amine absorption and cryogenic distillation, membrane separation are favored due to their advantages of low cost, high efficiency, and low energy consumption. Polymer membranes have excellent film-forming ability, processability and good mechanical properties, but there is often a restrictive balance between the permeability and selectivity of polymer membranes. Although inorganic membranes exhibit better separation performance, they are costly and difficult to process into uniform membranes. Mixed matrix membranes (MMMs), consisting of inorganic fillers dispersed in polymer mat...

Claims

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Application Information

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IPC IPC(8): B01D67/00B01D69/14B01D71/76B01D53/22
CPCB01D69/141B01D71/76B01D67/0002B01D53/228
Inventor 代岩贺高红宁梦佳刘红晶章星郑文姬阮雪华焉晓明
Owner DALIAN UNIV OF TECH PANJIN INST OF IND TECH
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