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A coating composition, its preparation method and use thereof

A composition, coating technology, applied in the direction of coating, etc.

Pending Publication Date: 2022-02-22
BASF COATINGS GMBH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the disadvantage of high solvent content is also obvious, namely the VOC problem that negatively affects the environment

Method used

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  • A coating composition, its preparation method and use thereof
  • A coating composition, its preparation method and use thereof
  • A coating composition, its preparation method and use thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0038] In the preparation of polyesters, polycarboxylic acids such as aliphatic polycarboxylic acids such as adipic acid, and polyols such as aliphatic polyols such as aliphatic triols and tetraols such as trimethylolpropane can be used , glycerin, pentaerythritol, or any combination thereof.

[0039] It is likewise possible to use aromatic polycarboxylic acids and aromatic polyols, or polyhydric compounds containing not only (straight-chain, branched and / or cyclic) aliphatic groups but also aromatic groups in addition to the functional groups defining their class of compounds. Carboxylic acids and polyols. Straight-chain, branched and / or cyclic aliphatic and / or aromatic hydroxycarboxylic acids and lactones can also be used, i.e. hydroxycarboxylic acids and lactones which, in addition to having functional groups which define their class of compounds, also have a linear , branched and / or cycloaliphatic and / or aromatic groups.

[0040] Therefore, in some embodiments of the pre...

Embodiment approach

[0100] The invention provides a coating composition comprising:

[0101] a) 25-50% by weight, preferably 28-40% by weight, more preferably 30-35% by weight of polymers selected from polyacrylates (A1) and / or polyesters (A2) having a crosslinkable amount of hydroxyl groups Binder as component (A), b) 15-25% by weight, preferably 16-20% by weight, of a crosslinker having functional groups reactive towards OH groups as component (B), and

[0102] c) 35-50% by weight of at least one monomeric and / or oligomeric reactive diluent having at least one ethylenic double bond as component (C),

[0103] Weight percents are based on the total weight of the coating composition.

[0104] Preferably, the coating composition has a hardness of at least 110 seconds, more preferably at least 120 seconds, even more preferably at least 130 seconds, particularly preferably at least 150 seconds after curing to form a coating, measured according to standard DIN EN ISO 1522.

[0105] Preferably, the p...

Embodiment

[0126] Material information:

[0127] Laromer LR 9000: reactive diluent, isocyanate-functional acrylate, commercially available from BASF AG;

[0128] Desmodur 3300: hardener, aliphatic polyisocyanate (HDI trimer), commercially available from Covestro AG;

[0129] Desmodur 3370: hardener, aliphatic polyisocyanate (blocked HDI trimer), commercially available from Covestro AG;

[0130] Desmodur BL 3575: hardener, aliphatic polyisocyanate (blocked HDI trimer), commercially available from Covestro AG;

[0131] Luwipal 014: hardener, melamine-formaldehyde amino resin etherified with n-butanol, commercially available from BASF AG;

[0132] Luwipal 018: hardener, melamine-formaldehyde amino resin etherified with n-butanol, commercially available from BASF AG;

[0133] Luwipal 072: Hardener, melamine-formaldehyde amino resin etherified with alcohol, commercially available from BASF AG.

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Abstract

The present invention relates to a coating composition comprising a) from 25 to 50% by weight of a polymeric binder selected from polyacrylates (A1) and / or polyesters (A2) with a crosslinkable amount of hydroxyl groups, as component (A), b) from 15 to 25% by weight of a crosslinking agent having functional groups that are reactive to OH groups, as component (B), and c) from 35 to 50% by weight of at least one monomeric and / or oligomeric reactive diluent with at least one olefinic double bond, as component (C), the weight percentage is based on the total weight of the coating composition. This coating composition has not only low VOC but also high hardness after curing. The present invention also relates to the preparation method of said coating composition and the use thereof.

Description

[0001] field of invention [0002] The invention relates to a coating composition, in particular to a solvent-based automotive coating. The invention also relates to a method for preparing the coating composition and its use in automobiles. [0003] Background of the invention [0004] In automotive finishing, metal or plastic substrates are coated with multilayer coatings, including electrocoats, primers, basecoats and clearcoats. The clearcoat layer is the outermost layer attached to the basecoat layer, which protects the underlying coating and at the same time provides a glossy appearance. An important requirement for the varnish layer is scratch resistance, so the varnish layer needs to have high hardness. [0005] Generally, the coating composition used for the clear coat is solvent-based, because the solvent is a key component to reduce the viscosity and improve the appearance of the clear coat, and it is difficult to achieve the same or comparable performance with the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D4/02C09D4/06C09D7/63C09D7/65
CPCC09D4/06C09D7/63C09D7/65C09D133/066C09D161/32C08K5/103C08L33/06C08L61/20C08L2312/00C08K5/32
Inventor 汪明李春阳宋媛园眭凌宇S·希尔斯曼C·科尔顿
Owner BASF COATINGS GMBH