NANO flow sensors
A sensor, flow technology, applied in/method development, the field of battery life, can solve the problems of cumbersome, error-prone, long time, etc.
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example 1
[0054] Example 1: Capillary Observation Tubes - Making Silica Capillary Walls Fluorophilic
[0055] Silica capillaries of different inner diameters and an outer diameter of 360 μm were used as observation tubes. However, unless otherwise stated, all data reported here relate to 11 μm ID, 35 cm long polyimide coated fused silica capillaries.
[0056] To make the fluorophilic wall, the capillary was washed sequentially with 0.1M ethanol KOH, water, 0.1M HCl, and water, each step took about 15 minutes, and finally filtered dry N 2 Blow it through to dry and suck the TCPFOS into it and let it react overnight. use N 2 After flushing the spent / excess reagents, flush the capillary with FC. A comparison of the air-fluorocarbon interface between untreated and TCPFOS-treated fused silica capillaries indicated that the contact angle of FC decreased significantly after TCPFOS treatment. Figure 8A and Figure 8B The larger bore 180 μm capillary and the aqueous phase stained with me...
example 2
[0057] Example 2: Generation of multi-segment fluid flow markers
[0058] The procedure for setting up multi-segment flow markers includes providing simultaneous monitoring of flow through the reference method, as follows. In this example, mercury was used because it provides a very visible marker under the microscope. The reference and measurement segments - separated by 1 cm - consisted of a ~2 mm mercury segment in the middle of the test fluid and a string of FC / AA / FC (~5 / 2 / 5 mm in length) as multi-segment markers, respectively.
[0059] To help achieve at least approximately the desired marker length, a 10 cm length of capillary was marked every mm with a fine-tipped marker. All liquids were introduced into the capillary with dedicated 1 mL syringes using appropriate luer adapters to threaded unions. The flow cell is first filled with test fluid (TF). Then, 2mm Hg, 1cm TF, 5mm FC, 2mm AA and 5mm FC were injected sequentially. In all cases, the amount of liquid initia...
example 3
[0066] Example 3: Detection method
[0067] optical detector
[0068] To measure smaller flow rates, the observation tube was a 28 μm inner diameter clear cyclic olefin polymer (COP) capillary; a 10 μL syringe was used for FC delivery and a custom zero dead volume capillary tee was used. Fluorocarbon water interfaces are not discernible even with the smallest optical slits. If the transmission through the aqueous phase is reduced by incorporating a high concentration of dye, the interface can be seen by the detector.
[0069] Using a mercury segment with FC on the side, a reflective interface detection method is explored. This detector construction is very simple and cheap since it does not require special optical aperture or slit arrangements. Initial experiments clearly indicated that the Hg-FC interface was easily detected even in capillaries of 11 μm inner diameter. In some embodiments, further contrast between light reflected by the metal surface and light scattered...
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