Super-capacity graphene battery and preparation method thereof
A graphene and super-capacity technology, applied in the direction of battery electrodes, lithium storage batteries, battery pack components, etc., can solve the problems of electrochemical stability, high and low temperature resistance performance to be further improved, to alleviate the problem of volume expansion, electrochemical Excellent performance and improved rechargeability
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Embodiment 1
[0031] A kind of ultra-capacity graphene battery, it is characterized in that, the positive electrode material of described lithium metal graphene battery is nitrogen-doped nickel cobalt manganese-graphene base compound; The negative electrode material of described lithium metal graphene battery is titanium dioxide quantum dot / Lithium metal / fullerene composite; the diaphragm of the lithium metal graphene battery is made of the following components in parts by weight: 50 parts of hyperbranched polyborosiloxane containing epoxy groups, 10 parts of melamine , 8 parts of nano calcium carbonate.
[0032] The nitrogen-doped nickel-cobalt-manganese-graphene-based composite is a mixture formed by mixing nitrogen-doped nickel-cobalt-manganese ternary material and graphene uniformly at a mass ratio of 3:1; the nitrogen-doped nickel-cobalt-manganese ternary material is Made by the method of Example 1 in Chinese patent document CN107565127B.
Embodiment 2
[0041] A kind of ultra-capacity graphene battery, it is characterized in that, the positive electrode material of described lithium metal graphene battery is nitrogen-doped nickel cobalt manganese-graphene base compound; The negative electrode material of described lithium metal graphene battery is titanium dioxide quantum dot / Lithium metal / fullerene composite; the diaphragm of the lithium metal graphene battery is made of the following components in parts by weight: 53 parts of hyperbranched polyborosiloxane containing epoxy groups, 11 parts of melamine , 8.5 parts of nano calcium carbonate.
[0042] The nitrogen-doped nickel-cobalt-manganese-graphene-based composite is a mixture formed by mixing nitrogen-doped nickel-cobalt-manganese ternary material and graphene uniformly at a mass ratio of 3.5:1; the nitrogen-doped nickel-cobalt-manganese ternary material is Made by the method of Example 1 in Chinese patent document CN107565127B.
[0043] The titanium dioxide quantum dot...
Embodiment 3
[0052] A kind of ultra-capacity graphene battery, it is characterized in that, the positive electrode material of described lithium metal graphene battery is nitrogen-doped nickel cobalt manganese-graphene base compound; The negative electrode material of described lithium metal graphene battery is titanium dioxide quantum dot / Lithium metal / fullerene composite; the diaphragm of the lithium metal graphene battery is made of the following components in parts by weight: 55 parts of hyperbranched polyborosiloxane containing epoxy groups, 13 parts of melamine , 9 parts of nano calcium carbonate.
[0053] The nitrogen-doped nickel-cobalt-manganese-graphene-based composite is a mixture formed by mixing nitrogen-doped nickel-cobalt-manganese ternary material and graphene uniformly at a mass ratio of 4:1; the nitrogen-doped nickel-cobalt-manganese ternary material is Made by the method of Example 1 in Chinese patent document CN107565127B.
[0054] The titanium dioxide quantum dot / met...
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