Hydrofining catalyst containing molybdenum and/or tungsten and nickel and/or cobalt and its preparation process

A hydrorefining and catalyst technology, applied in refining to remove heteroatoms, etc., can solve the problem of low hydrodesulfurization activity and achieve the effect of high hydrodesulfurization activity

Inactive Publication Date: 2005-01-19
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] Although the existing method can produce hydrorefining catalysts that meet the requirements of some hydrorefining processes, the hydrodesulfurization activity is still low

Method used

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  • Hydrofining catalyst containing molybdenum and/or tungsten and nickel and/or cobalt and its preparation process
  • Hydrofining catalyst containing molybdenum and/or tungsten and nickel and/or cobalt and its preparation process
  • Hydrofining catalyst containing molybdenum and/or tungsten and nickel and/or cobalt and its preparation process

Examples

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Effect test

example 1

[0029] 50 grams of industrial gamma-alumina carrier (Changling Refinery Catalyst Factory product) is placed in reaction vessel 5 (see figure 1 ), weigh ammonium metatungstate ((NH 4 ) 2 W 4 o 13 18H 2 O, Sichuan, chemically pure) 50 grams and nickel nitrate (Ni(NO 3 ) 2 ·6H 2 (2, Yixing, chemically pure) 23 grams of water is dissolved into 200 milliliters of solutions, and solution is added to reaction vessel 5 (the liquid-solid ratio of solution and gamma-alumina is 4 milliliters / gram) and soaks for 3 hours, after soaking for 30 minutes, put The probe 3 is inserted into the impregnation solution impregnated with the alumina carrier, the generator 4 is turned on, and ultrasonic radiation is used for 30 minutes. The volume ratio of the ultrasonic radiation power to the impregnation solution is 1.5 W / ml, cooled, filtered, and put into a microwave oven (brand Galanz WD900B) for 15 minutes. Catalyst B-1 was obtained. The catalyst B-1 was dried at 120° C. for 4 hours, and t...

example 2

[0039] 50 grams of industrial gamma-alumina carrier (Changling Refinery Catalyst Factory product) is placed in reaction vessel 5 (see figure 1 ), weigh ammonium metatungstate (NH 4 ) 2 W 4 o 13 18H 2 O, Sichuan, chemically pure) 26 grams and nickel nitrate (Ni(NO 3 ) 2 ·6H 2 (2, Yixing, chemically pure) 9 grams of water are dissolved into 100 milliliters of solutions, and the solution is added to reaction vessel 5 (the liquid-solid ratio of solution and γ-alumina is 2 milliliters / gram) and soaked for 2 hours, after soaking for 30 minutes, The probe 3 is inserted into the impregnation solution impregnated with the alumina carrier, the generator 4 is turned on, and ultrasonic radiation is used for 60 minutes. The volume ratio of the ultrasonic radiation power to the impregnation solution is 3 watts / ml, cooled, filtered, and put into a microwave oven (brand Galanz WD900B) for 20 minutes. Catalyst B-2 was obtained. The catalyst B-2 was dried at 120° C. for 4 hours, and the...

example 3

[0041] 50 grams of industrial gamma-alumina carrier (Changling Refinery Catalyst Factory product) is placed in reaction vessel 5 (see figure 1 ), weigh ammonium metatungstate (NH 4 ) 2 W 4 o 13 18H 2 O, Sichuan, chemically pure) 35 grams and nickel nitrate (Ni(NO 3 ) 2 ·6H 2 (2, Yixing, chemically pure) 18 grams of water is dissolved into 300 milliliters of solutions, and solution is added to reaction vessel 5 (the liquid-solid ratio of solution and γ-alumina is 6 milliliters / gram) and soaks for 4 hours, after soaking for 30 minutes, put The probe 3 is inserted into the impregnation solution impregnated with the alumina carrier, the generator 4 is turned on, and ultrasonic radiation is used for 100 minutes. The volume ratio of the ultrasonic radiation power to the impregnation solution is 1 W / ml, cooled, filtered, and put into a microwave oven (brand Galanz WD900B) for 20 minutes. Catalyst B-3 was obtained. The catalyst B-3 was dried at 120° C. for 4 hours, and the wei...

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Abstract

The invention discloses a hydrofining catalyst containing molybdenum and/or tungsten and nickel and/or cobalt, wherein the catalyst comprises a heat-proof inorganic oxide carrying agent and molybdenum and/or tungsten or tungsten and nickel and/or cobalt loaded on the carrying agent, wherein the catalyst is prepared through immersing the heat-proof inorganic oxide carrying agent with dipping solution containing molybdenum and/or tungsten and nickel and/or cobalt compound. The catalyst prepared by the process provided by the present invention has higher hydrogenation desulfurization activity than the conventional catalyst.

Description

technical field [0001] The present invention relates to a hydrorefining catalyst and its preparation method, more specifically to a hydrorefining catalyst containing molybdenum and / or tungsten and nickel and / or cobalt and its preparation method. Background technique [0002] In recent years, in order to meet the requirements of environmental protection, the harmful gas NO in automobile exhaust x , SO x Countries around the world have promulgated and implemented strict gasoline and diesel standards. This promotes the rapid development of hydrofinishing technology aimed at improving the quality of distillate oil, and hydrofining catalyst is one of the most important and key factors. [0003] Existing hydrorefining catalysts are usually catalysts loaded with Group VIB and Group VIII non-noble metal components on heat-resistant inorganic oxide carriers. It is a common preparation method for this type of catalyst to introduce the active metal componen...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G45/06
Inventor 张乐石亚华聂红龙湘云刘学芬
Owner CHINA PETROLEUM & CHEM CORP
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