Polyurethane blended hollow fiber membrane and method for preparing same
A polyurethane and fiber membrane technology, used in chemical instruments and methods, membrane technology, semi-permeable membrane separation, etc., can solve the problem that the separation performance cannot be completely restored to the original state, the degree of structural densification is low, and the accuracy of memory function is not ideal, etc. problem, to achieve the effect of good separation memory function, good pressure response performance, and wide applicability
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Embodiment 1
[0026] Fiber-grade polyurethane (mass ratio of hard segment / soft segment is 1 / 2) is used as the matrix phase, polyvinylidene fluoride is used as the dispersed component, and the content of polyvinylidene fluoride is 25% (mass percentage, the same below), and the content of polyurethane After uniformly mixing polyurethane and polyvinylidene fluoride chips at a ratio of 75%, they are added to a twin-screw extruder for melt blending and spinning. , 2.5, 3, and 4 times, and then heat-set at 60°C until the fiber structure is relatively stable, and hollow fiber membranes with different microporous structures can be obtained.
Embodiment 2
[0028] According to the method of Example 1, the water flux of the hollow fiber membranes obtained by the four spinneret draw ratios was measured at a pressure of 0.1 MPa and a temperature of 20 ° C, and the corresponding values obtained were 71, 107, 123, and 189 respectively. (L·m -2 h -1 ), showing the proportional relationship between the draw ratio and the water flux of the inventive method.
Embodiment 3
[0030] According to the method of Example 1, the hollow fiber membrane obtained by the spinneret stretching ratio of 4 is measured at the temperature of 20 ° C and the circulation process of 0.05, 0.1, 0.15, 0.1, 0.05Mpa pressure, respectively. Measure its water flux, The corresponding values obtained are 18.15, 189, 597, 188, 18.5 (L·m -2 h -1 ), showing the good pressure response characteristics of the membrane of the present invention.
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