The invention discloses a composition of 2. 5PB 5. 5/8 dyestuff and process for preparing physical color lump therefrom, wherein the composition comprises (by weight portions) CSC-B base-material 995-1005 parts, PV23 with a dyestuff content of 30% 4. 50-4. 60 parts, PB15:3 with a dyestuff content of 27% 7. 07-7. 47 parts, PBK7 with a dyestuff content of 9% 0.68-0.70 part. The principal ingredients of the CSC-B base-material being acrylic acid copolymer with a content of 30-40%. ISO 591 R2 type is selected as the main white dyestuff with the content of TiO2 >=95%, oil absorption <20g/100g, tinting power = 1800, content = 8-12%, the base-material has a contrast ratio of 0.78-0.82, a Stormer viscosity of 90-100KU, when the incident angle is 85 Deg, the lustrousness is 5-10 Deg. The composition of the invention has high weatherability and stability, and good proportioning repeatability. The raw material and technical process can meet low VOC and zero VOC environmental protection requirement and standard, the obtained physical color lump has very low color-difference compared with the normalized value in theoretical models of the Chinese color systems. The invention can achieve high accuracy of color realization, fine production process and high practical values.