Coated fabric containing organic metal catalyst, and its preparing method and use
An organometallic, coated fabric technology, used in textiles and papermaking
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Embodiment 1
[0025] Disperse 2 grams of commercially available iron phthalocyanine in 1000 grams of self-crosslinking polyacrylate emulsion diluted to 1.5% and whose glass transition temperature Tg is -10° C., and stir evenly. Use the method of two dipping and two padding to pad the prepared solution on the cotton knitted fabric, so that the liquid volume is 70% of the weight of the cotton cloth, then dry at 80°C, and then bake at 140°C for 3 minutes. Make it cross-linked and set. That is, a cotton wool cloth containing iron phthalocyanine was obtained. The ammonia elimination rate of the cloth is 72%, and the hydrogen sulfide elimination rate is above 90%.
[0026] Detection method: Put 4 grams of cloth containing the catalyst in a 10-liter plexiglass sealed box with a latex injection window, fill it with odorless fresh air and seal it, inject ammonia or vulcanization through the latex window with a syringe Hydrogen gas so that its concentration is around 100 PPM. Analyze the concentra...
Embodiment 2
[0028] Disperse 1.5 grams of commercially available porphyrin iron in 1000 grams of water-soluble polyurethane solution diluted to 2.5%, and stir evenly. The prepared solution is dipped on the acrylic knitted fabric by two dipping and two rolling methods, so that the liquid amount is 75% of the weight of the acrylic fabric, and then dried at 100° C. to set the shape. That is to obtain the acrylic knitted fabric containing porphyrin iron. The cloth uses the measuring method of embodiment 1 to record the elimination rate of ammonia gas of 64%, and the elimination rate of hydrogen sulfide of 86%.
Embodiment 3
[0030]Dissolve 2.5 grams of sodium iron tetracarboxyphthalocyanine in 1000 grams of water-soluble polyurethane solution diluted to 2%, and stir evenly. The prepared solution is dipped on the polyester plain cloth by the method of two dipping and two rolling, so that the amount of liquid carried is 55% of the weight of the polyester plain cloth, and then dried at a temperature of 100 ° C to set the shape. That is to obtain the acrylic knitted fabric containing iron phthalocyanine. The ammonia elimination rate of the polyester cloth measured by the measurement method in Example 1 is 76%, and the hydrogen sulfide elimination rate is above 90%.
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