Transparent substrate with optical compensation function and its LCD device
A liquid crystal display and transparent substrate technology, applied in optics, optical components, nonlinear optics, etc., can solve the problems of complicated manufacturing process and increased manufacturing cost of flexible liquid crystal displays
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Embodiment 1
[0035] Embodiment 1: 6FDA-m-TB-HG-co-6FDA-DACH (PI-FTD)
[0036] At room temperature, using a three-necked flask with nitrogen, 1.64 g of 2.2'-dimethyl-4-4'-diamine biphenyl (2,2'-Dimethyl-4,4'-diamino biphenyl, m -TB-HG) and 0.70g of 4,4-dimethylene-bis-cyclohexylamine (4,4-methylene bis(cyclohexylamine), DACH) were dissolved in 30g of DMAc, and m-TB-HG and After the DACH was completely dissolved, 5 g of 6FDA bis-acid anhydride was added until the 6FDA was completely dissolved, and the stirring was continued for 3 hours to form a viscous polyamic acid solution. Then use a scraper to form a film on the glass substrate, and then heat it to 100°C, 200°C and 300°C for 1 hour to bake for imidization reaction, and form a highly transparent and colorless polyimide film material. Its molecular structure is as follows: Figure 5 shows.
Embodiment 2
[0037] Embodiment 2: 6FDA-ODA-co-6FDA-DACH (PI-FOD)
[0038] At room temperature, using a three-necked flask with nitrogen gas, dissolve 1.10 g of ODA and 1.16 g of DACH dianiline into 30 g of DMAc, and then add 5 g of 6FDA bis-anhydride until 6FDA is completely dissolved. After complete dissolution, the stirring was continued for 3 hours to form a viscous polyamic acid solution. Then use a scraper to form a film on the glass substrate, and then heat it to 100°C, 200°C and 300°C for 1 hour to bake for imidization reaction, and form a highly transparent and colorless polyimide film material. Its molecular structure is as follows: Figure 6 shows.
Embodiment 3
[0039] Embodiment three: 6FDA-DACH-co-DSDA-DACH (PI-FSD-I)
[0040] At room temperature, using a three-necked flask with nitrogen, dissolve 2.49 g of DACH dianiline into 30 g of DMAc, and then add 3.5 g of 6FDA and 1.5 g of 3,3′,4,4 '-diphenyl sulfone tetracarboxylic acid anhydride 4,4-disulfonyldiphthalic anhydride, DSDA) was added until 6FDA and DSDA were completely dissolved, and continued stirring for 3 hours to form a viscous polyamic acid solution. Then use a scraper to form a film on the glass substrate, and then heat it to 100°C, 200°C and 300°C for 1 hour to bake for imidization reaction, and form a highly transparent and colorless polyimide film material. Its molecular structure is as follows: Figure 7 shows.
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