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Black dye composition and black ink composition

一种黑色染料、组成物的技术,应用在有机染料、油墨、颜料浆料等方向,能够解决日光牢度等特性不佳、未能满足打印需求、墨水pH值不稳定等问题

Inactive Publication Date: 2011-03-30
ETHICAL INT WAREHOUSING TRADING SHANGHAI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] When using reactive dyes (such as Reactive Black No. 31) as the dye component of inkjet ink, the reactive group will be hydrolyzed over time, causing the pH value of the ink to be unstable, and the salts in the ink will also be hydrolyzed by the dye increase, causing problems such as nozzle clogging or changes in the hue of the ink
[0004] U.S. Patent No. 4,694,302 and U.S. Patent No. 5,062,892 once disclosed that the dye composition of black ink commonly used in the past, such as food black No. 2 (Food Black 2), has poor characteristics such as light fastness
[0005] Chinese Taiwan patents TWI265193 and TW200628564 have revealed that the black ink composition prepared with a dye mixture can improve the light fastness of the ink, but its light fastness and printing strength (depth) still fail to meet the aforementioned printing requirements

Method used

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  • Black dye composition and black ink composition
  • Black dye composition and black ink composition
  • Black dye composition and black ink composition

Examples

Experimental program
Comparison scheme
Effect test

preparation example 1

[0164] Take 300 parts of the compound of formula (I-2), add 2700 parts of water to adjust the dissolution, adjust the pH value to 10-11 with 45% aqueous sodium hydroxide solution, and control the temperature at 80-85 ° C, carry out the hydrolysis reaction for 90 minutes, and then use 32 % hydrochloric acid solution to adjust the pH value to 5-9, perform reverse osmosis desalination, and spray dry to obtain the compound of formula (I-1) of the present invention.

[0165]

preparation example 2

[0167] The compound of formula (II-1) of the present invention can be obtained by using the compound of formula (II-2) as a starting material and repeating the steps of Preparation 1.

[0168]

preparation example 3

[0170] The compound of formula (IV-1) of the present invention can be obtained by using the compound of formula (IV-2) as a starting material and repeating the steps of Preparation 1.

[0171]

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PUM

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Abstract

The invention relates to a black dye compound which comprises compositions of: (a) a compound shown in the following formula (I), (b) a compound shown in the following formula (II), and (c) a compound shown in the following formula (III), wherein, the definitions of R1, R2, R3 and R4 are described as instructions. The invention also relates to a black ink compound prepared by the black dye compound. The black ink compound is suitable for paper inkjet printing, and has the characteristics of good sunlight fastness, high power (depth), and good solubility and printing fluency.

Description

technical field [0001] The invention relates to a black dye composition and a black ink composition, in particular to a black dye composition and a black ink composition suitable for inkjet printing on paper. Background technique [0002] Inkjet printing technology is a non-impact printing technology. Its technical characteristics include: sharp, non-feathering images, and good wash fastness ( Water-fastness), light-fastness, optical density, fast drying and good storage stability, good printing fluency, non-clogging nozzles and other characteristics. [0003] When using reactive dyes (such as Reactive Black No. 31) as the dye component of inkjet ink, the reactive group will be hydrolyzed over time, causing the pH value of the ink to be unstable, and the salts in the ink will also be hydrolyzed by the dye And increase, causing problems such as nozzle clogging or ink hue changes. [0004] US Pat. No. 4,694,302 and US Pat. No. 5,062,892 disclosed that the dye components of b...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09B67/36C09D17/00C09D11/02
CPCC09D11/328C09B67/0057C09B67/0055C09B62/0081C09B62/01C09B62/03
Inventor 林文琴孙自揆林仁方
Owner ETHICAL INT WAREHOUSING TRADING SHANGHAI