Foam type stopping agent for preventing mine coal spontaneous combustion and its use method

A chemical inhibitor, coal spontaneous combustion technology, applied in chemical instruments and methods, dustproof, mining equipment, etc., can solve the problems of difficult flame retardant control effect, difficult to distribute evenly, and inability to spray and pour liquid chemical inhibitor into designated areas. , to achieve the effect of overcoming the low efficiency of resistance

Active Publication Date: 2009-07-08
UNIV OF SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Although the traditional method of spraying and pouring inhibitors can play a certain role in the prevention and control of coal spontaneous combustion, it has great limitations, especially for some long and narrow mine roadways, liquid inhibitors (including physical Inhibitors and chemical inhibitors) are sprayed and poured into designated areas, and it is difficult to achieve uniform distribution, and the flame retardant time is also limited; the current method of using the two chemical inhibitors alone is suitable for mines with high requirements for the prevention and control of spontaneous combustion Coal is difficult to achieve effective flame retardant control effect
The existing above-mentioned traditional methods are difficult to achieve ideal prevention and control effects on mine coal with high requirements for spontaneous combustion of coal

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] The preparation process of the chemical inhibitor in this embodiment is: take 1g of potassium permanganate, 2g of fatty alcohol ether sulfosuccinate disodium salt (MES), 0.2g of dodecyl dimethyl amine oxide (OB-2), 0.2g sodium α-olefin sulfonate (AOS), 0.1g cocamidopropyl betaine (CAB), 0.02g polyacrylamide (PAM) and 0.1g alkylphenol ethoxylates (OP-10), successively dissolved in 196.38g of water, stirred until homogeneous.

[0022] The preparation process of physical inhibitor is: take 8g calcium chloride (CaCl 2 ), 12g magnesium chloride (MgCl 2 ), 2g of fatty alcohol ether sulfosuccinate disodium salt (MES), 0.2g of dodecyl dimethyl amine oxide (OB-2), 0.2g of sodium α-olefin sulfonate (AOS), 0.1 g cocamidopropyl betaine (CAB), 0.02 g polyacrylamide (PAM) and 0.1 g alkylphenol ethoxylate (OP-10), were dissolved in 177.38 g water in turn, and stirred until homogeneous.

[0023] The use method of the inhibitor in the present embodiment and the comparative experiment...

Embodiment 2

[0027] The preparation process of the chemical inhibitor in the present embodiment is: weigh 2g of potassium permanganate, 2.4g of fatty alcohol ether sulfosuccinate disodium salt (MES), 0.6g of dodecyl dimethyl oxide Amine (OB-2), 0.1g cocamidopropyl betaine (CAB), 0.02g polyacrylamide (PAM) and 0.15g alkylphenol ethoxylate (OP-10), dissolved in 194.73g water in sequence , and stir until homogeneous.

[0028] The preparation process of the physical inhibitor is: weigh 10g of calcium chloride (CaCl 2 ), 14g magnesium chloride (MgCl 2), 2.4g fatty alcohol ether sulfosuccinate disodium salt (MES), 0.6g lauryl dimethylamine oxide (OB-2), 0.1g cocamidopropyl betaine (CAB), 0.02g of polyacrylamide (PAM) and 0.15g of alkylphenol polyoxyethylene ether (OP-10) were successively dissolved in 172.73g of water and stirred until homogeneous.

[0029] The use method of the inhibitor in the present embodiment and the comparative experiment process thereof are:

[0030] First weigh 100g ...

Embodiment 3

[0033] The preparation process of the chemical inhibitor in the present embodiment is: take by weighing the potassium permanganate of 4g, 3g fatty alcohol ether sulfosuccinate disodium salt (MES), 0.8g α-sodium olefin sulfonate (AOS ), 0.15g cocamidopropyl betaine (CAB), 0.05g polyacrylamide (PAM) and 0.2g alkylphenol ethoxylate (OP-10), were dissolved in 191.8g water in turn, stirred until homogeneous .

[0034] The preparation process of the physical inhibitor is: weigh 10g of calcium chloride (CaCl 2 ), 20g magnesium chloride (MgCl 2 ), 3g of fatty alcohol ether sulfosuccinate disodium salt (MES), 0.8g sodium α-olefin sulfonate (AOS), 0.15g cocamidopropyl betaine (CAB), 0.05g polyacrylamide (PAM) and 0.2g of alkylphenol polyoxyethylene ether (OP-10), were successively dissolved in 165.8g of water, stirred until homogeneous.

[0035] The use method of the inhibitor in the present embodiment and the comparative experiment process thereof are:

[0036] First weigh 100g of ...

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Abstract

The invention discloses a foam retardant for preventing mine well from spontaneously combusting and a using method thereof. The retardant is characterized in that according to the gross mass of a chemical retardant, 0.5 to 2 percent of oxidizing agent is dissolved in water, and then 1 to 1.5 percent of foaming agent, 0.2 to 0.4 percent of foam stabilizing agent, 0.05 to 0.1 percent of thickening agent and 0.05 to 0.1 percent of emulsifying agent are sequentially added and stirred uniformly so as to prepare the chemical retardant; according to the gross mass of a physical retardant, 10 to 15 percent of inorganic salt and other compositions are added by the same method as the former so as to prepare the physical retardant; when the retardant is used, the chemical retardant is diluted into an aqueous solution with a concentration of between 1.76 and 4.1 weight percent first, and the aqueous solution is sprayed to a target coal layer area; after 30 minutes to 1 hour, the physical retardant which is diluted into an aqueous solution with a concentration of between 11.06 and 16.9 weight percent is sprayed into the same area; and inhibition foams are covered on the surface of the coal layer so as to achieve the effect of preventing the spontaneous combustion for a long time on the coal layer of the area.

Description

technical field [0001] The invention belongs to the technical field of preventing and controlling spontaneous combustion of mine coal, and in particular relates to a foam-type inhibitor containing an oxidizing agent, an inorganic salt and a surfactant and a use method thereof. Background technique [0002] The existing inhibitors for preventing spontaneous combustion of mine coal can be divided into two categories: physical inhibitors and chemical inhibitors. Physical inhibitors are mainly inorganic salts, including sodium chloride (NaCl), calcium chloride (CaCl 2 ) and magnesium chloride (MgCl 2 ) etc.; because these inorganic salts have strong water absorption, when they attach to the surface of coal, they can absorb moisture in the air, thereby reducing the temperature of the coal seam and forming a water-containing liquid film on the surface of coal particles, preventing the coal from contacting oxygen. Contact, play the role of oxygen barrier resistance. Chemical inh...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): E21F5/06E21F5/00C09K3/00
Inventor 胡源杨伟宋磊
Owner UNIV OF SCI & TECH OF CHINA
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