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Use of polypropylene composition

A technology of propylene polymer and composition, used in rotomolding products, the application field of polymer composition for rotomolding

Active Publication Date: 2013-03-06
BOREALIS TECH OY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

To date, there has been no rotomolded polypropylene-based composition that provides an article with an excellent balance of all these properties

Method used

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  • Use of polypropylene composition
  • Use of polypropylene composition
  • Use of polypropylene composition

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0124] Example 1 - Blending

[0125] Preparation of propylene polymer components

[0126] Polymers having the properties listed in Table 1 below were prepared according to the methods described in the illustrated prior art or purchased from the indicated suppliers.

[0127] Table 1

[0128] get together

combine

thing

nature

MFR 2

(g / 10

minute)

Nucleation

C 2 content

(wt%)

Tc

(℃)

T m

(℃)

reduce

stick

crack

change *

Tensile modulus

(MPa)

warping

(mm)

1 a

Homopolymer

20

yes, use

VCH's

polymer

-

129

167

no

2200

47

2 b

Homopolymer

20

no

-

110

161

yes ...

Embodiment 2

[0148] Example 2 - Preparation of bimodal propylene polymers using a reactor

[0149] Preparation of Bimodal Propylene Polymers

[0150] Two polymers with the properties listed in Table 4 below were prepared according to the Borstar method described here.

[0151] Table 4

[0152]

[0153]Polymers 11 and 12 were prepared according to the examples in EP887379, with the difference that, where noted, a multistage polymerization process was used comprising prepolymerization, polymerization in a loop reactor (slurry polymerization), followed by Final polymerization in gas phase reactor. The loop reactor and / or the gas phase reactor are additionally replenished with comonomer during the polymerization. The ZN catalyst used is described in US 5,234,879, used at a temperature of 135°C. The catalyst is contacted with a cocatalyst (triethylaluminum, TEAL) and an external donor (donor D, dicyclopentyldimethoxysilane) to produce a catalyst system with an Al / Ti ratio of 200 and an...

Embodiment 3

[0159] Example 3 - Preparation of bimodal propylene polymer / impact modifier using reactor

[0160] Three polymers with the properties listed in Table 6 below were prepared according to the Borstar method described here.

[0161] These polymers were prepared according to the examples in EP887379, only where it was noted that a multi-stage polymerization process was used, which included prepolymerization, polymerization in a loop reactor (slurry polymerization), followed by a gas phase reactor final aggregation. The loop reactor and / or the gas phase reactor are additionally replenished with comonomer during the polymerization. The ZN catalyst used is described in US 5,234,879, used at a temperature of 135°C. The catalyst was contacted with a cocatalyst (triethylaluminum, TEAL) and an external donor (donor D, dicyclopentyldimethoxysilane) to obtain a catalyst system with an Al / Ti ratio of 200, respectively (executed Example 13) and 360 (Examples 14 and 15) with an Al / D ratio o...

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Abstract

This invention relates to use of a polymer composition for rotomoulding, wherein said composition comprises: (i) at least two propylene polymer components; (ii) a nucleating agent; and (iii) an impact modifier.

Description

technical field [0001] The present invention relates to the application of special polypropylene composition in rotomoulding, to the method of rotomolding using the composition and the rotomolding product obtained therefrom. More specifically, the present invention relates to the use for rotomoulding of a polymer composition comprising at least two polypropylene components, at least one nucleating agent and an impact modifier. Background technique [0002] Rotational molding (or rotational molding) is a molding in which particulate polymer, molding powder is filled into a mold, the mold is placed in an oven and rotated so that the polymer melts and coats the inner surface of the mold method. To ensure that molded articles are defect-free, a homogeneous melt must be formed. Therefore the key step in rotomolding is the sintering of the molding powder. It is characterized by the appearance of agglomeration of the molding powder and the generation of a porous three-dimensiona...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/10B29C41/04
CPCB29K2075/00C08L23/12B29L2031/7692C08L2205/03C08L23/10C08L23/0815B29C39/10B29C39/24C08L23/142B29C39/006B29L2031/4828B29L2031/5254C08L2205/02Y10T428/2982C08L2666/02
Inventor 埃斯彭·欧蒙德森佩塔尔·多舍弗海迪·芬斯塔罗尼·尔维克
Owner BOREALIS TECH OY