Method for preparing bamboo dissolving pulp by improved prehydrolysis alkaline process and product thereof

A technology of dissolving pulp and pre-hydrolysis, which is applied in pulping with inorganic alkali, pretreatment with acidic compounds, non-woody plant/crop pulp, etc., can solve the problems of process shortening and waste of resources, and achieve the reduction of processing costs and comprehensive The effect of low production cost

A technology of dissolving pulp and pre-hydrolysis, which is applied in pulping with inorganic alkali, pretreatment with acidic compounds, non-woody plant/crop pulp, etc., can solve the problems of process shortening and waste of resources, and achieve the reduction of processing costs and comprehensive The effect of low production cost

CN101514529AInactive Publication Date: 2009-08-26上海士林纤维材料有限公司

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Method for preparing bamboo dissolving pulp by improved prehydrolysis alkaline process and product thereof
  • Method for preparing bamboo dissolving pulp by improved prehydrolysis alkaline process and product thereof
  • Method for preparing bamboo dissolving pulp by improved prehydrolysis alkaline process and product thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0066] Provide a kind of method that the improved pre-hydrolysis alkali method manufactures bamboo dissolving pulp, comprises the steps:

[0067] (1) Bamboo material preparation: cut two to three-year-old bamboo into bamboo chips with a length of 15-30mm, a width of 10-20mm, and a thickness of 3-8mm through a slicer, screen through a high-frequency vibrating screen, and spray and wash with high-pressure water , remove impurities and dust;

[0068] (2) Pretreatment: carried out in a hydrolysis pot, the treatment agent is sulfuric acid, and the process conditions are: the sulfuric acid concentration is 0.1wt%, the temperature is 110 ° C, the liquid ratio is 1: 10, the treatment time is 60 minutes, and the treatment is discharged after the pretreatment liquid, and washing material;

[0069] (3) Pre-hydrolysis: carried out in a hydrolysis pot, the hydrolysis catalyst is sulfuric acid, and the process conditions are: the concentration of sulfuric acid is 0.7wt%, the temperature is...

Embodiment 2

[0081] Provide another kind of improved prehydrolysis alkali method to manufacture the method for bamboo dissolving pulp, comprise the steps:

[0082] (1) Bamboo material preparation: with embodiment 1, two to three-year-old bamboo materials are cut into long 15~30mm, wide 10~20mm, thick 3~8mm bamboo slices by slicer, screened by high-frequency vibrating sieve, and use high-pressure Spray washing with water to remove impurities and dust;

[0083] (2) pretreatment: with embodiment 1, carry out in hydrolysis pot, treatment agent is sulfuric acid, and process condition is: sulfuric acid concentration is 0.1wt%, and temperature is 110 ℃, and liquid ratio is 1: 10, and treatment time is 60 minutes, After pretreatment, the treatment liquid is discharged and the material is washed;

[0084] (3) Pre-hydrolysis: carried out in a hydrolysis pot, the hydrolysis catalyst is sulfuric acid, the process conditions are: the acid concentration is 1.5wt%, the temperature is 125 ° C, the liquid...

Embodiment 3

[0087] Provide another kind of improved prehydrolysis alkali method to manufacture the method for bamboo dissolving pulp, comprise the steps:

[0088] (1) Bamboo material preparation: with embodiment 1, two to three-year-old bamboo materials are cut into long 15~30mm, wide 10~20mm, thick 3~8mm bamboo slices by slicer, screened by high-frequency vibrating sieve, and use high-pressure Spray washing with water to remove impurities and dust;

[0089] (2) pretreatment: with embodiment 1, carry out in hydrolysis pot, treatment agent is sulfuric acid, and technological condition is: sulfuric acid concentration is 0.1wt%, and temperature is 110 ℃, and liquid ratio is 1: 10, and treatment time is 60 minutes, After pretreatment, the treatment liquid is discharged and the material is washed;

[0090] (3) pre-hydrolysis: with embodiment 1, carry out in hydrolysis pot, hydrolysis catalyst is sulfuric acid, and process condition is: sulfuric acid concentration is 0.7wt%, and temperature is...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
sizeaaaaaaaaaa
sizeaaaaaaaaaa
thicknessaaaaaaaaaa
Login to View More

Abstract

The invention relates to a method for preparing bamboo dissolving pulp by improved prehydrolysis alkaline process, which comprises the following steps of: bamboo material preparation, in which bamboo is made into bamboo sheets and bamboo threads, the bamboo sheets and threads are washed to remove impurities and dust; pretreatment, which is for removing more organic and nonorganic impurities, and in which the loss of pentosan is less than 2 percent; prehydrolysis, which is carried out at an acid concentration of sulphuric acid and hydrochloric acid of 0.1 to 10.0 weight percent, a temperature of between 80 and 14 DEG C and a liquor ratio of 1:4-15 for 30 to 400 minutes; and alkaline process. The method has the advantages that: the performance index of the bamboo dissolving pulp meets the requirements of viscose fibre pulp and the like; the improved prehydrolysis process allows the major part of pentosan in the bamboo to be hydrolyzed; the hydrolysate can be used as a raw material for xylose, xylitol, L-Arabinitol, ethanol and other products; the improved prehydrolysis process lays a good foundation for cooking and improving the reaction performance of the dissolving pulp; little production cost is added, the treatment load and cost of waste are reduced with the recovery of the products of the prehydrolysis, and the comprehensive cost is the lowest; and the comprehensive utilization of the components of biomass is realized during the pulping process of the dissolving pump.

Description

technical field [0001] The invention relates to the fields of chemical engineering, hydrolysis technology and dissolving pulp manufacturing technology, in particular to an improved prehydrolysis alkali method for manufacturing bamboo dissolving pulp and its products. Background technique [0002] Lignocellulosic raw materials are mainly used in pulp and dissolving pulp, the latter including viscose fiber pulp, cellulose acetate dissolving pulp, nitrocellulose dissolving pulp and cellulose ether dissolving pulp. Viscose fiber pulp is one of the most important varieties. The viscose fiber pulp industry has formed a complete raw material and technology system after nearly a hundred years of development. In recent years, with the rapid expansion of market demand and fiber production capacity, domestic viscose fiber pulp consumption has also increased significantly, and a large amount of wood pulp needs to be imported every year, and the bottleneck contradiction of raw materials ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
26 Aug 2009
Publication
CN101514529A
IPC
D21C1/04; D21C3/02; D21H11/12
Inventors
吴学东; 陈惠敏