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Method for preparing controllable photodegraded flexible indoor air purifying material

A technology for indoor air and purification materials, applied in chemical instruments and methods, catalyst activation/preparation, chemical/physical processes, etc., can solve the constraints of industrial production of flexible air purification functional materials, poor photocatalyst reusability, and no chemical bond cooperation To achieve the effect of efficient and rapid air purification, large surface area, and self-cleaning

Inactive Publication Date: 2012-01-04
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Among the above three preparation methods that have been reported, the first two kinds of titanium dioxide are mainly adsorbed on the flexible polymer carrier by hydrogen bonding, and there is no chemical bonding with the flexible polymer substrate, so the reusable performance of the photocatalyst may be compared. Difference [20]
In addition, due to the coating method, the photocatalyst is covered by the binder, which will lead to a decrease in its photocatalytic activity.
Regardless of the method, there are problems of how to make the surface of the flexible material function as a photocatalyst, the low concentration of organic gas pollutants, the low adsorption efficiency of the photocatalyst, and the oxidative degradation of the flexible substrate or organic adhesive by the photocatalyst. question
Especially the latter problem, because the strong oxidative power of the photocatalyst will cause the fiber or adhesive to decompose itself. At present, there is a lack of in-depth understanding of the photooxidative degradation mechanism of flexible substrates, and there is a lack of effective methods to solve this problem, so it is seriously restricted. Industrialized production of flexible air purification functional materials

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] (1) 80 mL of a mixed solution of N-(beta-aminoethyl)-gama-aminopropyltrimethoxysilane and 2-methoxyethanol with a ratio of 3:1 of the mass of the configuration substance, silver nitrate in the mixed solution , stir vigorously until the silver nitrate is completely dispersed evenly, slowly add 10mL of 98% titanium tetraisopropoxide dropwise to the above solution, and under the action of vigorous stirring, gradually add 80mL of 2-methoxy A mixed solution of ethanol and water, after standing still to form a gel, put it in a vacuum oven and dry it at 65°C for 60 hours, then slowly reduce the pressure to 1100Pa, then raise the temperature to 140°C and dry it for 20 hours. catalyst powder. Wash the powder with deionized water under the action of ultrasonic waves for 3 hours, then filter with filter paper, wash the filtered powder twice with a mixed solution of deionized water and methanol, filter, and place the filtered powder in a blast oven at 40°C After drying for 1 hour,...

Embodiment 2

[0034] (1) 90mL of N-(beta-aminoethyl)-gama-aminopropyltrimethoxysilane and 2-methoxyethanol mixed solution with a ratio of 2:1, and silver nitrate was added to the mixed solution , stir vigorously until the silver nitrate is completely dispersed and uniform, slowly add 15mL of 98% titanium tetraisopropoxide dropwise to the above solution, and under the action of vigorous stirring, gradually add 90mL of 2-methoxy A mixed solution of ethanol and water, after standing still to form a gel, put it in a vacuum drying oven and dry it at 70°C for 66 hours, the pressure slowly drops to 1150Pa, and then the temperature is raised to 145°C and dried for 22 hours to obtain a light catalyst powder. Wash the powder with deionized water under the action of ultrasonic waves for 4.5h, then filter with filter paper, wash the filtered powder twice with a mixed solution of deionized water and methanol, filter, and place the filtered powder in a blast oven at 45°C After drying under high temperat...

Embodiment 3

[0043] (1) 100 mL of a mixture of N-(beta-aminoethyl)-gama-aminopropyltrimethoxysilane and 2-methoxyethanol with a ratio of 1:1 of the mass of the preparation, and nitric acid was added to the mixture Silver, stir vigorously until the silver nitrate is completely dispersed evenly, slowly add 20mL of 98% titanium tetraisopropoxide dropwise to the above solution, and under the action of vigorous stirring, gradually add 100mL of 2- The mixed solution of methoxyethanol and water, after statically forming a gel, is dried in a vacuum oven at 75°C for 72 hours, the pressure is slowly reduced to 1200Pa, and then the temperature is raised to 150°C and dried for 24 hours to prepare photocatalyst powder. Wash the powder with deionized water under the action of ultrasonic waves for 6 hours, then filter with filter paper, wash the filtered powder with a mixed solution of deionized water and methanol for 3 times, filter, and place the filtered powder in a blast oven at 50°C After drying fo...

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Abstract

The invention relates to a method for preparing a controllable photodegraded flexible indoor air purifying material. The method comprises the following steps of: (1) preparing a photocatalyst with a hollow heterogeneous structure; (2) treating the surface of a flexible base material and setting an intermediate protective layer; and (3) printing a print agent onto the flexible base material by a method of screen printing, and preparing the controllable photodegraded flexible indoor air purifying material after drying and washing. The preparation method is simple and easy for operation and is applicable to industrial scale production; and the prepared controllable photodegraded flexible indoor air purifying material can remove indoor typical pollutants with high efficiency, such as formaldehyde, benzene, toluene, volatile organic matters and other harmful substances.

Description

technical field [0001] The invention belongs to the field of preparation of air purification materials, in particular to a preparation method of controllable photodegradable flexible indoor air purification materials. Background technique [0002] Since the 1990s, indoor air pollution and health have become one of the important environmental issues that governments and the public pay attention to. Especially in my country, with the improvement of people's material living standards, interior decoration, the popularization of a large number of electrical products and air conditioners, the use of various daily chemicals, architectural design styles and the use of central air conditioners have increased the airtightness of living rooms, etc. The reason is that a large number of physical, chemical, biological and radioactive pollution factors are produced indoors, causing a serious decline in indoor air quality and seriously endangering human health, which has aroused great concer...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/50B01J21/06B01J21/08B01J35/02B01J37/08D06M11/83D06M11/79D06M11/46A62D3/10A61L9/18A61L101/12A62D101/20A62D101/28
Inventor 何瑾馨刘保江高品程绪帮刘路赵强强郑兆和郝绍芳
Owner DONGHUA UNIV