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Method for preparing polyethylene/maize cob meal composite material

A technology of corn cob powder and composite materials, which is applied in the field of composite materials, can solve the problems of polyolefin/corn cob powder composite materials that have been reported but have not yet been discovered, and achieve cheap raw materials, suitable for large-scale industrial production, and good machinery. Performance and effects of biodegradability

Inactive Publication Date: 2011-08-31
SHAANXI UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Corncob flour is a low-cost natural high polymer. Its porous structure makes it have good adsorption performance, large specific surface area and fast degradation rate. So far, no effect on polyolefin / corncob flour has been found. Research on composite materials is reported

Method used

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  • Method for preparing polyethylene/maize cob meal composite material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Weigh each raw material according to mass percentage: 10% of corn cob powder, 80% of polyethylene, 5% of polyethylene grafted maleic anhydride, 2% of zinc stearate, and the balance is glycerin. Corncob powder and glycerin (glycerin mass is 30% of the corncob powder mass) are added to a high-speed mixer for uniform mixing, then the uniformly mixed mixture is placed in a plastic bag and sealed for 24 to 48 hours to make the small molecular plastic The chemical agent is fully penetrated into the corn cob powder; the above mixture is added to a high-speed mixer together with polyethylene, polyethylene grafted maleic anhydride and zinc stearate for uniform mixing to obtain a polyethylene / corn cob powder mixture, and finally the The above homogeneously mixed polyethylene / corn cob powder mixture is added to the twin-screw extruder, and the mixed Extrude the material to obtain a strip-shaped polyethylene / corn cob powder composite material extrusion with a diameter of about 3mm....

Embodiment 2

[0023] Weigh each raw material according to mass percentage: 20% of corncob powder, 60% of polyethylene, 15% of ethylene-vinyl acetate copolymer, 1% of calcium stearate, and the balance is ethylene glycol. Add corncob powder and ethylene glycol (the quality of ethylene glycol is 20% of the mass of corncob powder) into a high-speed mixer for uniform mixing, then place the well-mixed mixture in a plastic bag and seal it for 24 to 48 hours Make the small molecule plasticizer fully penetrate into the corncob powder; add the above mixture together with polyethylene, ethylene-vinyl acetate copolymer and calcium stearate into a high-speed mixer for uniform mixing to obtain polyethylene / corncob powder mixture , and finally the above-mentioned homogeneously mixed polyethylene / corncob mixture is added to the twin-screw extruder, at an extrusion temperature of 100°C-140°C-160°C-140°C (from the feed port to the discharge port) Next, extrude the mixture to obtain a strip-shaped polyethylen...

Embodiment 3

[0025] Weigh each raw material according to mass percentage: 40% of corncob powder, 50% of polyethylene, 5.5% of ethylene-methyl acrylate copolymer, 0.5% of polyethylene wax, and the balance is glycerin and urea. Glycerin and urea (the total mass of glycerol and urea is 10% of the corn cob powder mass) are mixed evenly and added to the corn cob powder, then added to a high-speed mixer for uniform mixing, and the uniformly mixed mixture is placed in a plastic bag After sealing, place it for 24-48 hours to allow the small molecule plasticizer to fully penetrate into the corncob powder; add the above mixture together with polyethylene, ethylene-methyl acrylate copolymer and polyethylene wax into a high-speed mixer for uniform mixing to obtain poly Ethylene / corncob powder mixture, and finally the above-mentioned homogeneously mixed polyethylene / corncob powder mixture is added to the twin-screw extruder, at 100℃-140℃-160℃-140℃ (from the inlet to the outlet Extrude the mixture at th...

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Abstract

The invention discloses a method for preparing a polyethylene / maize cob meal composite material. The method comprises the following steps: after weighing polyethylene, maize cob meal, plasticizer, compatibilizer and lubricant according to a certain mass percentage, firstly, adding the maize cob meal and the plasticizer into a high-speed mixer for uniform mixing; then, placing mixture into a plastic bag for sealing, adding the mixture, the polyethylene, the compatibilizer and the lubricant into the high-speed mixer for uniform mixing after placement; and finally, adding the uniformly-mixed polyethylene / maize cob meal mixture into an extruder, and extruding the mixture at a certain extrusion temperature to obtain the polyethylene / maize cob meal composite material. The composite material prepared by the invention has good mechanical performance and biodegradation performance and can be used for machining a biodegradable plastic product, and has low cost; the polyethylene / maize cob meal composite material provided by the invention can be completed in the extruder by one step; and a preparation process is simple, easy to operate and suitable for large-scale industrialized production.

Description

technical field [0001] The invention belongs to the field of composite materials, and in particular relates to a preparation method of a polyethylene / corn cob powder composite material. Background technique [0002] In order to solve the environmental pollution caused by non-degradable plastic waste, researchers in many countries are working on the research and development of environmentally degradable plastics. At present, polyolefin-based starch, cellulose, lignin and other filled and modified composite materials are widely used. This material is eroded by microorganisms in the soil to starch, cellulose, lignin, etc., so that the filled compound The material product is shredded and gradually degraded. However, in these composite materials, the degradation rate of cellulose and lignin is relatively slow, and the cost of starch as food is relatively high, which is not conducive to obtaining good economic benefits. As a by-product of the corn starch production process, corn...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08K5/098C08L51/06C08L23/06C08L23/08C08K5/21C08K5/09C08L33/02C08K5/053C08L33/08B29C47/92C08L31/04C08L97/02B29C48/92
CPCB29C48/92B29C2948/92704B29C2948/92895
Inventor 杨晓明
Owner SHAANXI UNIV OF TECH