Modified polymer complex, complex monomer, polymer complex, and redox catalyst

A complex and polymer technology, applied in the direction of organic compound/hydride/coordination complex catalyst, physical/chemical process catalyst, copper organic compound, etc., can solve the problem of poor storage stability, poor manufacturing reproducibility, expensive catalyst, etc. problem, to achieve the effect of high reactivity and excellent thermal stability
CN101772488AInactive Publication Date: 2010-07-07SUMITOMO CHEM CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SUMITOMO CHEM CO LTD
Publication Date
2010-07-07
Estimated Expiration
Not applicable · inactive patent

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Abstract

Disclosed is a modified polymer complex produced by the intermolecular and / or intramolecular crosslinking of a polymer complex via its side chains, wherein the polymer complex is a copolymer of a complex monomer meeting the requirements (i) to (iii) and a comonomer represented by the general formula (1): R02R03=R01E [wherein the definitions for R01, R02, R03 and E are omitted]. (i) The complex monomer has two or more transition metal atoms. (ii) The complex monomer has a polydentate ligand having three or more coordinating atoms that coordinately bind to the transition metal atoms. (iii) The polydentate ligand has one or more polymerizable functional groups.
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Description

technical field

[0001] The invention relates to a modified polymer complex, a complex monomer, a polymer complex and a redox catalyst. Background technique

[0002] A polynuclear complex is a complex containing two or more metal atoms as central atoms in one complex (Chemical Dictionary, 1st edition, 1994, Tokyo Chemical Doujin). Such a multinuclear complex exhibits specific and various reactivity based on the interaction between multiple metal sites, so it can be used as a reaction catalyst, for example, it is useful as a catalyst for a chemical reaction involving electron transfer such as a redox catalyst. (For example, refer to Kenichi Koyanagitsu, Makoto Yuasa, Surface 2003, 41(3), 22).

[0003] As a polynuclear complex, as a catalyst (hydrogen peroxide decomposition catalyst) that suppresses the generation of free radicals (hydroxyl radicals, hydrogen peroxide radicals, etc.) and decomposes hydrogen peroxide into water and oxygen, manganese dinuclear Complexes (see, f...

Claims

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