Aspects of the disclosure relates to articles, compositions, and systems for several optoelectronic applications. In some embodiments, the disclosure relates to the
metal organic frameworks (MOF). The MOFs comprise a plurality of
metal clusters and a plurality of ligands that are coordinated with the plurality of
metal clusters. Some aspects of the disclosure relate to the luminescent MOFs and the various synthetic methods for their preparation. Some aspects also disclose one or more mechanisms unveiled by luminescent MOFs for various
OLED applications. In some embodiments, the disclosure relates to the
lanthanide-based metal organic frameworks for
OLED applications. Some aspects of the disclosure focus on the versatile coordination
chemistry shown by the lanthanides along with the structural tunability of MOFs, thereby resulting in exceptional
luminescence, high
thermal stability and tuneable
electronic properties. In some embodiments, the disclosure relates to the enhancement of the luminescent behaviour by the utilization of dual-based
lanthanide metal-organic frameworks. Lastly, in some embodiments, the disclosure relates to the
zirconium-based and
zinc-based MOFs due to their stability and tuneable
luminescence behaviour. Thus, the
lanthanide-based MOFs play an important role in shaping the future of advanced photonic and optoelectronic devices due to their outstanding characteristic properties and their ability to integrate multiple functionalities within a single framework.