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260results about "Group 2/12 element organic compounds" patented technology

Novel dinuclear metal complex and pyrophosphate assay using the same

A novel coordination complex formed by dinuclear metal complexation is provided. The complex is a dinuclear metal complex of a compound, wherein the compound comprises a conjugation ring system substituted with: a) an electron donating group selected from —OH, —SH and —NH2; b) an indicating group selected from a chromogenic group, a fluorescent group and an electrochemical group; and c) two binding auxiliary groups, in combination with the electron donating group each of which being coordinated with the metal to provide an anion bonding site, wherein as the complex binds to a anion, the coordination of the electron donating group with the metal is weakened and electron donation of the electron donating group to the conjugation ring system is reinforced such that the reinforced electron donation by the electron donating group is transferred through the conjugation ring system to the indicating group to produce an indicating signal concomitant with the change of its electronic density. The coordination complex shows high sensitivity and high selectivity for pyrophosphate over other anions in an aqueous solvent over a wide pH range. Therefore, the complex is useful for pyrophosphate assay as a pyrophosphate sensor.
Owner:SEOUL NAT UNIV FOUND

Method and Apparatus for Microwave Reduction of Organic Compounds

The invention described herein generally pertains to utilization of high power density microwave energy to reduce organic compounds to carbon and their constituents, primarily in a gaseous state. The process includes, but is not limited to, scrap tires, plastics, asphalt roofing shingles, computer waste, medical waste, municipal solid waste, construction waste, shale oil, and PCB / PAH / HCB-laden materials. The process includes the steps of feeding organic material into a microwave applicator and exposing the material to microwave energy fed from at least two linear polarized sources in non-parallel alignment to each other, and collecting the material. The at least two sources of microwave energy are from a bifurcated waveguide assembly, whose outputs are perpendicular to each other and fed through waveguide of proper impedance, such that the microwave sources are physically and electrically 90° out of phase to each other. The microwave frequency is between 894 and 1000 MHz, preferably approximately 915 MHz.
Owner:NOVAK JUDITH

Zeolite-like metal organic frameworks (ZMOFS): modular approach to the synthesis of organic-inorganic hybrid porous materials having a zeolite like topology

The subject invention pertains to metal organic frameworks (MOF) having zeolite-net-like topology, their methods of use, and their modes of synthesis. The ZMOFs are produced by combining predesigned tetrahedral building, generated in situ using heterochelation, with polyfunctional ligands that have the commensurate angle and the required donor groups for the chelation. Each molecular building block is contrasted of a single metal ion and ligands with both heterochelation functionality and bridging functionality. Advantageously, zeolite-net-like MOFs of the subject invention are porous and contain large functional cavities, which is useful for encapsulating large molecules.
Owner:UNIV OF SOUTH FLORIDA

Microwave torrefaction of biomass

There is described a processor for use in the microwave torrefaction of biomass material which comprises, a micronised biomass char material and a method of producing a biomass char material, and a method of producing L-glucosan.
Owner:THE UNIV OF YORK

Process for microwave decomposition of hazardous matter

This process occurs in the presence of activated carbon or its equivalent by decomposing adsorbed hazardous materials, such as hydrazine and microorganisms, on the carbon surface by radiofrequency energy in the microwave range at near ambient conditions of temperature and pressure. Further microwave oxidation to nonhazardous gases occurs in the presence of a microwaves enhanced oxidation catalyst.
Owner:CHA CHANG YUL

Systems and methods for producing fuels from biomass

The present invention relates to systems and methods for producing fuels. In an embodiment, the invention includes a method of producing a diesel-equivalent fuel, including pyrolyzing biomass to form a pyrolysis oil and contacting the pyrolysis oil and an alcohol with a metal oxide catalyst at a temperature of greater than about 60 degrees Celsius. In an embodiment, the invention includes a method of refining pyrolysis oil including contacting pyrolysis oil and an alcohol with a metal oxide catalyst at a temperature of greater than about 60 degrees Celsius. In an embodiment, the invention includes a system for processing biomass into fuel including a pyrolysis chamber defining an interior volume; a first heating element configured to heat the pyrolysis chamber; a refining chamber in selective fluid communication with the pyrolysis chamber, the refining chamber defining an interior volume, a metal oxide catalyst disposed within the interior volume; and a second heating element configured to heat the refining chamber. Other embodiments are also described herein.
Owner:SARTEC

Water repellent metal-organic frameworks, process for making and uses regarding same

Microwave assisted synthesis may be used to produce water-repellent metallic organic frameworks (MOFs) molecules. The water-repellent MOFs contain non-polar functional groups, such as a trifluoromethoxy group, which has a strong water repellent effect. The water-repellent MOF, when exposed to water vapor for one week does not result in a significant X-ray power pattern change. The water-repellent MOFs may be suitable as an adsorbent in many industrial applications, such as gas chromatography.
Owner:THE BOARD OF TRUSTEES OF THE UNIV OF ILLINOIS

Highly Luminescent Nanostructures and Methods of Producing Same

Highly luminescent nanostructures, particularly highly luminescent quantum dots, are provided. The nanostructures have high photoluminescence quantum yields and in certain embodiments emit light at particular wavelengths and have a narrow size distribution. The nanostructures can comprise ligands, including C5-C8 carboxylic acid ligands employed during shell formation and / or dicarboxylic or polycarboxylic acid ligands provided after synthesis. Processes for producing such highly luminescent nanostructures are also provided, including methods for enriching nanostructure cores with indium and techniques for shell synthesis.
Owner:NANOSYS INC

Plasmonic engineering of singlet oxygen and/or superoxide generation

ActiveUS20080215122A1Increase triplet yieldIncreased oxygen generationBiocideGroup 8/9/10/18 element organic compoundsEnergy absorptionSuperoxide
The present invention provides for a method to increase the triplet yield of a photosensitizer by the coupling to metal surface plasmons which leads to increased singlet oxygen generation by electric field enhancement or enhanced energy absorption of the photosensitizer. The extent of singlet oxygen enhancement can be tuned for applications in singlet oxygen based clinical therapy by modifying plasmon coupling parameters, such as metallic nanoparticle size and shape, photosensitizer / metallic nanoparticle distance, and the excitation wavelength of the coupling photosensitizer.
Owner:UNIV OF MARYLAND BALTIMORE COUNTY

Microwave induced functionalization of single wall carbon nanotubes and composites prepared therefrom

The invention is directed to a method of forming, producing or manufacturing functionalized nanomaterials, and, specifically, soluble functionalized nanomaterials. The presently described invention also relates to nanomaterial-based composites consisting of a target material, which can include ceramic, polymer, or metallic matrices incorporated into or grown on nanomaterials, as well as a method or synthesis technique for the formation, production, or manufacture of nanomaterial-based composites through microwave-induced reaction.
Owner:NEW JERSEY INSTITUTE OF TECHNOLOGY

Reaction and temperature control for high power microwave-assisted chemistry techniques

A method is disclosed for carrying out microwave assisted chemical reactions. The method includes the steps of placing reactants in a microwave-transparent vessel, placing the vessel and its contents into a microwave cavity, applying microwave radiation within the cavity and to the vessel and its contents while concurrently externally cooling the vessel conductively.
Owner:CEM CORP

Compositions and Formulations for the Treatment of Halitosis

An orally disintegrating composition comprising a chelate comprising a metal ion and a biologically acceptable amino acid and having the general formulawherein M is the metal ion Zn2+ and R is H in the biologically acceptable amino acid glycine, use of the composition for the treatment of halitosis, and a chewing gum for the treatment of halitosis comprising a chelate comprising a metal ion and a biologically acceptable amino acid and having said general formula, which chewing gum is based on a carrier composition comprising a gum base, sorbitol, xylitol, one or more plasticizer(s), and one or more anticaking agent(s).
Owner:EJP PHARMA APS

Fluorinated dye stabilizers in fluorinated dielectric solvent

The present invention is directed to novel fluorinated dye stabilizers having both high quenching efficiency and solubility in halogenated solvents. These dye stabilizers have shown a significantly effect on improving the dye fastness in hostile photooxidation conditions.
Owner:E INK CALIFORNIA

Catalytic process for the treatment of organic compounds

A process for the catalytic reaction of organic compounds, in which the organic compounds are contacted with a catalyst comprising an interstitial metal hydride, having a reaction surface, to produce a catalyst-organic compound mixture, energy is applied, monatomic hydrogen is produced at the reaction surface of the interstitial metal hydride, and the organic compounds are reacted with the monatomic hydrogen. Reactions accomplished by this process include petroleum hydrocracking and hydrotreating processes. The method's performance can be further enhanced using radio frequency (RF) or microwave energy.
Owner:CARNEGIE MELLON UNIV

Beta-diketiminate ligand sources and metal-containing compounds thereof, and systems and methods including same

The present invention provides metal-containing compounds that include at least one β-diketiminate ligand, and methods of making and using the same. In certain embodiments, the metal-containing compounds include at least one β-diketiminate ligand with at least one fluorine-containing organic group as a substituent. In other certain embodiments, the metal-containing compounds include at least one β-diketiminate ligand with at least one aliphatic group as a substituent selected to have greater degrees of freedom than the corresponding substituent in the β-diketiminate ligands of certain metal-containing compounds known in the art. The compounds can be used to deposit metal-containing layers using vapor deposition methods. Vapor deposition systems including the compounds are also provided. Sources for β-diketiminate ligands are also provided.
Owner:MICRON TECH INC

Magnetic nano-composite for contrast agent, intelligent contrast agent, drug delivery agent for simultaneous diagnosis and treatment, and separation agent for target substance

The present invention relates to water soluble magnetic nanocomposite using an amphiphilic compound. Specifically, the present invention relates to water soluble magnetic nanocomposite which may be not only used as a contrast agent for magnetic resonance imaging (MRI), an intelligent contrast agent for diagnosing cancer characterized by binding a tissue-specific binder ingredient, a drug delivery system for simultaneous diagnosis and treatment by polymerizing or enveloping drugs and binding a tissue-specific binder ingredient, but also used for separating a target substance using magnetism, and a process for preparing the same.
Owner:IND ACADEMIC CORP FOUND YONSEI UNIV

Doped titanium dioxide as a visible and sun light photo catalyst

Methods for preparing and using a photocatalyst are described. The catalyst is prepared by oxidation of a metal salt which has been doped in situ to form a photocatalyst active in visible light. The photocatalyst is used for degrading toxic and irritating compounds and infectious agents.
Owner:ENVIRONMENTAL PROTECTION AGENCY US

Ultrasonic and microwave methods for enhancing the rate of a chemical reaction and apparatus for such methods

The invention relates generally to chemical reactions and processes, and in particular to a method for enhancing the rate of a chemical reaction and to apparatus for carrying out the method. The invention more particularly relates to methods and apparatus which utilize microwave and ultrasonic energy to enhance chemical reaction rates; and in specific instances, the invention relates to methods, processes and apparatus for the synthesis of biodiesel fuels. The methods, processes and apparatus of the invention are useful for the synthesis of biodiesel fuels; and also useful for production of reaction products of esterification and / or transesterification reactions including fatty acid alkyl esters.
Owner:PENN STATE RES FOUND

Precursors for cvd/ald of metal-containing films

Precursors useful for vapor phase deposition processes, e.g., CVD / ALD, to form metal-containing films on substrates. The precursors include, in one class, a central metal atom M to which is coordinated at least one ligand of formula (I):wherein:R1, R2 and R3 are each independently H or ogano moieties; andG1 is an electron donor arm substituent that increases the coordination of the ligand to the central metal atom M;wherein when Ga is aminoalkyl, the substituents on the amino nitrogen are not alkyl, fluoroalkyl, cycloaliphatic, or aryl, and are not connected to form a ring structure containing carbon, oxygen or nitrogen atoms. Also disclosed are ketoester, malonate and other precursors adapted for forming metal-containing films on substrates, suitable for use in the manufacture of microelectronic device products such as semiconductor devices and flat panel displays.
Owner:ENTEGRIS INC

Method for preparing conductive polymer dispersion, conductive polymer material made therefrom and solid electrolytic capacitor using the material

The present invention provides a method for preparing a conductive polymer dispersion, including: adding a conductive compound, a polyanion, and an oxidant to a solvent; and polymerizing the conductive compound with microwaves. The present invention further provides a conductive polymer material made from the conductive polymer dispersion and a solid electrolyte capacitor using the conductive polymer material. Compared to a conventional method, the conductive polymer is prepared by the method of the present invention in a shorter time and environmental friendly. Moreover, the conductive polymer material made from the dispersion exhibits a high conductivity.
Owner:FAR EASTERN NEW CENTURY COPRRATION

Microwave-based recovery of hydrocarbons and fossil fuels

Disclosed are methods for microwave-based recovery of hydrocarbons from fossil fuels, plastics, tires, drilling fluids, and other carbon-containing compositions. Also disclosed are associated apparatuses.
Owner:GORTRAGH DEV

Precursor compositions for atomic layer deposition and chemical vapor deposition of titanate, lanthanate, and tantalate dielectric films

Barium, strontium, tantalum and lanthanum precursor compositions useful for atomic layer deposition (ALD) and chemical vapor deposition (CVD) of titanate thin films. The precursors have the formula M(Cp)2, wherein M is strontium, barium, tantalum or lanthanum, and Cp is cyclopentadienyl, of the formula (I), wherein each of R1-R5 is the same as or different from one another, with each being independently selected from among hydrogen, C1-C12 alkyl, C1-C12 amino, C6-C10 aryl, C1-C12 alkoxy, C3-C6 alkylsilyl, C2-C12 alkenyl, R1R2R3NNR3, wherein R1, R2 and R3 may be the same as or different from one another and each is independently selected from hydrogen and C1-C6 alkyl, and pendant ligands including functional group(s) providing further coordination to the metal center M. The precursors of the above formula are useful to achieve uniform coating of high dielectric constant materials in the manufacture of flash memory and other microelectronic devices.
Owner:ENTEGRIS INC

Rutile titanium dioxide nanoparticles each having novel exposed crystal face and method for producing same

Provided are: novel rutile titanium dioxide nanoparticles each having a high photocatalytic activity; a photocatalyst including the rutile titanium dioxide nanoparticles; and a method for oxidizing an organic compound using the photocatalyst. The rutile titanium dioxide nanoparticles each have an exposed crystal face (001). The rutile titanium oxide nanoparticles may be produced by subjecting a titanium compound to a hydrothermal treatment in an aqueous medium in the presence of a hydrophilic polymer. A polyvinylpyrrolidone, for example, is used as the hydrophilic polymer. An organic compound having an oxidizable moiety can be oxidized with molecular oxygen or a peroxide under photoirradiation in the presence of the photocatalyst including the rutile titanium oxide nanoparticles.
Owner:DAICEL CHEM IND LTD

Plasma reactor for carrying out gas reactions and method for the plasma-supported reaction of gases

A device for carrying out gas reactions, comprising a plasma reactor with a through-flow of gases which has a, particularly cylindrical, plasma chamber, wherein flow-forming elements for forming a flow of gases are arranged before and / or in and / or after the plasma reactor in order to form a gas stream within the plasma chamber such that at least one, particularly central, zone in the gas flow is formed which is flow-reduced. A method for carrying out gas reactions is also provided.
Owner:IPLAS

Organic electrolysis reactor for performing an electrolytic oxidation reaction and method for producing a chemical compound by using the same

Disclosed is an organic electrolysis reactor for performing an electrolytic oxidation reaction of a system comprising a substrate and a reductant, comprising: a casing; an anode which comprises an anode active material and which is ion-conductive or active species-conductive; a cathode which comprises a cathode active material and which is ion-conductive or active species-conductive; and means for applying a voltage between the anode and the cathode, wherein the means for applying a voltage is disposed in the outside of the casing and connected to the anode and the cathode, wherein the anode and the cathode are disposed in spaced relationship in the casing to partition the inside of the casing into an intermediate compartment between the anode and the cathode, and an anode compartment on the outside of the anode. Also disclosed is a method for producing a chemical compound by performing an electrolytic oxidation reaction of a system comprising a substrate and a reductant, using the organic electrolysis reactor mentioned above.
Owner:ASAHI KASEI KK
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