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Method for recycling waste liquor of zinc plating using potassium salt in laboratory

A galvanizing waste liquid and laboratory technology, applied in chemical instruments and methods, water/sewage multi-stage treatment, water/sludge/sewage treatment, etc., can solve environmental pollution, soil, animal pollution, and cannot be recycled And other issues

Inactive Publication Date: 2012-06-06
SHANDONG JIANZHU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Cu was added to the laboratory potash salt galvanizing process experiment 2+ and Cr 6+ Interfering ions, cannot be recycled
However, it contains heavy metal ions, which will pollute the environment if discharged directly
However, there is no sewage treatment station for centralized treatment of waste liquid containing heavy metal ions in the school
Moreover, the amount of waste liquid in the laboratory is not very large, and it is generally discharged directly into the sewer, but this will also pollute the soil, animals, etc., and waste some of the reusable resources.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] Take 1L galvanizing waste solution, add 3mLH 2 o 2 After adding 3 g of activated carbon for treatment, cool to 0° C., and filter to obtain 20 g of solid boric acid. Add 70 mg NaHSO to the filtrate 3 And 300mgNaOH solid, filter out the precipitate, and bury it deeply. The filtered solution was distilled to obtain 0.85 L of distilled water.

Embodiment 2

[0017] Take 1.5L galvanizing waste liquid, add 6mLH 2 o 2 After adding 7 g of activated carbon for treatment, cool to 5° C., and filter to obtain 28 g of solid boric acid. Add 110 mg NaHSO to the filtrate 3 And 450mgNaOH solid, filter out the precipitate, and bury it deeply. The filtered solution was distilled to obtain 1.3 L of distilled water.

Embodiment 3

[0019] Take 2L galvanizing waste solution, add 10mLH 2 o 2 After adding 10 g of activated carbon for treatment, cool to 10° C., and filter to obtain 35 g of solid boric acid. Add 150 mg NaHSO to the filtrate 3 And 550mgNaOH solid, filter out the precipitate, and bury it deeply. The filtered solution was distilled to obtain 1.9 L of distilled water.

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PUM

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Abstract

The invention discloses a method for recycling waste liquor of zinc plating using potassium salt in a laboratory and relates to the field of comprehensive utilization of waste liquor in the field of plating. The method comprises the following steps of: adding hydrogen peroxide and activated carbon into the waste liquor to remove organic impurities from the waste liquor; then reducing the temperature of the solution by using a refrigeration sheet, and filtering out solid in the solution; adding NaOH solid and NaHSO3 into the solution; precipitating heavy metal elements in the solution out through chemical reaction; and finally distilling to obtain distilled water. By the method, recoverable substances, such as distilled water, boric acid and the like in the waste liquor can be recycled, and unrecoverable substances, such as heavy metal ions (Cu<2+> and Cr<3+>) are subjected to innocent treatment by a deep burying method. The invention provides a simple and practical method, by which resources can be effectively recycled and pollution can be reduced, for treating the waste liquor of zinc plating using potassium salt in the laboratory.

Description

technical field [0001] The invention relates to a method for recycling laboratory potassium salt galvanizing waste liquid, and mainly discusses the function and operation method of the method. Background technique [0002] Now environmental problems are becoming more and more prominent, pollution is becoming more and more serious, and the harm of heavy metal ions is particularly serious, which must be paid attention to. Cu was added to the laboratory potash salt galvanizing process experiment 2+ and Cr 6+ Interfering ions cannot be recycled. However, it contains heavy metal ions, which will pollute the environment if discharged directly. However, there is no sewage treatment station for centralized treatment of waste liquid containing heavy metal ions in the school. Moreover, the amount of waste liquid in the laboratory is not very large, and it is generally discharged directly into the sewer, but this will also pollute the soil, animals, etc., and waste some of the reus...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/10
Inventor 刘科高商广旭许斌石磊
Owner SHANDONG JIANZHU UNIV