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Catalytic conversion method for producing diesel and propylene in high yield

A catalytic conversion method, diesel technology, applied in the field of catalytic conversion of high cetane number diesel oil and propylene, can solve the problems of improving the properties of diesel oil, poor selectivity of dry gas and coke, etc.

Active Publication Date: 2011-05-11
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] CN1900226A discloses a catalytic cracking co-catalyst and its preparation method for prolific diesel oil production. Adding a certain amount of the co-catalyst can increase the diesel yield of the FCC catalytic unit and improve Product distribution, but the method does not mention improvement in diesel properties
It has been found through research that although these fine particle catalysts have high cracking capacity, their selectivity to dry gas and coke is poor. Optimizing the sieve composition of the catalyst can improve the selectivity of dry gas and coke

Method used

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  • Catalytic conversion method for producing diesel and propylene in high yield
  • Catalytic conversion method for producing diesel and propylene in high yield

Examples

Experimental program
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Embodiment

[0101] This embodiment is tested according to the flow process of accompanying drawing, and cracked raw material oil is directly used as the raw material of catalytic cracking, adopts catalyst CAT-MP-2, carries out test on the medium-sized device of riser reactor, and cracked raw material enters the middle and upper part of reaction zone I, Cracking raw materials at a reaction temperature of 530°C and a weight hourly space velocity of 35h -1 , the weight ratio of catalytic cracking catalyst to raw material is 4, and the cracking reaction is carried out under the condition that the weight ratio of water vapor to raw material is 0.15. In the cracking reaction, the oil gas and the catalyst to be charred are separated in the settler, and the products are cut according to the distillation range in the separation system, so as to obtain propylene, butene, gasoline, diesel and catalytic wax oil fractions. The catalytic wax oil is sent to the hydrotreating unit for treatment, at a hyd...

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Abstract

The invention discloses a catalytic conversion method for producing diesel and propylene in high yield. Raw oil is contacted with a catalyst in coarse particle size distribution in a reactor for reaction, the reaction temperature, weight hourly space velocity, and the weight ratio of the catalyst to the raw oil sufficiently ensures that a reaction product comprising catalytic wax oil which is 12 to 60 weight percent of the raw oil is obtained in the reaction, and the catalytic wax oil enters a hydrotreater for further treatment. The catalytic cracking, hydrotreating and a process of producing diesel in high yield are integrated, hydrocarbons such as alkane, alkyl side chain and the like in the raw material are selectively subjected to cracking and isomerization catalysis, aromatic hydrocarbon in the raw material is reduced to the greatest extent to enter diesel fraction, other components in the product are prevented from generating aromatic hydrocarbon through aromatization and other reaction so as not to remain the aromatic hydrocarbon in the diesel fraction, the raw material is converted into high cetane number diesel and propylene, the yield of dry gas and coke is greatly reduced, and the catalyst breaking trend and catalyst consumption are reduced.

Description

technical field [0001] The invention belongs to the catalytic conversion method of hydrocarbon oil in the absence of hydrogen, more specifically, it is a catalytic conversion method for converting heavy feedstock into high cetane number diesel oil and propylene. Background technique [0002] At present, the global demand for high-quality gasoline is increasing day by day, and the technology for producing high-quality gasoline is developing rapidly, while the technology for producing high-cetane diesel is developing relatively slowly. Although the demand for gasoline and diesel varies from region to region, overall, the growth rate of global demand for diesel will gradually exceed the growth rate of demand for gasoline. The cetane number of diesel produced by traditional catalytic cracking process is relatively low, so it is often used as a blending component of diesel. In order to meet the demand of high-quality diesel oil, it is necessary to upgrade the catalytic light die...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G69/04C10G55/06C10G11/05C07C11/06
CPCY02P20/52
Inventor 崔守业许友好胡志海陈昀董建伟马建国
Owner CHINA PETROLEUM & CHEM CORP
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