Liquid electrophotographic ink with a charge director system
A technology of liquid electrophotography and charge director, which can be used in inks, developers, household appliances, etc., and can solve problems such as printing defects
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Embodiment 1
[0047] Example 1 – Preparation of liquid electrophotographic (LEP) inks
[0048] Several LEP inks use alkaline Barium Petronate (LT); Ba[(C 13 h 27 )-O-C(O)CH 2 CH(SO 3 - )C(O)-O-(C 13 h 27 )] 2 and BaHPO 4( SCD); isopropylamine dodecylbenzenesulfonate (GT); light isoparaffinic oil (ISOPAR® L, Exxon Mobile); ethylene acrylic acid copolymer, ethylene methacrylic acid copolymer; and Cabot monarch 800 to prepare. The percentages of LT, SCD and GT for different inks are shown in Table 1.
[0049] Table 1
[0050] Charged System No.
SCD
LT
GT
1
0.04
0.1
0.06
2
0.02
0.1
0.06
3
0.01
0.1
0.06
4
0.04
0.08
0.06
5
0.04
0.06
0.04
6
0.04
0.04
0.06
7
0.04
0.1
0.04
8
0.04
0.1
0.02
9
0.04
0.1
0.01
10
0.02
0.08
0.04
11
0.04
0.14
0.06
12
0.03
0.1
0.08
13
0.05
0.08
0.0...
Embodiment 2
[0054] Example 2 – Conductivity of LEP ink
[0055] During preparation, the conductivity of the LEP ink of Example 1 was tested after 3 hours and 18 hours of electrophorhetic mobility. The results are shown in Table 2.
[0056]
Embodiment 3
[0057] Example 3 – Evaluation of LEP Ink No.11
[0058] The LEP ink No. 11 of Example 1 was further evaluated for streak performance. The SCD / LT / GT ratio of LEP Ink No. 11 was slightly changed to provide two additional LEP inks (11a and 11b). In addition, a comparative LEP ink without the charge director system of the present invention was used as indicated by the SCD / LT / GT ratio. All inks were formulated according to the composition of LEP Ink No. 11 except for the ratio of SCD / LT / GT shown. Table 3 shows the obtained conductivity before and after printing.
[0059] table 3
[0060]
[0061] LT – Alkaline Barium Petronate;
[0062] SCD-Ba[(C 13 h 27 )-O-C(O)CH 2 CH(SO 3 - )C(O)-O-(C 13 h 27 )] 2 and BaHPO 4 ;
[0063] GT-dodecylbenzenesulfonic acid isopropylamine salt
[0064] As shown in Table 3, LEP inks No. 11, 11a and 11b achieved a low-field conductivity of at least 20 pS / cm, while the comparative ink did not. The LEP inks are stable after printing...
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