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Method for preparing vanadium liquid

A technology of vanadium liquid and base liquid, which is applied in the direction of regenerative fuel cells, etc., can solve the problems of low power storage capacity, low capacity ratio of vanadium liquid, and low economic benefits, and achieve high energy, high molar number, and high cost performance.

Active Publication Date: 2012-10-03
TIANJIN BINHAI ENERGY STORAGE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The traditional vanadium solution preparation method is based on sulfuric acid, adding oxalic acid or hydrochloric acid as a stabilizer to the sulfuric acid. The vanadium solution prepared in this way has a low capacity ratio (up to 1.9 mol). , low power storage capacity, low economic benefits, seriously restricting the development of vanadium battery industry

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] B: Heating the reaction kettle, and putting the vanadium pentoxide which is 9.84% of the total weight ratio of the vanadium liquid to be prepared and the sulfuric acid of 38.52% by weight into the hydrochloric acid by a stirring device The above-mentioned mixed solution is stirred at a speed of 60 to 80 rpm, and the reactor is continuously heated while stirring;

[0047] C: Gradually add oxalic acid whose weight accounts for 12.3% of the total weight ratio of the vanadium liquid to be prepared into the mixed solution in the step B, while maintaining the stirring device to stir the above mixed solution at a speed of 60 to 80 rpm , while stirring, continue to heat the reactor until the temperature of the mixed solution in the reactor is 80 degrees Celsius;

[0048] D: After adding the above-mentioned substances, when the constant temperature is 80 degrees Celsius, the mixed solution is continuously stirred at a speed of 60 to 80 rpm for 1.5 hours;

[0049] E: Stop stirri...

Embodiment 2

[0053]B: Heating the reaction kettle, and putting the vanadium pentoxide that the weight accounts for 10% of the total weight ratio of the vanadium liquid to be prepared and the sulfuric acid that is 37% of the total weight ratio of the vanadium liquid to be prepared into hydrochloric acid, and simultaneously passes through the stirring device The above-mentioned mixed solution is stirred at a speed of 60 to 80 rpm, and the reactor is continuously heated while stirring;

[0054] C: Gradually add oxalic acid whose weight accounts for 13% of the total weight ratio of the vanadium solution to be prepared into the mixed solution in the step B, while maintaining the stirring device to stir the above mixed solution at a speed of 60 to 80 rpm , while stirring, continue to heat the reactor until the temperature of the mixed solution in the reactor is 80 degrees Celsius;

[0055] D: After adding the above-mentioned substances, when the constant temperature is 80 degrees Celsius, the mi...

Embodiment 3

[0060] B: Heating the reaction kettle, and putting the vanadium pentoxide and the sulfuric acid that accounts for 8% of the total weight ratio of the vanadium liquid to be prepared into the hydrochloric acid with a weight of 40% of the total weight ratio of the vanadium liquid to be prepared, and simultaneously passes through the stirring device The above-mentioned mixed solution is stirred at a speed of 60 to 80 rpm, and the reactor is continuously heated while stirring;

[0061] C: Gradually add oxalic acid whose weight accounts for 7% of the total weight ratio of the vanadium solution to be prepared into the mixed solution in the step B, while maintaining the stirring device to stir the above mixed solution at a speed of 60 to 80 rpm , while stirring, continue to heat the reactor until the temperature of the mixed solution in the reactor is 80 degrees Celsius;

[0062] D: After adding the above-mentioned substances, when the constant temperature is 75 degrees Celsius, the m...

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PUM

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Abstract

The invention relates to a method for preparing vanadium liquid with high capability ratio, wherein the mole number of the vanadium liquid is not less than 2.8. According to the method for preparing vanadium liquid, hydrochloric acid of which the weight is 37-47% of the total weight of the vanadium liquid to be prepared is taken as a base solution, and sulfuric acid of which the weight is 33-43% of total weight of the vanadium liquid to be prepared and oxalic acid of which the weight is 5-17% of total weight of the vanadium liquid to be prepared are taken as auxiliary additive solutions. The vanadium liquid prepared by the technical scheme is high in energy, high in mole number and high in cost performance.

Description

【Technical field】 [0001] The invention relates to a preparation method of vanadium liquid, in particular to a preparation method of high capacity ratio vanadium liquid whose molar number is not less than 2.8. 【Background technique】 [0002] The traditional vanadium solution preparation method is based on sulfuric acid, adding oxalic acid or hydrochloric acid as a stabilizer to the sulfuric acid. The vanadium solution prepared in this way has a low capacity ratio (up to 1.9 mol). , low power storage capacity, and low economic benefits have seriously restricted the development of the vanadium battery industry. 【Content of invention】 [0003] In order to solve the technical problems in the prior art, the invention provides a method for preparing vanadium liquid with a molar number not lower than 2.8 and a high capacity ratio. [0004] The technical solution adopted by the present invention to solve the problems in the prior art is to provide a method for preparing vanadium l...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M8/18
CPCY02E60/528Y02E60/50
Inventor 郑役军郑东冬
Owner TIANJIN BINHAI ENERGY STORAGE TECH