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Technology for continuously producing nitrocompound fertilizer by using low-grade phosphorus ore and dolomite

Through the continuous process of low-grade phosphate rock and dolomite, combined with high-tower granulation technology, high-efficiency nitro compound fertilizer is made, which solves the problem of lack of nitrate nitrogen and calcium and magnesium in compound fertilizer production and achieves environmental protection and low cost. The production of compound fertilizers improves product uniformity and dissolution speed to meet the nutrient needs of crops.

Active Publication Date: 2013-11-06
SICHUAN GOLDEN ELEPHANT SINCERITY CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Domestic enterprises that use phosphate rock to produce ammonium nitrophosphate have a lot of waste solids and waste gas, which are difficult to deal with, cause great environmental pollution, and have high requirements for the grade of phosphate rock and high production costs.
Moreover, domestic phosphate rock resources are increasingly scarce, and domestic phosphate rock resources are decreasing day by day. In particular, high-grade phosphate rock needs to be imported, and a large number of low-grade phosphate rock cannot be used by many enterprises. Compared with granulation, the uniformity of product nutrients is poor and the dissolution rate is slow

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The production ratio is N+P 2 o 5 +K 2 O≥20+5+0, Ca≥8, Mg≥2 formula compound fertilizer.

[0026] Calculated according to the production of one ton of compound fertilizer batching reaction production:

[0027] Take 250Kg of phosphate rock, add no more than 35Kg of water for wetting, then add 40Kg of concentrated sulfuric acid with an appropriate fraction of 98% for reaction, and recover and treat the tail gas after the reaction. After about 2 hours, add 160Kg of dolomite, and add no more than 15Kg After about 1 hour, use a pulverizer to crush, then add an appropriate amount of ammonium phosphate, send it to the granulation tower with a bucket elevator, heat the mixture to nearly 80°C, add ammonium nitrate solution in proportion, and control the reaction temperature. 140°C, at this time, the viscosity of the slurry is suitable. It is granulated by a granulator, convected with the air, shrinks into round particles in the tower and falls, collects and cools, and adds an...

Embodiment 2

[0030] The production ratio is N+P 2 o 5 +K 2 O≥20+5+0, Ca≥6 formula compound fertilizer. According to the production of one ton of compound fertilizer batching reaction production:

[0031] Take 350Kg of phosphate rock, add no more than 45Kg of water to moisten it, then add 40Kg of concentrated sulfuric acid to react, recover and treat the tail gas, and discharge the waste gas. After about 2 hours, use a pulverizer to crush it, add an appropriate amount of ammonium phosphate, and send it to Go to the granulation tower, heat the mixture to nearly 80°C, add ammonium nitrate solution in proportion to control the reaction temperature to 150°C, at this time the viscosity of the slurry is appropriate, use a granulator to granulate, form convection with the air, and shrink in the tower Fall into round particles, collect and cool, add anti-caking oil and anti-caking powder, and pack the finished product. The mass percent content of detected N was 20.52%, P 2 o 5 The mass percen...

Embodiment 3

[0033] The production ratio is N+P 2 o 5 +K 2 O≥20+10+0, Ca≥7, Mg≥2 formula compound fertilizer.

[0034] According to the production of one ton of compound fertilizer batching reaction production:

[0035] Take 100Kg of phosphate rock, add no more than 35Kg of water to moisten it, add 40Kg of concentrated sulfuric acid to react, and recover and treat the tail gas. After about 2 hours, add 160Kg of dolomite, add no more than 15Kg of water to moisten it, and after about 1 hour, crush it with a pulverizer, add An appropriate amount of ammonium phosphate is sent to the granulation tower with a bucket elevator, the mixture is heated to nearly 80°C, and ammonium nitrate solution is added in proportion to control the reaction temperature at 160°C. The viscosity of the slurry is suitable, and the granulator granulates to form convection with the air , shrink into round particles in the tower and fall, collect and cool, add anti-caking oil and anti-caking powder, and pack the finis...

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Abstract

The invention relates to the fertilizer production device field, and is a technology for producing high efficiency nitrocompound fertilizer with low price and easy raw material acquisition, especially relates to a technology by using low-grade phosphorus ore and abundant mineral product dolomite, and concretely relates to the technology for continuously producing nitrocompound fertilizer by using low-grade phosphorus ore and dolomite. According to the technology, phosphorus ore and dolomite extracted by using sulfur to obtain effective phosphor and water-soluble calcium magnesium, a proper amount of monoammonium phosphate is added, and is reacted with melted ammonium nitrate, and is granulated in a high tower to produce the compound fertilizer. The method employs seven steps combination of performing phosphor extraction, performing calcium magnesium extraction, pulverizing, burdening, melting, granulating and cooling. According to the invention, low-grade phosphorus ore is selected for solving the problem of difficult usage of low-grade phosphorus ore, the product contains macroelements nitrogen and phosphor required by the crops, and contains three secondary elements calcium magnesium sulfur required by the growth of the crops as well as a part of trace elements, and the high tower granulation can ensure the full reaction and uniform mixing of various substances.

Description

technical field [0001] The invention relates to the field of chemical fertilizer production equipment. It is a low-cost and easy-to-obtain raw material to produce high-efficiency nitro compound fertilizer. In particular, it uses low-grade phosphate rock and mineral-rich dolomite. Process for continuous production of nitro-compound fertilizers from high-grade phosphate rock and dolomite. Background technique [0002] At present, the compound fertilizers produced by most domestic enterprises do not contain nitrate nitrogen and the content of calcium and magnesium is not up to the standard. The compound fertilizers produced in developed countries are mainly nitro fertilizers. Farmers often add calcium and magnesium fertilizers as base fertilizers, and the compound fertilizers contain nitrate nitrogen. And calcium and magnesium elements are the development trend of soil testing formula fertilization. Domestic enterprises that use phosphate rock to produce ammonium nitrophospha...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C05G1/00C05G5/00
Owner SICHUAN GOLDEN ELEPHANT SINCERITY CHEM CO LTD