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Linear precipitated polymer

A technology of polymers and mixtures, applied in the field of precipitation polymers, which can solve problems such as incompatibility, unsatisfactory thickening effect of thickeners, and increased molecular weight of polymers

Inactive Publication Date: 2012-11-07
BASF AG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the use of known thickeners often has disadvantages, depending on the field of application of the formulation to be thickened
Thus, the thickening action of the thickener may be unsatisfactory, its use may be unnecessary, or it may be difficult or impossible to introduce into the preparation to be thickened, for example because of its interaction with the compound to be thickened. incompatibility between
Another disadvantage that is usually caused when using polymers as thickeners for the production of higher viscosity or gel-like formulations is that the molecular weight of the polymer increases so that its incorporation becomes generally more difficult and in the end usually only observation to the swelling of the polymer, rather than the desired dissolution

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 5

[0387] The preparation of the copolymer of Example 5 is described here as an example:

[0388] Poly ( 6877O) 50 / 5 / 35 / 10 (weight ratio))

[0389] Initial charge: 412 g butyl acetate

[0390] 0.15g 101

[0391] Feed 1: 75 g vinylpyrrolidone

[0392] 7.5g vinylimidazole

[0393] 52.5g acrylic acid

[0394] 15.0g 6877O

[0395] Feed 2: 40 g butyl acetate

[0396] 0.10g tert-butyl peroctoate

[0397] Feed 3: 100 g butyl acetate

[0398] 0.15g tert-butyl peroctoate

[0399] 0.10g 101

[0400] Feed 1 and Feed 2 were added to a stirred apparatus with reflux condenser, internal thermometer and four feeding devices at 87-88°C over 2 hours. The reaction mixture was stirred for an additional 3 hours at about 88°C. Feed 3 was metered in within 30 minutes, and the resulting mixture was stirred at 90° C. for a further 3 hours. Then, the reaction mixture was post-polymerized at 120° C. for 2 hours. After cooling to about...

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Abstract

The present invention relates to precipitation polymers obtainable by polymerization of a monomer mixture which comprises a) 30 to 99% by weight of at least one nonionic water-soluble monomer and b) at least one monomer that is different from a) and is selected from i) monomers carrying at least one hydroxyl group, ii) anionic monomers and iii) mixtures of i) and ii), and c), if appropriate, a monomer carrying at least one amino group or, if appropriate, further monomers, wherein the total amount of a), b), c) and d) is 100% by weight and the monomer mixture, based on the total amount of a), b), c) and d), comprises less than 0.1% by weight of a monomer with at least two free-radically polymerizable double bonds per molecule. The invention furthermore relates to the use of these polymers as rheology modifiers for aqueous compositions, to aqueous compositions comprising these polymers and to the use of the polymers for thickening cosmetic and pharmaceutical preparations.

Description

[0001] This application is a divisional application of Chinese patent application 200980107297.9. The filing date of this Chinese patent application is January 28, 2009, and the title of the invention is "linear precipitation polymer". field of invention [0002] The invention relates to a precipitation polymer obtainable by polymerization of a monomer mixture containing: 30-99% by weight of at least one nonionic, water-soluble monomer a); at least one different from a) and selected from i) monomers bearing at least one hydroxyl group, ii) anionic monomers and iii) monomers in mixtures of i) and ii); optionally, monomers c) bearing at least one amino group; any Optionally, other monomers, wherein the total amount of a), b), c) and d) is 100% by weight, and wherein the monomer mixture contains less than 0.1% by weight of monomers having at least two free-radically polymerizable double bonds per molecule. The invention also relates to the use of these polymers as rheology modif...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F226/10C08F226/06C08F220/06C08F220/28A61K8/81
CPCC08F226/06
Inventor S·源金I·法斯特
Owner BASF AG
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