Linear precipitated polymer
A technology of polymers and mixtures, applied in the field of precipitation polymers, which can solve problems such as incompatibility, unsatisfactory thickening effect of thickeners, and increased molecular weight of polymers
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Embodiment 5
[0387] The preparation of the copolymer of Example 5 is described here as an example:
[0388] Poly ( 6877O) 50 / 5 / 35 / 10 (weight ratio))
[0389] Initial charge: 412 g butyl acetate
[0390] 0.15g 101
[0391] Feed 1: 75 g vinylpyrrolidone
[0392] 7.5g vinylimidazole
[0393] 52.5g acrylic acid
[0394] 15.0g 6877O
[0395] Feed 2: 40 g butyl acetate
[0396] 0.10g tert-butyl peroctoate
[0397] Feed 3: 100 g butyl acetate
[0398] 0.15g tert-butyl peroctoate
[0399] 0.10g 101
[0400] Feed 1 and Feed 2 were added to a stirred apparatus with reflux condenser, internal thermometer and four feeding devices at 87-88°C over 2 hours. The reaction mixture was stirred for an additional 3 hours at about 88°C. Feed 3 was metered in within 30 minutes, and the resulting mixture was stirred at 90° C. for a further 3 hours. Then, the reaction mixture was post-polymerized at 120° C. for 2 hours. After cooling to about...
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