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Digital printing binding agent, preparation method and applications of digital printing binding agent

A digital printing and adhesive technology, which is applied in dyeing, textiles and papermaking, etc., can solve problems such as configuration troubles, residual pulp cannot be reused, and viscosity increase, so as to improve adhesion and product color fastness, and application Effects with a wide range and application methods and various application methods

Inactive Publication Date: 2014-05-21
CHINA TEXTILE ACAD JIANGNAN BRANCH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this kind of low-temperature adhesive has poor stability, and the storage time is not long. The moisture of this adhesive evaporates quickly, and it is easy to cross-link to form a film at room temperature, resulting in an increase in the viscosity of the entire system, which leads to printing. Blocking phenomenon, people sometimes add some humectant to the printing paste system, but new problems follow, because if the humectant will affect the wet rubbing fastness of the fabric
[0005] The second type is some adhesives with external catalysts, that is, A+B two-component, where A is the catalyst and B is the adhesive. Through the catalysis of A, B can complete cross-linking and curing at low temperature. The disadvantage is that The configuration is troublesome, and the stability of the preparation is not good, and the residual pulp cannot be reused
[0006] The third type of low-temperature adhesives mainly uses radiation-induced crosslinking technology to synthesize low-temperature adhesives, but the cost is relatively high, and it is difficult to popularize.
Although the above-mentioned low-temperature adhesives meet the requirements of polylactic acid fabrics in terms of baking temperature, they are far from meeting the requirements of digital printing systems, such as compatibility with paint inks, maintaining the wettability and smoothness of digital printing machine nozzles. properties, self-dispersion, particle size distribution, etc.

Method used

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  • Digital printing binding agent, preparation method and applications of digital printing binding agent
  • Digital printing binding agent, preparation method and applications of digital printing binding agent
  • Digital printing binding agent, preparation method and applications of digital printing binding agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] (1) Preparation of low-temperature self-crosslinking resin: the formula of low-temperature self-crosslinking resin is shown in Table 1.

[0043] Table 1. Low temperature self-crosslinking resin formula (by weight percentage)

[0044]

[0045] Preparation method: first add polydimethylsiloxane emulsion into the reaction kettle, then add low-temperature cross-linking monomer, emulsifier, deionized water, and 1 / 3 of methyl acrylate, stir for half an hour, and heat up to 50°C Carry out polymerization to obtain a core / shell emulsion polymer, then add water-based polyurethane prepolymer, add 2 / 3 of the potassium persulfate initiator dropwise at a rate of 2 hours, raise the temperature to 70°C for 2 hours after the dropwise addition, and then within 1 hour Add the remaining 2 / 3 of methyl acrylate and 1 / 3 of the potassium persulfate initiator, raise the temperature to 75°C and keep it warm for 3 hours. After the reaction is completed, neutralize it with triethanolamine to fo...

Embodiment 2

[0052] (1) Preparation of low-temperature self-crosslinking resin: the formula of low-temperature self-crosslinking resin is shown in Table 3.

[0053] Table 3. Low temperature self-crosslinking resin formula (by weight percentage)

[0054]

[0055] Preparation method: first add polydimethylsiloxane emulsion into the reaction kettle, then add low-temperature crosslinking monomer, emulsifier, deionized water, and 1 / 3 ethyl acrylate, stir for half an hour, and heat up to 60°C Carry out polymerization to obtain a core / shell emulsion polymer, then add water-based polyurethane prepolymer, add 2 / 3 of the ammonium persulfate initiator dropwise at a rate of 1.5h, raise the temperature to 70°C for 2 hours after the dropwise addition, and then in 1h Add the remaining 2 / 3 of ethyl acrylate and 1 / 3 of the ammonium persulfate initiator, raise the temperature to 75°C and keep it warm for 3 hours. After the reaction is completed, neutralize it with triethanolamine to form a three-layer po...

Embodiment 3

[0062] (1) Preparation of low-temperature self-crosslinking resin: the formula of low-temperature self-crosslinking resin is shown in Table 5.

[0063] Table 5. Low temperature self-crosslinking resin formula (by weight percentage)

[0064]

[0065] Preparation method: first add polydimethylsiloxane emulsion into the reaction kettle, then add low-temperature crosslinking monomer, emulsifier, deionized water, and 1 / 3 glycidyl methacrylate, stir for half an hour, Raise the temperature to 60°C for polymerization to obtain a core / shell emulsion polymer, then add water-based polyurethane prepolymer, add 2 / 3 of the azobisisobutylcyanide initiator dropwise at a rate of 1 hour, and then raise the temperature to 70°C for reaction After 3 hours, add the remaining glycidyl methacrylate and the remaining 1 / 3 of the azobisisobutyrocyanide initiator within 1.5 hours, raise the temperature to 75°C and keep it warm for 3 hours. After the reaction is completed, use triethanolamine And, a t...

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Abstract

The invention discloses a digital printing binding agent, a preparation method and applications of the digital printing binding agent. The digital printing binding agent is characterized by comprising the following components by weight percent: 40%-50% of low-temperature self-crosslinking resin, 5%-10% of surface active agent, 5%-15% of dispersing agent, 10%-20% of polyhydric alcohols and the balance of deionized water. The digital printing binding agent disclosed by the invention does not contain APEO (Alkylphenol Ethoxylates), formaldehyde, degradation-resistant compound and the like, and is environment-friendly and pollution-free; according to the digital printing binding agent, the stability and the dispersion are good, pigment particles can be prevented from coagulation, and the digital printing binding agent is baked to be subjected to film formation and crosslinking under low temperature, so that the energy consumption and sewage discharging amount are lowered greatly; and the digital printing agent can be applied to the digital printing of polylactic acid fiber fabric, so that the good printing color fastness and the soft handfeeling can be obtained.

Description

Technical field: [0001] The invention relates to a digital printing adhesive, more specifically, a digital printing adhesive, a preparation method and its application, and belongs to the technical field of textile chemistry. Background technique: [0002] In the paint digital inkjet printing process, the development of paint ink is very important, and the key technology is the research and development of paint ink binder (the nature of the general binder determines the temperature of fabric baking). The quality of the adhesive directly affects the feel, color and color fastness of the fabric. The residual quality of adhesives used for pigment digital printing in the market is uneven, and there are common problems such as poor water resistance of film formation, poor hand feeling, cold and brittle hot stickiness, etc. At the same time, these adhesives need to be baked at high temperature. is unfavorable. Polylactic acid fiber is obtained from grains, and its products can be...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06P1/52D06P1/651
Inventor 贾佳崔桂新张孝南王尧峰
Owner CHINA TEXTILE ACAD JIANGNAN BRANCH