Digital printing binding agent, preparation method and applications of digital printing binding agent
A digital printing and adhesive technology, which is applied in dyeing, textiles and papermaking, etc., can solve problems such as configuration troubles, residual pulp cannot be reused, and viscosity increase, so as to improve adhesion and product color fastness, and application Effects with a wide range and application methods and various application methods
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Embodiment 1
[0042] (1) Preparation of low-temperature self-crosslinking resin: the formula of low-temperature self-crosslinking resin is shown in Table 1.
[0043] Table 1. Low temperature self-crosslinking resin formula (by weight percentage)
[0044]
[0045] Preparation method: first add polydimethylsiloxane emulsion into the reaction kettle, then add low-temperature cross-linking monomer, emulsifier, deionized water, and 1 / 3 of methyl acrylate, stir for half an hour, and heat up to 50°C Carry out polymerization to obtain a core / shell emulsion polymer, then add water-based polyurethane prepolymer, add 2 / 3 of the potassium persulfate initiator dropwise at a rate of 2 hours, raise the temperature to 70°C for 2 hours after the dropwise addition, and then within 1 hour Add the remaining 2 / 3 of methyl acrylate and 1 / 3 of the potassium persulfate initiator, raise the temperature to 75°C and keep it warm for 3 hours. After the reaction is completed, neutralize it with triethanolamine to fo...
Embodiment 2
[0052] (1) Preparation of low-temperature self-crosslinking resin: the formula of low-temperature self-crosslinking resin is shown in Table 3.
[0053] Table 3. Low temperature self-crosslinking resin formula (by weight percentage)
[0054]
[0055] Preparation method: first add polydimethylsiloxane emulsion into the reaction kettle, then add low-temperature crosslinking monomer, emulsifier, deionized water, and 1 / 3 ethyl acrylate, stir for half an hour, and heat up to 60°C Carry out polymerization to obtain a core / shell emulsion polymer, then add water-based polyurethane prepolymer, add 2 / 3 of the ammonium persulfate initiator dropwise at a rate of 1.5h, raise the temperature to 70°C for 2 hours after the dropwise addition, and then in 1h Add the remaining 2 / 3 of ethyl acrylate and 1 / 3 of the ammonium persulfate initiator, raise the temperature to 75°C and keep it warm for 3 hours. After the reaction is completed, neutralize it with triethanolamine to form a three-layer po...
Embodiment 3
[0062] (1) Preparation of low-temperature self-crosslinking resin: the formula of low-temperature self-crosslinking resin is shown in Table 5.
[0063] Table 5. Low temperature self-crosslinking resin formula (by weight percentage)
[0064]
[0065] Preparation method: first add polydimethylsiloxane emulsion into the reaction kettle, then add low-temperature crosslinking monomer, emulsifier, deionized water, and 1 / 3 glycidyl methacrylate, stir for half an hour, Raise the temperature to 60°C for polymerization to obtain a core / shell emulsion polymer, then add water-based polyurethane prepolymer, add 2 / 3 of the azobisisobutylcyanide initiator dropwise at a rate of 1 hour, and then raise the temperature to 70°C for reaction After 3 hours, add the remaining glycidyl methacrylate and the remaining 1 / 3 of the azobisisobutyrocyanide initiator within 1.5 hours, raise the temperature to 75°C and keep it warm for 3 hours. After the reaction is completed, use triethanolamine And, a t...
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