Double-sided pressure-sensitive adhesive sheet
A technology of pressure-sensitive adhesive sheets and pressure-sensitive adhesives, applied in the direction of pressure-sensitive films/sheets, adhesives, release paper, etc., can solve the problems of poor peeling operability and damage, and achieve excellent peeling operability
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Embodiment 1
[0166] (Preparation of pressure-sensitive adhesive composition)
[0167] 100 parts by weight of butyl acrylate (BA) and 5 parts by weight of acrylic acid (AA) as a monomer component of an acrylic polymer, 0.2 parts by weight of benzoyl peroxide as a polymerization initiator, and 240 parts by weight of toluene as a polymerization solvent Charge to a collapsible flask and stir for two hours while purging with nitrogen. In this way, after removing oxygen from the polymerization system, the temperature was increased to 62° C., and the resultant was reacted for seven hours to obtain an acrylic polymer solution having a solid content concentration of 30 wt %. The weight-average molecular weight (M) of the acrylic polymer w ) is 550,000.
[0168] As shown in Table 1, 30 parts by weight of a phenol-modified rosin-based resin (trade name: "TAMANOL 803L", Manufactured by Arakawa Chemical Industry, Japan, phenolic hydroxyl value: less than 20 mgKOH / g) and 10 parts by weight of terpene...
Embodiment 2
[0174] As shown in Table 1, a double-sided pressure-sensitive adhesive sheet was obtained in the same manner as in Example 1, except that a heat-curable polysiloxane-based release agent [100 parts by weight of the trade name "AST- 8" (manufactured by Japan Arakawa Chemical Industry Co., Ltd.) and 7.3 parts by weight of a product with the trade name "CATA12070" (manufactured by Bluestar Silicones)] was used as the polysiloxane-based release agent.
Embodiment 3
[0176] As shown in Table 1, a double-sided pressure-sensitive adhesive sheet was obtained in the same manner as in Example 1, except that a heat-curable polysiloxane-based release agent [100 parts by weight of trade name "BY24 -4538" (manufactured by Dow Corning Toray Industries, Ltd.) and 10 parts by weight of a product under the trade name "BY24-490" (manufactured by Dow Corning Toray Industries, Ltd.)] was used as the silicone-based peeling agent agent. Here, the blending amount (parts by weight) of "BY24-4538" and "BY24-490" is the total amount of "BY24-4538" and "BY24-490" themselves (actual products) relative to 100 parts by weight of the acrylic polymer. Mixed amount.
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