Hollow ceramic microsphere and preparation method of hollow ceramic microsphere

A technology of hollow ceramics and microspheres, which is applied in the field of hollow ceramic microspheres and its preparation, can solve the problems of high density, cracking of airgel blocks, increase of solid-phase heat transfer, etc., and achieve excellent high temperature performance, high product activity, The effect of low cracking temperature

Inactive Publication Date: 2013-11-13
TIANJIN CHENGJIAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented process describes methods for making small spherules (having diameter between 1-5 mm) containing silicon dioxide microparticles encased within glass or plastic particles called poly(methyl methacrylate). These tiny balls act like mini mirrors on surfaces they hit during use. They help reduce friction while still allowing light transmission through them without losing their ability to reflect back into space around us. Additionally, these techniques allow for precise control over particle size distribution and purity levels. Overall, this technology allows creation of new types of opaque ceramics such as those used in various industries including defense applications where fireproof properties must meet specific requirements.

Problems solved by technology

This patented technical problem addressed in this patents relates to improving thermal insulators made from conventional fibre/porcelain composites while maintaining transparency (transparent) properties without losing them due to damage caused by external factors like weather exposure over prolonged periods.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] A hollow ceramic microsphere is a ceramic ball with a hollow structure, and the hollow ceramic ball is a TiO2-coated SiC core-shell structure. TiO2 has a rutile structure. The diameter of the hollow ceramic ball is Φ1-3um, the hollow size of the hollow structure is Φ1-2um, and the hollow ceramic ball is a core-shell structure of TiO2 coated SiC

Embodiment 2

[0045] A hollow ceramic microsphere is a ceramic ball with a hollow structure, and the hollow ceramic ball is a TiO2-coated SiC core-shell structure. SiC is obtained by sintering ceramic precursors; TiO2 has a rutile structure. The diameter of the hollow structure ceramic ball is Φ1-2um, and the hollow size of the hollow structure is Φ0.8-1.5um. The hollow ceramic microspheres in this example are prepared by using the sacrificial template method first, and then coated with a layer of titanium dioxide infrared covering agent on the surface by the hydrothermal method, and finally obtained the final hollow ceramic microspheres through high-temperature pressureless sintering.

Embodiment 3

[0047] A preparation method of hollow ceramic microspheres, comprising the following process steps:

[0048] Step 1: Preparation of solid microspheres

[0049] 1. Making PS Microspheres

[0050] (1) Add dispersion stabilizer, alcohol, and water into the three-necked flask, and turn on the stirrer while feeding nitrogen and oil bath.

[0051] (2) Dissolve a certain amount of styrene monomer and anionic initiator in the mixed solution of alcohol and water, fully shake and dissolve, and inject it into the three-necked flask under a certain temperature condition.

[0052] (3) React the three-neck flask of (2) at a specific temperature for a period of time to obtain PS microspheres.

[0053] 2. Sulfonate the prepared PS microspheres

[0054] 3. Coat the sulfonated PS microspheres with a layer of ceramic precursor

[0055] Put the sulfonated PS microspheres into the alcohol solution of the precursor, and stir thoroughly for a period of time.

[0056] Step 2: Ceramic precurso...

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Abstract

The invention relates to a hollow ceramic microsphere and a preparation method of the hollow ceramic microsphere, belonging to the technical field of ceramic microspheres. The hollow ceramic microsphere is a ceramic ball with a hollow structure, and the hollow ceramic ball is in a core-shell structure formed by cladding TiO2 on SiC. The preparation method of the hollow ceramic microsphere comprises the following steps: 1. preparation of a solid microsphere: (1) producing a polystyrene microsphere; (2) carrying out sulfonation; and (3) cladding a layer of ceramic precursor; 2. cladding the TiO2 on the surface of the polystyrene solid microsphere clad with the ceramic precursor: (1) dispersing the microsphere in a mixed solution of ethanol and dibutyl phthalate; (2) adding acid and deionized water into the mixed solution; and (3) carrying out hydrothermal treatment to obtain the polystyrene solid microsphere clad with the ceramic precursor; and 3. preparation of the hollow ceramic microsphere: placing the polystyrene solid microsphere clad with the ceramic precursor with the surface being clad with the TiO2 in a vacuum furnace for sintering to obtain the hollow ceramic microsphere. The hollow ceramic microsphere and the preparation method have the advantages of high product activity, excellent performance, good thermal insulation effect, wide applicable range and the like.

Description

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Claims

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Application Information

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Owner TIANJIN CHENGJIAN UNIV
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