Hollow ceramic microsphere and preparation method of hollow ceramic microsphere
A technology of hollow ceramics and microspheres, which is applied in the field of hollow ceramic microspheres and its preparation, can solve the problems of high density, cracking of airgel blocks, increase of solid-phase heat transfer, etc., and achieve excellent high temperature performance, high product activity, The effect of low cracking temperature
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Embodiment 1
[0043] A hollow ceramic microsphere is a ceramic ball with a hollow structure, and the hollow ceramic ball is a TiO2-coated SiC core-shell structure. TiO2 has a rutile structure. The diameter of the hollow ceramic ball is Φ1-3um, the hollow size of the hollow structure is Φ1-2um, and the hollow ceramic ball is a core-shell structure of TiO2 coated SiC
Embodiment 2
[0045] A hollow ceramic microsphere is a ceramic ball with a hollow structure, and the hollow ceramic ball is a TiO2-coated SiC core-shell structure. SiC is obtained by sintering ceramic precursors; TiO2 has a rutile structure. The diameter of the hollow structure ceramic ball is Φ1-2um, and the hollow size of the hollow structure is Φ0.8-1.5um. The hollow ceramic microspheres in this example are prepared by using the sacrificial template method first, and then coated with a layer of titanium dioxide infrared covering agent on the surface by the hydrothermal method, and finally obtained the final hollow ceramic microspheres through high-temperature pressureless sintering.
Embodiment 3
[0047] A preparation method of hollow ceramic microspheres, comprising the following process steps:
[0048] Step 1: Preparation of solid microspheres
[0049] 1. Making PS Microspheres
[0050] (1) Add dispersion stabilizer, alcohol, and water into the three-necked flask, and turn on the stirrer while feeding nitrogen and oil bath.
[0051] (2) Dissolve a certain amount of styrene monomer and anionic initiator in the mixed solution of alcohol and water, fully shake and dissolve, and inject it into the three-necked flask under a certain temperature condition.
[0052] (3) React the three-neck flask of (2) at a specific temperature for a period of time to obtain PS microspheres.
[0053] 2. Sulfonate the prepared PS microspheres
[0054] 3. Coat the sulfonated PS microspheres with a layer of ceramic precursor
[0055] Put the sulfonated PS microspheres into the alcohol solution of the precursor, and stir thoroughly for a period of time.
[0056] Step 2: Ceramic precurso...
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