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Method for preparing high-quality tire oil by catalytic cracking of waste and old tires

PendingCN122234835Asuppress overproductionhigh yieldLiquid hydrocarbon mixture production
This invention discloses a method for preparing high-quality tire oil through catalytic pyrolysis of waste tires. The method uses a eutectic solvent formed by choline chloride and ferric chloride hexahydrate as a low-temperature phase change medium, which functions as a heat carrier, swelling agent, catalyst, and sulfur capture agent. Waste tire rubber powder is mixed with this medium, and a low-temperature swelling and pyrolysis desulfurization reaction is carried out under an inert atmosphere. The Lewis acidity of iron ions in the medium preferentially breaks the C-S and S-S bonds in the rubber crosslinking bonds. The sulfur-containing active species generated by the breakage are captured in situ as inorganic sulfides and retained in the liquid phase. The escaped oil vapor is condensed to directly obtain ultra-low sulfur, light-colored, transparent, high-quality tire oil. The used medium can be oxidized and regenerated by introducing air under heating conditions, and the sulfur is recovered in the form of elemental sulfur, allowing the medium to be recycled. This invention achieves synergistic unity of low-temperature pyrolysis and deep desulfurization at the source, with a simple process flow that is economical and environmentally friendly.
Owner:YUANPING YEHUAN RENEWABLE RESOURCES COMPREHENSIVE UTILIZATION CO LTD