The invention discloses a method for preparing high-purity low-sulfur expanded graphite, which belongs to the preparation method of expanded graphite. The existing chemical method of the present invention to prepare expanded graphite has the technical problems of low product purity and high production cost. The method of the present invention: 1. high-temperature purification of phosphorus flake graphite; 2. putting it into a polypropylene mesh bag, soaking it in peroxide water, and lifting it to pour water; 3. wrapping the graphite block with a polypropylene mesh bag as an anode, and putting In the graphite electrolytic cell, then inject the electrolyte solution, use graphite as the cathode, and then electrolyze. During the electrolysis process, the polypropylene mesh bag is inflated and stirred; 4. Constant temperature drying and expansion; that is, high-purity low-sulfur expanded graphite is obtained. The method of the invention is simple and easy to operate, and the degree of intercalation can be controlled by adjusting the current intensity and electrolysis time, and the prepared high-purity expanded graphite is low in sulfur, and there is no pollution to the water body during the washing process, and no other impurities are doped in the product. The invention uses a small amount of oxidant to trigger, little or almost no pollution in production, and relatively low production cost.