149results about How to "Reduce secondary reactions" patented technology

A process for preparing low-carbon olefin from methanol or dimethyl ether includes loading its raw material and silicon aluminium phosphate (SAPO34) molecular sieve as catalyst into gas-solid parallel down-flowing fluidized bed reactor, super-short contact, reaction, fast gas-solid separation to separating resultant from catalyst to prevent secondary reaction, and regerating catalyst for cyclic use. Its advantages include high output rate (93%), high conversion rate of raw material, and less by-product.

The invention discloses microcrystal NaY-type molecular sieves and a preparation method thereof. In the microcrystal NaY-type molecular sieves, the molar ratio of SiO2 to Al2O3 is 4.0 to 6.0, and the average particle size is 100 to 700 nanometers. The microcrystal NaY-type molecular sieves are prepared by a method combining low-temperature synthesis directing agent, low-temperature synthesis gel and two-stage variable-temperature dynamic crystallization. The NaY-type molecular sieves have a relative crystallinity of over 80 percent after being roasted in the air at 600 DEG C for 3 hours or after undergoing hydrothermal treatment with vapor at 650 DEG C for 1 hour, as well as high thermostability and hydrothermal stability.

The invention provides an H-ZSM-5 zeolite catalyst for preparing propylene from methanol and an application thereof. An H-ZSM-5 zeolite with small crystal grains obtained by directional preparation through the hydrothermal synthesis technology has small crystal grain size and high specific surface area, and can achieve the purpose of shortening the length of a diffusion path of molecules of a product, improving the diffusion performance of the catalyst and reducing the secondary reaction of a low-carbon olefin product. The H-ZSM-5 zeolite catalyst is used in the reaction for preparing the propylene from the methanol, the yield of the propylene and the P/E (propylene/ethylene) weight ratio are greatly improved, and the P/E weight ratio is above 8.

The invention discloses the heavy distillate oil hydrotreatment catalyst and preparing method. The method comprises the following: using the metal at the VIB and VIII as hydrogenation componemt, using the refractory oxide as carrier, the catalyst containing the 1%-20% modified ª‰ zeolite possessing the multi-stage pore path structure of 0.1-1.7nm,1.7-6.0nm and 10.0-90.0nm, The mole ratio of SiO2 and Al2O3 in the ª‰ zeolite being 80-120, and the particle mean size being 0.1-0.5ª–m. Due to choose the proper ª‰ zeolite, the catalyst possesses the characteristics of the high activity of desulfuration and denitrification, and is used for hydrotreating process of inferior distillate oil to produce FCC raw material.

The invention relates to a preparation method of an H-ZSM-5 molecular sieve based catalyst and a prepared catalyst; preheating is performed before sealed hydrothermal crystallization through hydro-thermal synthesis technology, which reduces the water content of a gel mixture, increases the solid content of the system, thus reaches the target of producing small crystal grains, and greatly improves the yield per single kettle of the molecular sieve; meanwhile the product separation process is avoided, which reduces the discharge of amine-containing waste water, and reduces environment pollution. With the catalyst of the present invention, the length of the product molecular diffusion path is shortened; the diffusion performance of the catalyst is improved; the secondary reaction of low carbon olefins is reduced; thus the propylene selectivity and P/E ratio are increased; and substances above C4 are ensured to be mainly olefins, and especially to be olefins with poor side chains.

The invention discloses a fluidized bed reactor used for light olefin cracking and Methanol To Olefin (MTO), which comprises a reactor and a pre-riser; the reactor comprises a dense phase fluidized bed reactor and a dilute phase conveying reactor which are positioned at same axis, the pre-riser and the dilute phase conveying reactor are respectively positioned at upper part and lower part of the dense phase fluidized bed reactor; diameter of the pre-riser is smaller than diameter of the dense phase fluidized bed reactor, the upper part of the pre-riser extends into the dense phase fluidized bed reactor; an upper end port of the pre-riser in the dense phase fluidized bed reactor is sealed, and a perforate is provided on the tube wall of the pre-riser in the dense phase fluidized bed reactor; or the perforate is provided on the upper end of the pre-riser in the dense phase fluidized bed reactor, and a baffle plate is arranged over the perforate. The reactor is capable of increasing gas-solid contact efficiency, the backmixing degree of oil gas and a catalyst is less, and conversion rate of one way of the light olefin cracking and Methanol To Olefin (MTO) reactions can be greatly improved, and the target product micromolecule olefin selectivity can be greatly improved.

The invention discloses a method for producing chemical raw material and diesel oil by Fischer-Tropsch synthetic wax and the method is that the Fischer-Tropsch synthetic wax and hydrogen gas contact with hydrogen cracking catalyst under hydrogen cracking condition and then the reaction products are treated by fractionation; diesel distillate obtained is the clean diesel with a low freezing point, while the naphtha cut obtained is high-quality raw material used for cracking of steam to ethane, and distillation range is higher than the hydrogen cracking of tail oil circulation of the diesel oil, wherein, the hydrogen cracking catalyst is the hydrogen cracking catalyst containing Beta zeolite and the weight content of the Beta zeolite in the catalyst is 0.5 percent to 60 percent; the Beta zeolite has properties that SiO2/Al2O3 molar ratio is 20 to 150 and Na2O less than or equal to 0.2w percent. The method of the invention can prepare the Fischer-Tropsch synthetic wax into the clean diesel oil with a low freezing point and high-quality raw material used for producing ethylene by steam cracking.

The invention discloses a high-silicon octahedra zeolite and preparing method with the molar rate of SiO2/Al2O3 at 6-20, wherein the XRD spectral analysis belongs to Y-typed zeolite in the octahedra zeolite, whose crystal particle shape displays sheet appearance; producing the product under fitful moulding agent and low alkaline condition without guiding agent (zeolite seed).

The invention relates to a novel rare-earth electrolytic bath. A gap is reserved in the center of each anode, and the bottom surface of each anode is a concave surface being concave from the periphery towards the center. A cathode is correspondingly arranged below each anode. The cathodes are buried in a protruding high-temperature-resisting material. The top of each cathode is an arc convex surface and protrudes out of the high-temperature insulating material. An electrical insulating layer is arranged between the high-temperature-resisting material and each cathode. A metal groove is formed between every two cathodes, and the high-temperature-resisting material is concave downwards to form the metal grooves. A cathode steel bar is located at the bottom of each cathode and connected with the cathode. The space between every two adjacent cathode steel bars is filled with a graphite block. An electrical insulating layer is arranged between each graphite block and the corresponding cathode steel bar. A feeder is arranged on the top of a bath body. According to the novel rare-earth electrolytic bath, the convex surfaces of the cathodes are higher than the high-temperature insulating layers, so that a high-temperature zone of the electrolytic bath is moved upwards. Through the metal grooves designed for the electrolytic bath, the contact area of metal and an electrolyte is reduced, re-dissolution of the metal is restrained, and the current efficiency is improved. The shapes of the anodes of the electrolytic bath are beneficial for discharging of anode bubbles.

The invention discloses a method for producing needle coke by adopting the technique combining delay coking and kettle-type coking. The method comprises: when treating the conventional coking raw material by using the delay coking technique, introducing FCC slurry oil into a delay coking tower from the upper part inside the tower at the low temperature, and obtaining needle coke raw material by fractionating high temperature oil gas obtained by the reaction; and then, treating the needle coke raw material by using the kettle-type coking technique, and obtaining high quality needle coke. In the method, as the FCC slurry oil is injected into the coking tower at the lower temperature, the decomposition temperature of the conventional coking raw material is lowered, the high temperature decomposition time of the raw material is shortened, the occurrence of secondary reaction is reduced, green coke rate is reduced, the stable operation cycle of a signal tower is prolonged, and light components which have high reaction activity and are not beneficial to producing the needle coke, heavy components with high polymerization activity, and a great deal of impurities such as catalyst powder, heavy metal and the like can be removed. The obtained needle coke has high yield and good quality.

The invention discloses an electrolytic cathode containing a titanium boride-carbon coating, and a preparation method thereof. The electrolytic cathode is characterized in that: a coating is coated on the surface of the electrolytic cathode, wherein the coating comprises components of, by mass: 20 to 22% of TiB2, 15 to 20% of epoxy resin, 24 to 27% of diethylene triamine, 0.3 to 0.8% of carbon fiber, and balance of graphite powder. The preparation method of the aluminum electrolytic cathode comprises steps that: the materials are sufficiently mixed and uniformly coated on the surface of the electrolytic cathode; the coating is heated from normal temperature to 150 DEG C, such that the coating is cured, and the electrolytic cathode containing the titanium boride-carbon coating is obtained.According to the invention, good wettability of aluminum liquid and the electrolytic cathode is utilized, such that aluminum oxide deposition is not easy to be left on the surface of the electrolyticcathode. Therefore, deposition or crusting is not easy to occur, current is uniformly distributed, disturbance of magnetic fields to the aluminum liquid is reduced, current efficiency is improved, energy consumption is reduced, the service life of an electrolyte tank is prolonged, and aluminum liquid level and polar pitch can be appropriately reduced. With the electrolytic cathode provided by theinvention, an average working voltage and a secondary reaction probability of the aluminum electrolyte tank are reduced, aluminum electrolytic production is improved, and the quality of aluminum products is improved.

The invention discloses a coal flash pyrolysis system and method. The coal flash pyrolysis system comprises a flash pyrolysis reactor, a slag cooler and a cooling device. The flash pyrolysis reactor comprises a reactor body, multiple layers of heat storage type radiant tubes, a coal inlet, a distributor, a distribution gas inlet, multiple pyrolysis gas outlets and a semicoke outlet. The slag cooler is connected with the semicoke outlet and is suitable for cooling semicoke. The cooling device is connected with the pyrolysis gas outlets and is suitable for cooling pyrolysis gas so that tar and fuel gas can be obtained. The system can significantly increase the tar yield and greatly simplify the flash pyrolysis reaction technological process.

The invention discloses a rapid biomass pyrogenation system and method. The system comprises a rapid pyrogenation reactor, a residue cooling machine and a spraying tower. The rapid pyrogenation reactor comprises a reactor body, a multi-layer heat storage type radiation pipe, a biomass inlet, a material distributor, a distribution gas inlet, a plurality of pyrogenation gas outlets and a semicoke outlet. The residue cooling machine is connected with the semicoke outlet and suitable for cooling semicoke. The spraying tower is connected with the pyrogenation gas outlet and suitable for spraying pyrogenation gas through cooling liquid so that bio-oil and fuel gas can be obtained. The system can convert biomass into bio-oil with high value-added, and therefore efficient and clean utilization of biomass is achieved, and the rapid pyrogenation reaction technological process is greatly simplified.

The invention discloses a flash pyrolysis reaction device. The flash pyrolysis reaction device comprises a reactor, multiple layers of heat storage type radiant tubes, a distributor, a material inlet, a distribution gas inlet, multiple pyrolysis gas outlets and a semicoke outlet. The reactor comprises a reactor body, and a reaction space is defined in the reactor body and forms a dispersion zone, a pyrolysis zone and a discharge zone from top to bottom. The multiple layers of heat storage type radiant tubes are distributed at intervals in the pyrolysis zone in the height direction of the reactor body, and each layer of heat storage type radiant tubes comprises multiple heat storage type radiant tubes distributed at intervals in the horizontal direction. The material inlet is located in the position, above the distributor, in the dispersion area. The distribution gas inlet is located in the dispersion zone and communicated with the distributor so that materials in the distributor can be conveniently blown out through distribution gas to enter the dispersion zone and then evenly fall into the pyrolysis zone. The multiple pyrolysis gas outlets are formed in the dispersion zone and/or the pyrolysis zone. The semicoke outlet is formed in the discharge zone. The device can significantly increase the tar yield and greatly simplify the flash pyrolysis reaction technological process.

The invention belongs to the technical field of a structured catalyst and an application thereof, in particular to a porous carborundum surface single-layered and b-axis oriented ZSM-5 zeolite coating material and a preparation method thereof. Foamy carborundum or honeycomb structured carborundum is taken as a carrier, wherein a porous layer which is composed of overlapped carborundum grains is formed on the outer surface of the carrier; a zeolite coating layer is uniformly formed in the zeolite coating; the zeolite coating layer has a single-layer structure; and a b axis of a zeolite crystalis vertical to the surface of the carborundum carrier. The preparation method comprises the following steps: growing a layer of seed crystal colloid in situ on a carborundum ceramic surface in advance; controlling the basicity of a secondary growing solution, the concentration of nutrient substances and an added quantity of alkali metallic ions; and realizing the controllable growth of zeolite crystal on the surface of the carborundum carrier. The channel of the structured catalyst is opened; the molecular diffusion property is excellent; a specific surface area and a load are bigger; a contact area between the zeolite crystal and the carborundum carrier is big; the strengthened mass transfer and heat transfer are boosted; and the contact time among the reactant, the reaction product and the catalyst is shortened.

The invention relates to a preparation method of nanometer NaY molecular sieve, which is as follow: under the hypergravity condition of the revolving bed, performing guiding agent preparation, mother solution preparation, and mixing of guiding agent and mother solution, and the sequent crystallization of the reaction product. The invention enables to shorten the crystallization reaction time, simplify the technological process and prepare the high-quality nanometer NaY molecular sieves. The nanometer NaY molecular sieve catalyst prepared through the method can be used for the catalytic cracking of the heavy oil. Compared with the normal industrial molecular sieve, the nanometer NaY molecular sieve has the advantages of great increase of gasoline productivity, diesel fuel productivity, clean oil yield and total-liquid yield, improvement of the product selectivity, and obvious improvement of the product distribution.

The invention discloses a system and method for pyrolyzing coal. The system comprises a moving bed pyrolysis reactor and a spray tower; the reactor comprises a coal material inlet, a semicoke outlet, regenerative radiant tubes, oil gas exporting pipelines, a stirring device and gas collecting tubes; the regenerative radiant tubes are arranged in the reactor in the height direction of the reactor for multiple layers, and multiple regenerative radiant tubes which are parallel to one another in the horizontal direction are arranged on each layer; through holes are formed in the pipe walls of the oil gas exporting pipelines; the stirring device comprises a stirring shaft and multiple stirring rods connected to the stirring shaft; the gas collecting tubes comprise the gas collecting header tube and the gas collecting branch tubes, and the gas collecting header tube is connected with the spray tower. According to the system, powdered coal can be effectively treated, and the treatment efficiency is high; meanwhile, oil gas resources generated through pyrolysis can be quickly exported, secondary reactions are few, the tar oil quality is high, and the content of light components in tar oil is high; in addition, due to the fact that the regenerative radiant tubes are adopted in the pyrolysis reactor and rotatable inner elements are arranged in the regenerative radiant tubes, heat transfer among particles and between the particles and the radiant tubes is increased, and the heat transfer efficiency is high.

The present invention discloses an EU-1/ZSM-5 composite molecular sieve and a toluene disproportionation and transalkylation catalyst and application of the catalyst. In the EU-1/ZSM-5 composite molecular sieve, a ZSM-5 molecular sieve is embedded around a EU-1 molecular sieve, the EU-1 molecular sieve accounts for 30% to 70% weight percent of the composite molecular sieve, and the molar ratio of silica/alumina is 30 to 50. The toluene disproportionation and transfer catalyst includes the composite molecular sieve. The composite molecular sieve-containing toluene disproportionation and transalkylation catalyst of the present invention has excellent performance in use without carrying metal components, and has relatively high toluene conversion rate, and benzene and xylene (B + C8A) selectivity.

The invention discloses a system and a method of fast pyrolysis of oil shale. The system comprises a fast pyrolysis reactor and a spray tower, wherein the fast pyrolysis reactor comprises a reactor body, a multilayer regenerative radiant tube, an oil shale inlet, a distributing device, a distributing gas inlet, a plurality of pyrolysis gas outlets and a carbocoal outlet, the fast pyrolysis reactor is suitable for performing fast pyrolysis treatment on the oil shale by adopting the regenerative radiant tube, so as to obtain carbocoal and pyrolysis gas, and the spray tower is connected with the plurality of pyrolysis gas outlets and is suitable for performing spray treatment on the pyrolysis gas by adopting cooling liquid, so as to obtain shale oil and gas. According to the system, fast pyrolysis of the oil shale can be realized, and the yield of the obtained shale oil is high.

The invention provides a production device and a production process for producing linear alpha-olefin through ethylene selective oligomerization, and belongs to the technical field of homogeneous catalysis. The device comprises a raw material pretreatment unit, a reaction unit and a separation unit, the reaction unit comprises a reaction kettle, a circulating fan, a primary condenser, a primary condensate tank, a secondary condenser and a secondary condensate tank which are sequentially communicated, and the primary condensate tank is communicated with the separation unit; the secondary condensate tank is communicated with a reaction kettle; a temperature sensor is arranged in the reaction kettle, a gas regulating valve is arranged between the primary condenser and the circulating fan, the gas regulating valve and the temperature sensor are interlocked, and the opening degree of the regulating valve is controlled through the temperature of the reaction kettle. The process and the device are mainly used for an ethylene oligomerization process, and have the characteristics that the activity of the catalyst is promoted to be improved, the selectivity of linear alpha-olefin is improved, the secondary reaction degree in which the product participates is low, high-carbon byproducts are few, and the reaction heat removal capability is strong.

The invention relates to the field of methanol-to-olefin catalysts, discloses a high-silicon ZSM-5 molecular sieve and a preparation method and application thereof, in particular to a preparation method of the high-silicon ZSM-5 molecular sieve. The preparation method comprises the following steps: mixing a solid silicon source, an aluminum source, a ZSM-5 molecular sieve seed crystal, a template, an alkali, urea and water uniformly in sequence, and carrying out aging and hydro-thermal synthesis crystallization, wherein urea is added in the stage of uniformly mixing the raw materials, the liquid silicon source is SiO2, the aluminum source is Al2O3, and the mixing ratio of the raw materials meets that the molar ratio of the solid silicon source, the aluminum source, the template, the alkali, the urea to the water is 1: (0.001 to 0.01): (0.025 to 0.25): (0.02 to 0.2): (0.3 to 4): (2 to 50), and the weight ratio of the ZSM-5 molecular sieve seed crystal to SiO2 in the solid silicon source is (1 to 10): 100. The invention also relates to the high-silicon ZSM-5 molecular sieve prepared by the invention and application thereof. When the prepared flaky high-silicon ZSM-5 molecular sieve is used for reactions for catalyzing methanol to propylene and/or butane, the selectivity of C3 and/or C4 olefin products is improved.

The invention discloses a submicron composite molecular sieve for preparing a catalyst for producing low-carbon olefin through organic oxygen compound and a preparation method of the submicron composite molecular sieve. The composite molecular sieve is formed by compounding an SAPO-5 molecular sieve and an SAPO-18 molecular sieve. Raw materials for preparing the composite molecular sieve satisfy the following condition: the molar ratio of SiO2: Al2O3: P2O5 is (0.1-0.6): 1: (0.7-1.3); the addition quantity of the SAPO-5/SAPO-18 composite sieve screen crystal seed is 1.0 to 5.5 percent by adopting the weight of effective solid content in mixed gel as a benchmark. The SAPO-5/SAPO-18 composite molecular sieve has submicron-meter granularity and is good in catalytic activity, long in service life and high in qualification molecular sieve yield.