Clean fracturing fluid with liquid thickening agent and preparation method thereof

A technology of clean fracturing fluid and thickener, applied in the field of fracturing fluid, can solve the problems of increased construction links, viscoelastic damage of fracturing fluid, and reduction of viscoelastic properties of fracturing fluid, so as to improve oil recovery efficiency and reduce formation damage small effect

Inactive Publication Date: 2013-11-27
上海圣轩生物科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In order to uniformly disperse the small molecule thickener in water, certain measures need to be taken, but most of these measures will result in an increase in the construction process or a decrease in the viscoelastic properties of the fracturing fluid
If the method of heating to promote dissolution will increase the number of on-site equipment, the method of preparing the concentrated solution in advance will cause a large increase in the volume of the thickener due to the solubility of the surfactant, which will cause inconvenience in transportation. Use organic solvents to prefabricate high-concentration solutions The method will cause damage to the viscoelasticity of the fracturing fluid due to the intervention of organic solvents

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Step 1: mixing high-melting-point unsaturated fatty acids with low-melting-point unsaturated fatty acids in a mass ratio of 1:2 to prepare an unsaturated fatty acid thickener;

[0028] Among them, the unsaturated fatty acid with high melting point is erucic acid, and the unsaturated fatty acid with low melting point is oleic acid.

[0029] Step 2: Prepare a strong alkali solution, that is, a mixed aqueous solution of sodium hydroxide and potassium chloride, wherein the mass percentage of sodium hydroxide is 0.8%, and the mass percentage of potassium chloride is 2.2%.

[0030] Step 3: Mix the unsaturated fatty acid thickener in step 1 and the strong alkali solution in step 2 at a mass ratio of 2.4:100 under vigorous stirring to form clean fracturing that can carry sand within 3 minutes Liquid hydrogel, the viscosity at room temperature can reach 70mPa.s, used as fracturing fluid, can withstand the temperature above 50 ℃.

Embodiment 2

[0032] Step 1: mixing high-melting-point unsaturated fatty acids with low-melting-point unsaturated fatty acids at a mass ratio of 1:2.5 to prepare an unsaturated fatty acid thickener;

[0033] Among them, the unsaturated fatty acid with high melting point is erucic acid, and the unsaturated fatty acid with low melting point is oleic acid.

[0034] Step 2: Prepare a strong alkali solution, that is, a mixed aqueous solution of sodium hydroxide and potassium chloride, wherein the mass percentage of sodium hydroxide is 1.0%, and the mass percentage of potassium chloride is 2.6%.

[0035] Step 3: Mix the unsaturated fatty acid thickener in step 1 and the strong alkali solution in step 2 at a mass ratio of 2.7:100 under vigorous stirring to form clean fracturing that can carry sand within 3 minutes Liquid hydrogel, the viscosity at room temperature can reach 65mPa.s, used as fracturing fluid, can withstand the temperature above 50 ℃.

Embodiment 3

[0037] Step 1: mixing high-melting-point unsaturated fatty acids with low-melting-point unsaturated fatty acids at a mass ratio of 1:3 to prepare an unsaturated fatty acid thickener;

[0038] Among them, the unsaturated fatty acid with high melting point is erucic acid, and the unsaturated fatty acid with low melting point is palmitoleic acid.

[0039] Step 2: Prepare a strong alkali solution, that is, a mixed aqueous solution of sodium hydroxide and potassium chloride, wherein the mass percentage of sodium hydroxide is 1.2%, and the mass percentage of potassium chloride is 3%.

[0040] Step 3: Mix the unsaturated fatty acid thickener in step 1 and the strong alkali solution in step 2 at a mass ratio of 3:100 under vigorous stirring to form clean fracturing that can carry sand within 3 minutes Liquid hydrogel, the viscosity at room temperature can reach 65mPa.s, used as fracturing fluid, can withstand the temperature above 50 ℃.

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Abstract

The invention relates to a clean fracturing fluid with a liquid thickening agent and a preparation method thereof. The problem of dissolution of the thickening agent is one of the problem which causes that the clean fracturing fluid is difficult to widely use in the using process of the clean fracturing fluid, and most of most of viscoelastic surface active agents are generally difficult to fast dissolve under the condition of room temperature. The preparation method comprises the following steps of: mixing high-melting point unsaturated fatty acid and low-melting point unsaturated fatty acid according to the proportion of 1:(2-1):3 to prepare an unsaturated fatty acid thickening agent; preparing the mixed water solution of sodium hydroxide and potassium chloride, wherein the mass percent is respectively as follows: 0.8%-1.2% and 2.2%-3%; mixing the unsaturated fatty acid thickening agent and the mixed water solution at a ratio of 2.4:(100-3):100 under the condition of vigorous stirring to prepare a product. Compared with other clean fracturing fluids of the surface active agents, the clean fracturing fluid disclosed by the invention is more convenient in process when in use because the thickening agent is in a self liquid state and has good solubility of components. According to the invention, the adopted thickening agent is micromolecular and less in formation damage, so that the oil recovery efficiency is easier to increase.

Description

technical field [0001] The invention relates to a fracturing fluid in petroleum exploitation, in particular to a clean fracturing fluid using a liquid thickener and a preparation method thereof. Background technique [0002] Water-based fracturing fluid is a production stimulation measure commonly used before crude oil exploitation. In order to obtain a certain viscoelasticity for fracturing fluid, thickener is an indispensable raw material. Currently, the most used thickener is water-soluble Sexual polymers. However, in order to reduce the damage to the formation, the viscoelastic surfactant with small molecular weight has been paid more and more attention, and it is called clean fracturing fluid. [0003] During the use of clean fracturing fluids, the dissolution of thickeners is one of the problems that make it difficult to widely use clean fracturing fluids. Most of the currently used viscoelastic surfactants are solid powders, which need to be uniformly dispersed in ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/68
Inventor 李培枝秋列维杨晓武隋明炜张林
Owner 上海圣轩生物科技有限公司
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