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Rubber and plastic alloy asphalt modifier

A technology of asphalt modifier and rubber-plastic alloy, which is applied in the field of asphalt modification, can solve the problems of loss of modification effect, failure to achieve, high cost, etc., achieve good storage stability, increase high temperature strength, and reduce costs.

Active Publication Date: 2013-12-04
JIANGSU ZHONGHONG ENVIRONMENT TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Patent CN102337035A involves a kind of plastic modifier, which uses inorganic fillers such as talcum powder, diatomaceous earth, and carbon black with a particle size of 200-800 meshes to treat waste plastics, supplemented by compatibilizers such as aromatic oil and third-line oil, and effectively improves The storage stability of factory plastic modified asphalt was tested, but the low temperature performance of plastic modified asphalt was not dealt with
[0005] In addition, the patent CN1837291A discloses the composite modification technology of styrene-butadiene rubber, plastics such as PE, and thermoplastic elastomers such as SBS, but it does not involve waste rubber powder and waste plastics, especially because waste rubber powder and waste plastics are used Afterwards, many of the components have changed, and it is difficult to control the impact of this change on the modifier by the existing technology
CN101045821A discloses a two-step modification process of waste packaging EVA and waste rubber powder, but this technology only blends the two under a shearing machine, and the storage stability of asphalt is poor
CN102020860A Use polyethylene, styrene, styrene-butadiene rubber and other raw materials to realize the modification of rubber-plastic composites. To graft rubber-plastic blends, it is necessary to introduce various admixtures such as active agents, accelerators, and anti-aging agents, and it is necessary to use new High-grade plastic and rubber are used as raw materials, which causes the problem of high cost
CN102766337A relates to non-precipitating rubber-modified asphalt, adding waste rubber powder to 2-3% recycled polystyrene plastic particles in a certain proportion, supplemented by organic acid anhydrides, active agents and other additives, so that the rubber powder can be bonded with polystyrene branch, and then extruded and granulated by twin-screw machine, so that the rubber powder does not precipitate or segregate in asphalt, and improves storage stability, but this technology cannot control the grafting ratio of rubber powder and polystyrene, and the plastic is limited to polystyrene , and because the grafting reaction is difficult to control, the effect of its modification is actually not as good as the high and low temperature performance of asphalt obtained by the modification of the two alone, that is, the modification effect of the two polymers is lost to a certain extent and cannot be achieved. better effect
[0006] To sum up, the existing patents have made some progress in the treatment of plastics and rubbers individually modified or compositely modified, but there are still waste plastics that affect the low-temperature performance of asphalt, and waste tire rubber powder with high viscosity, both of which are easy to segregate. Special preprocessing and other issues

Method used

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  • Rubber and plastic alloy asphalt modifier

Examples

Experimental program
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Effect test

Embodiment 1

[0028] A rubber-plastic alloy asphalt modifier, its main composition and parts by weight: 65 parts of waste tire rubber powder, 25 parts of waste plastic particles, 2 parts of plasticizer, 0.2 part of surfactant;

[0029] Wherein said waste tire rubber powder is 20 mesh waste radial tire crushed rubber powder; said waste plastic particles are selected from crushed waste plastic particles with a PE component greater than 80wt%; all are purchased directly from the market;

[0030] The plasticizer is selected from epoxy fatty acid methyl ester; the surfactant is selected from FLUORADFC-430.

[0031] The specific preparation steps are as follows: heating waste tire rubber powder to 230-250° C. on a single-screw machine, adding plasticizer epoxy fatty acid methyl ester, maintaining the rubber powder at 230-250° C. to soften and degrade the rubber powder for 20-30 minutes, and then Add surfactant and waste plastic granules in sequence, run the above-mentioned blend twice on the scre...

Embodiment 2

[0049] A rubber-plastic alloy asphalt modifier, its main composition and parts by weight: 73 parts of waste tire rubber powder, 30 parts of waste plastic particles, 5 parts of plasticizer, and 0.6 part of surfactant;

[0050] Wherein said waste tire rubber powder is the crushed rubber powder of 40-mesh waste bias tire; said waste plastic particles are selected from the crushed particles of waste plastics with a PE component greater than 80wt%; all are purchased directly from the market;

[0051] The plasticizer is selected from epoxy fatty acid methyl ester; the surfactant is selected from FLUORADFC-430.

[0052] The specific steps are as follows:

[0053] Heat waste tire rubber powder to 230-250°C on a single-screw machine, add plasticizer epoxy fatty acid methyl ester, maintain the temperature at 230-250°C to soften and degrade the rubber powder for 20-30 minutes, and then add surfactants in sequence, For waste plastic granules, the above-mentioned blend is run twice on a s...

Embodiment 3

[0061] A rubber-plastic alloy asphalt modifier, its main composition and parts by weight: 72 parts of waste tire rubber powder, 25 parts of waste plastic particles, 2.7 parts of plasticizer, and 0.3 part of surfactant;

[0062] Wherein said waste tire rubber powder is the crushed rubber powder of 30 purpose waste radial tires and bias tires; the waste plastic particles are selected from the crushed particles of waste plastics whose PE composition is greater than 80wt%; all from the market purchased directly;

[0063] The plasticizer is selected from epoxy fatty acid methyl ester; the surfactant is selected from FLUORADFC-430.

[0064] The specific steps are as follows:

[0065] Heat waste tire rubber powder to 230-250°C on a single-screw machine, add plasticizer epoxy fatty acid methyl ester, maintain the temperature at 230-250°C to soften and degrade the rubber powder for 20-30 minutes, and then add surfactants in sequence, For waste plastic granules, the above-mentioned bl...

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Abstract

The invention relates to the field of asphalt additives and provides a rubber and plastic alloy asphalt modifier. The rubber and plastic alloy asphalt modifier is mainly made of untreated wasted plastic particles and wasted tire rubber powder and does not damage the individual modification effect of rubber and plastic. The rubber and plastic alloy asphalt modifier is good in asphalt storage stability performance and simple in the production technology. Rubber and plastic alloy modified asphalt manufactured with the rubber and plastic alloy asphalt modifier is applicable to continuously densely prepared asphalt blended materials. Under the condition that the high-temperature and the low-temperature performance of the blended materials can meet the requirements, water stability is obviously improved and two kinds of macromolecule wasted pollutants including wasted tire rubber powder and wasted plastic are effectively processed.

Description

technical field [0001] The invention relates to the field of asphalt modification, in particular to a rubber-plastic alloy asphalt modifier. Background technique [0002] In recent years, the environmental pollution caused by the accumulation of waste tires and waste plastics has attracted widespread attention. Waste rubber is the second largest waste polymer material. The world produces about 31 million tons of rubber products every year, 50% of which are tires, and the scrap rate of tires is as high as 55.4%. According to statistics, there are 1.5 billion tires (9 million tons) discarded every year in the world. Driven by the continuous increase in the number of private cars and trucks in my country, the output of waste tires has increased dramatically year by year. According to statistics, in 2006, my country's tire output was as high as 420 million, ranking first in the world, and the stock of waste tires reached 140 million, ranking second in the world. As of 2010, t...

Claims

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Application Information

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IPC IPC(8): C08L21/00C08L23/06C08K5/1515C08J11/26C08L95/00
CPCY02W30/62
Inventor 王立志王鹏任瑞波耿立涛徐强高晓宁战福豪王飞谭坦
Owner JIANGSU ZHONGHONG ENVIRONMENT TECH CO LTD
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