A microcarrier biochip and its application
A microcarrier and chip technology, applied in microcarrier biochips and its application fields, can solve complex chemical synthesis technology and surface chemical modification technology, complex preparation process, fluorescence resonance energy transfer and other problems, and achieve high-sensitivity parallel detection and detection The effect of simple means and large coding capacity
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Embodiment 1
[0050] Embodiment 1, the preparation of microcarrier of the present invention and its application effect experiment
[0051] 1. Preparation of microcarriers and their surface films.
[0052] A boron-doped silicon wafer with a crystal form of 100 is used to pass a mixed gas of hydrogen and oxygen at 1000°C. By controlling the reaction time, the thickness of the silicon dioxide film on the surface is controlled. Finally, a dicing process was used to prepare microcarriers with a size of 500 μm×500 μm. Microcarriers with film thicknesses of 93.0 nm, 267.2 nm and 360.7 nm were prepared.
[0053] For a specific film thickness, its reaction time can be obtained by the following formula:
[0054] t = X o 2 B + X o B / A
[0055] Where A and B are constants...
Embodiment 2
[0061] Embodiment 2, microcarrier film thickness resolution verification of the present invention
[0062] Microcarriers with silicon oxide films and silicon substrates were prepared according to the method of step 1 of Example 1, wherein the film thicknesses were 83.2nm, 87.7nm, and 93.0nm.
[0063] Use the above-mentioned system for collecting low-coherence images of micro-carriers to collect low-coherence images of micro-carriers, and analyze its surface color in RGB space to realize decoding. 28.0±2.55), (76.6±2.07, 32.0±2.35, 22.0±1.01), (65.2±0.93, 34.2±1.92, 35.0±1.71),
[0064] Such as Figure 4 As shown, the surface color signals of the three microcarriers with a thickness difference of about 5nm can be clearly distinguished in the three channels of R, G, and B, and through T test analysis, it is found that the signals in the three channels have significant sexual difference. (***: p<0.001; **: p<0.01, *: p<0.05, p<0.05 means there is a significant difference).
...
Embodiment 3
[0066] Embodiment 3, microcarrier sensitivity detection of the present invention
[0067] The film thickness that uses the method described in step 1-2 of embodiment 1 to prepare is the microcarrier of 93.0nm, 267.2nm and 360.7nm, detects target solution according to the method for step 3 in embodiment 1, and target solution is 100ul respectively 5 μg / ml Cy3-labeled goat anti-mouse IgG solution was sequentially used in 1xPBS (preparation method: sodium chloride (NaCl): 8g, potassium chloride (KCl): 0.2g, disodium hydrogen phosphate (NaCl) 2HPO 4 ): 1.44g, potassium dihydrogen phosphate (KH 2 PO 4 ): 0.24g, adjust the pH to 7.4, and set the volume to 1L) for 10, 10 2 、10 3 、10 4 、10 5 For the solution obtained after dilution, use a fluorescence microscope to detect the fluorescence signal to obtain the relationship between the concentration of the target molecule and the fluorescence signal, and use the 3σ principle, that is, use the background fluorescence signal value p...
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Abstract
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