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Low-bubble photo-curing adhesion agent

A light-curing, adhesive technology, used in adhesives, non-polymer organic compound adhesives, non-polymer adhesive additives, etc., can solve the problem of poor compatibility of defoamer, difficult to completely eliminate large bubbles, Can't use etc.

Inactive Publication Date: 2014-08-06
YANTAI DARBOND TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Bonding with ordinary light-curing adhesive, it is easier to squeeze out the bubbles when the area is small, but it is difficult to get out when the area is large, and it is impossible to drive out the bubbles when the area is large enough to a certain extent
This brings a lot of trouble to the use, and even can not be used
Of course, the problem of air bubbles can also be solved by vacuuming, but it needs to increase equipment and add a process during operation, so it not only increases the equipment cost but also reduces the production efficiency. This is what most users do not want to accept. The glue manufacturer will be asked to solve the problem from the glue, which presents a difficult problem for the glue manufacturer
It is generally thought of using defoamers to solve this problem, but most defoamers are not compatible with light-curing adhesives. Adding too little will not work, and too much will affect the transparency and other properties of the glue. The remaining large bubbles are also difficult to completely eliminate
That is to say, the defoamer is not a panacea. Although it generally has a certain effect on defoaming and foam suppression, it cannot fundamentally solve the problem of bubbles.

Method used

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Examples

Experimental program
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Embodiment Construction

[0012] Put the raw materials into the stirring tank according to the ratio, keep the temperature at 50 degrees, the vacuum at -0.08~-0.1MPa, the speed at 200r / min, stir for 40 minutes to 1 hour, and finally continue to vacuum for 10 to 15 minutes. Filtrate the material to get the finished product.

[0013] The raw material proportions of each embodiment and comparative example are shown in Table 1. In the comparative example, TEGO Airex 920, a defoamer commonly used in photocurable adhesives with better defoaming effect, was used

[0014] Table I:

[0015]

[0016] First, according to the specific implementation method and the ratio of raw materials of each embodiment and comparative example in Table 1, the finished glue is produced, and a certain amount is weighed to observe its transparency and measure its viscosity at 25 degrees. Then use 250ml plastic tanks to take 100 grams each, fix the stirring height, the stirring speed is 300r / min, and the stirring time is 5min. ...

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Abstract

The invention discloses a low-bubble photo-curing adhesion agent. The low-bubble photo-curing adhesion agent comprises, by weight, 10-50 parts of (methyl) acrylic ester prepolymer with polyolefin, 30-90 parts of (methyl) acrylic ester diluent monomer, 0.1-5 parts of silane coupling agents, 1-10 parts of photoinitiators, and 0-7parts of adhesion promoters. The addition of the adhesion promoters is determined according to requirements of a user; if the low-bubble photo-curing adhesion agent is used for adhesive bonding between glass or between glass and metal with a high requirement for adhesive strength, an appropriate number of the adhesion promoters can be added; if the low-bubble photo-curing adhesion agent is used for adhesive bonding between organic glass or between the glass and the metal with a low requirement for adhesive strength, the adhesion promoters may be not added. Compared with the prior art, few bubbles are generated when the low-bubble photo-curing adhesion agent is blended, and the generated bubbles can disappear by themselves in a short time; the bubbles are not easily generated at the time of adhesive bonding; even if a few bubbles are generated, the bubbles can disappear by themselves in a short time.

Description

technical field [0001] The invention relates to an adhesive, in particular to a low-foam light-curing adhesive suitable for large-area bonding. Background technique [0002] Light-curing adhesive is widely used in the bonding of transparent glass and plexiglass because it is transparent after curing and no traces can be seen. Generally, light-curing adhesives are prone to bubbles during the bonding process, especially for grating shielding glass, which requires a metal mesh with a small aperture between two pieces of glass. With ordinary light-curing adhesive bonding, it is easier to squeeze out the bubbles when the area is small, but it is difficult to drive out when the area is large, and it is impossible to drive out the bubbles when the area is large enough to a certain extent. This just brings very big trouble to use, even can't use. Of course, the problem of air bubbles can also be solved by vacuuming, but it needs to increase equipment and add a process during opera...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J4/02C09J11/06
Inventor 刘秀棉王建斌陈田安解海华
Owner YANTAI DARBOND TECH
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