Composite resin material for cables and preparation method thereof

A composite resin and composite filler technology, used in insulated cables, plastic/resin/wax insulators, cables, etc., can solve the problems of affecting polymer strength, high proportion of coupling agent, insufficient mixing of coupling agent and inorganic filler, etc. , to achieve the effect of improving impact strength and gloss, excellent impact strength, and reducing production costs

Active Publication Date: 2016-08-10
SHENZHEN BENDAKANG CABLE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, there is technology to mix and refine nano-scale fillers and resins to produce insulating materials for cables, but the proportion of coupling agents added is relatively high, which pushes up production costs on the one hand, and on the other hand, the mixing of coupling agents and inorganic fillers is not sufficient and easy Causes agglomeration of nanofillers, which affects the strength of the polymer
There is another technology that completely eliminates the use of coupling agents. At the same time, in order to prevent the mutual polymerization of nano-fillers, the amount of nano-fillers added is relatively low, up to 30%, which fails to give full play to the excellent performance of nano-fillers.
[0004] None of the above technologies comprehensively considered various factors such as the selection of nano-scale and micro-scale inorganic fillers, matrix polymer materials, and surface treatment methods to improve the performance and cost advantages of composite polymer materials.

Method used

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  • Composite resin material for cables and preparation method thereof
  • Composite resin material for cables and preparation method thereof
  • Composite resin material for cables and preparation method thereof

Examples

Experimental program
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preparation example Construction

[0063] This embodiment also provides a method for preparing the above-mentioned composite resin material for cables, and the process flow is as follows figure 1 shown. The method includes the following steps:

[0064] S01. Weigh the formula components: respectively weigh each component according to the formula of the above-mentioned composite resin material for cables;

[0065] S02. Preparation of mixed material: Divide the nanometer and micron composite filler into two parts, and melt and extrude one part with the above-mentioned resin to form a mixed material.

[0066] S03. Melt extrusion: the mixture material prepared in step S02 and another part of nanometer and micron composite filler and auxiliary are melt extruded to obtain the above-mentioned composite resin material for cables; the weight of the above-mentioned nanometer and micron composite filler and resin The parts ratio is 1:2 to 3, and the above-mentioned melt extrusion temperature is 190°C to 210°C.

[0067] ...

Embodiment 1

[0080] The weight percentage of the composite resin material for cables in this example is as follows, and the formula components are shown in Table 1 below.

[0081] Resin 60 parts

[0082] Nano and micro composite fillers 55 parts

[0083] 3 parts of adjuvant;

[0084] Wherein, the nanometer and micrometer composite fillers include the following components by weight:

[0085] Nanofiller 5 parts

[0086] 50 micron fillers

[0087] Coupling agent 1.2 parts.

[0088] Among them, the resin is polyethylene, the nano-filler is G-101 nano-calcium carbonate, the micro-filler is heavy calcium carbonate, the coupling agent is a zirconium type coupling agent, and the auxiliary agent is an antioxidant.

[0089] The preparation method of the composite resin material for the cable is as follows:

[0090] S11: Weigh the formula components: the formula of the above-mentioned composite resin material for cables is weighed respectively for each component;

[0091] S12: Preparation of m...

Embodiment 2

[0099]The weight percentage of the composite resin material for cables in this example is as follows, and the formula components are shown in Table 1 below.

[0100] Resin 60 parts

[0101] Nano and micro composite fillers 60 parts

[0102] 3 parts of adjuvant;

[0103] Wherein, the nanometer and micrometer composite fillers include the following components by weight:

[0104] Nanofiller 6 parts

[0105] Micron filler 54 parts

[0106] 1 part of coupling agent.

[0107] Among them, the resin is polyvinyl chloride, the nano-filler is G-101 nano-calcium carbonate, the micro-filler is ceramic powder, the coupling agent is zirconium type coupling agent, and the auxiliary agent is a stabilizer.

[0108] Refer to Example 1 for the preparation method of the composite resin material for cables.

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Abstract

The invention discloses a compound resin material for a cable and a preparation method thereof. The compound resin material for the cable comprises the following formula components in parts by weight: 35-65 parts of resin, 30-90 parts of nanometer and micrometer composite fillers and 1-30 parts of auxiliary agents. The compound resin material for the cable takes the resin as a main material, is endued with the advantages of excellent impact strength, surface scratch resistant capacity, bending strength and electrical insulation property, ageing resistance and high smoothness through the synergetic effect of the nanometer and micrometer composite fillers and the auxiliary agents. By using the preparation method of the compound resin material for the cable, the product can be obtained by only mixing the components in two steps according to a formula and extruding for granulation at appropriate temperature and has the advantages of simple process, material property enhancement and low cost and is suitable for industrialized production, and conditions are easy to control.

Description

technical field [0001] The invention belongs to the technical field of organic polymer materials, and particularly relates to a composite resin material for cables and a preparation method thereof. Background technique [0002] Cables are usually buried underground, and the insulating material on the surface needs to have strong impact strength and surface scratch resistance. Usually, the insulating material for cables is resin material, which has limited mechanical strength. At present, some people use nano-modified resin materials to change the aggregation state and crystalline morphology of the resin materials, so as to have new properties, which greatly improves the overall performance of the materials while overcoming the incompatibility between the rigidity and toughness of traditional materials. , such as impact strength. Nanotechnology has gradually attracted people's attention, and the research and development of nanocomposite materials has also become a new hot s...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/06C08L27/06H01B3/44H01B7/17C08K13/06C08K9/10C08K3/26C08K3/00C08K3/36B29C47/92B29C48/92
CPCB29C48/92
Inventor 郭挺科刘北喜
Owner SHENZHEN BENDAKANG CABLE
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