Environmentally friendly metal cleaner with anti-corrosion function
A technology of metal cleaning agent and cleaning main agent, which is applied in the field of cleaning agent, can solve problems such as complex process, environmental hazards, and metal surface damage, and achieve the effect of low corrosion and strong degreasing effect
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Embodiment 1
[0039] The preparation of embodiment 1 chloride 1-hydroxyethyl-3-hexadecyl imidazole
[0040] Mix 1.79 g of imidazole and 3.8 mL of hexadecane bromide (the molar ratio of substances is 2:1) in 35 mL of ethyl acetate, stir for 10 minutes with magnetic force and mix well. Pour the mixture into a polytetrafluoroethylene liner with a capacity of 60mL, seal the polytetrafluoroethylene liner into a stainless steel reactor, and put it into a digital oven, heat it from room temperature to 120°C for 16 hours, and then cool it naturally to room temperature. Then the mixture was filtered to take out the filtrate, washed several times with distilled water to remove the imidazole that did not participate in the reaction, and the solvent ethyl acetate was evaporated with a rotary evaporator, and the resulting product 1-hexadecyl imidazole was dried in a vacuum oven at 70°C for 12 hours to constant weight. Obtain pale yellow liquid, weigh the product, mix 2.9g of 1-hexadecyl imidazole and ...
Embodiment 2
[0041] Embodiment 2ω, the preparation of ω '-two (benzimidazol-2-yl) alkanes
[0042] Weigh 0.11 mol of o-phenylenediamine and 0.05 mol of fatty diacid respectively, thoroughly grind them in a mortar to make them evenly mixed, and transfer them to a three-necked flask. Add mixed acid, pass through nitrogen, and heat to reflux under mechanical stirring. TLC tracking and monitoring until the end of the reaction, about 10h, pour it into a 250mL beaker, let it stand for cooling, and adjust the pH=7 with concentrated ammonia water. Stand overnight at 4°C, filter and dry with suction, and recrystallize the crude product with methanol / water to obtain a pure product.
Embodiment 3
[0043] Embodiment 3: metal cleaning agent 1
[0044] Antifoaming agent tributyl phosphate 2g, cationic surfactant distearyl dimethyl ammonium chloride 8g, anionic surfactant sodium tosyl sulfonate 6g, as nonionic surfactant trade name Silicon surfactant 12g, sodium phosphate 20g and sodium silicate 10g, 1-hydroxyethyl-3-hexadecylimidazole chloride 2g prepared in Example 1, ω prepared in Example 2, ω'-bis( Dissolve 2 g of benzimidazol-2-yl)alkane in deionized water and stir for about 30 minutes to obtain the product.
[0045] Comparative Example 1 Metal cleaning agent 2
[0046] Antifoaming agent tributyl phosphate 2g, cationic surfactant distearyl dimethyl ammonium chloride 8g, anionic surfactant sodium tosyl sulfonate 6g, as nonionic surfactant trade name 12g of silicon surfactant, 20g of sodium phosphate and 10g of sodium silicate, 4g of 1-hydroxyethyl-3-hexadecylimidazole chloride prepared in Example 1 were dissolved in deionized water and stirred for about 30 minutes t...
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