A kind of hydrophobic, anti-ultraviolet aging wood-based composite material and its preparation method

A composite material and anti-ultraviolet technology, applied in wood treatment, impregnated wood, wood impregnation, etc., can solve the problems of reducing the degree of material photodegradation, moisture absorption, water absorption, etc., achieve high promotion and application value, high raw material utilization rate, and convenient The effect of mass production

Inactive Publication Date: 2016-02-24
SOUTHWEST FORESTRY UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, in the field of research and development of wood-based composite materials that are hydrophobic and anti-ultraviolet aging, researchers generally use anatase-type titanium dioxide to modify the surface of wood-based substrates to reduce the degree of photodegradation and moisture absorption and water absorption of the material. The construction of titanium dioxide on the surface of wood substrates is rarely reported

Method used

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  • A kind of hydrophobic, anti-ultraviolet aging wood-based composite material and its preparation method
  • A kind of hydrophobic, anti-ultraviolet aging wood-based composite material and its preparation method
  • A kind of hydrophobic, anti-ultraviolet aging wood-based composite material and its preparation method

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preparation example Construction

[0022] The preparation method of the hydrophobic and anti-ultraviolet aging wood-based composite material of the present invention includes preparation of precursor solution, multi-stage impregnation and drying process, specifically including:

[0023] The preparation of the precursor solution refers to dispersing the water-soluble titanium source in a 5-7mol / L sodium chloride aqueous solution, stirring evenly to obtain solution a, so that the concentration of the water-soluble titanium source in the solution is 0.001-0.500 mol / L; add the alkaline substance into the solution a and stir evenly to obtain solution b, namely the precursor solution, so that the concentration of the alkaline substance in the solution is 0.001-0.500mol / L.

[0024] The first-level impregnation and drying refers to immersing the wood substrate to be treated in the precursor solution, reacting at room temperature for 1-10 days, taking out the treated wood substrate, washing with water, and drying at room...

Embodiment 1

[0041] (1) Preparation of the hydrophobic and anti-ultraviolet aging wood-based composite material of the present invention

[0042] Disperse titanium trichloride in 6 mol / L sodium chloride aqueous solution, and stir evenly with magnetic force to obtain solution a, so that the concentration of titanium trichloride in the solution is 0.500 mol / L. Add sodium hydroxide to solution a, and stir evenly with magnetic force to obtain solution b, namely the precursor solution, so that the concentration of sodium hydroxide in the solution is 0.500 mol / L.

[0043] Cut Yunnan pine wood with a moisture content of 10% into pieces of 0.1cmx1.58cmx5.13cm, immerse in the precursor solution, react at room temperature for 5 days, take out the treated wood chips, and wash them with deionized water , and dried at room temperature for 2 days to obtain a wood-based composite material whose surface layer is a titanium dioxide layer with a rutile micro-nano secondary structure.

[0044] Immerse the woo...

Embodiment 2

[0049] (1) Preparation of the hydrophobic and anti-ultraviolet aging wood-based composite material of the present invention

[0050] Disperse titanium tetrachloride in a 5 mol / L sodium chloride aqueous solution, and stir evenly with a magnetic force to obtain solution a, so that the concentration of titanium tetrachloride in the solution is 0.010 mol / L. Add ethylenediamine into solution a, and stir evenly with magnetic force to obtain solution b, that is, the precursor solution, so that the concentration of ethylenediamine in the solution is 0.010 mol / L.

[0051] Cut Yunnan pine wood with a moisture content of 15% into pieces of 0.1cmx1.58cmx5.13cm, immerse in the precursor solution, react at room temperature for 1d, take out the treated wood chips, and wash them with deionized water , and dried at room temperature for 1 day to obtain a wood-based composite material whose surface layer is a titanium dioxide layer with a rutile micro-nano secondary structure.

[0052] Immerse ...

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Abstract

The invention discloses a hydrophobic and anti-ultraviolet aging wood-based composite material and a preparation method thereof. The surface layer of the composite material is a titanium dioxide layer with a micro-nano secondary structure, and its crystal structure is rutile. The preparation method includes precursor solution preparation, multi-stage impregnation and drying processes. First, the water-soluble titanium source is uniformly dispersed in 5-7mol / L sodium chloride aqueous solution to obtain solution a, so that the concentration of the water-soluble titanium source is 0.001 ~0.500 mol / L; uniformly add the alkaline substance into the solution a to obtain a precursor solution, so that the concentration of the alkaline substance is 0.001~0.500mol / L. Immerse the wood-based substrate in the precursor solution, react at room temperature for 1-10 days, wash and dry for 1-2 days, immerse the obtained wood-based composite material in a 0.8-1.2% solution of low surface energy substances, and react at room temperature for 0.2 ~1d, dry for 1~2d. The preparation method can construct a titanium dioxide surface layer with a rutile-type secondary micro-nano structure on the surface of the wood substrate, so that the wood-based composite material has excellent hydrophobicity and ultraviolet aging resistance.

Description

technical field [0001] The invention belongs to the technical field of wood-based composite materials, and in particular relates to a wood-based composite material which is hydrophobic and anti-ultraviolet aging and a preparation method thereof. Background technique [0002] Wood-based materials and their products are the only biological materials among the four most widely used materials (steel, cement, wood and plastic) in daily life and economic construction. They have high strength-to-weight ratio, easy bonding, moderate rigidity and flexibility, and can be recycled Take advantage of other advantages. The cell wall of wood-based materials is mainly composed of three components: cellulose, hemicellulose and lignin, all of which contain hydroxyl functional groups, so wood-based materials are naturally hydrophilic. When it is exposed to the outdoors, natural aging will gradually occur under the synergistic effect of factors such as water, sunlight, and microorganisms. Amo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B27K3/02B27K3/32B27K3/50B27K3/52B27K9/00
CPCB27K3/02B27K3/32B27K3/50B27K3/52B27K5/04B27K9/00B27K9/002B27K2240/70B27K2240/90
Inventor 郑荣波郭雪莲
Owner SOUTHWEST FORESTRY UNIVERSITY
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