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Hydrophobic and ultraviolet radiation aging-resistant wood-based composite material and preparation method thereof

A composite material, anti-ultraviolet technology, applied in wood treatment, impregnated wood, wood impregnation, etc., can solve the problems of reducing the degree of material photodegradation and moisture absorption, water absorption, etc., to achieve high promotion and application value, mild reaction conditions, and weather resistance outstanding effect

Inactive Publication Date: 2015-01-07
SOUTHWEST FORESTRY UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, in the field of research and development of wood-based composite materials that are hydrophobic and anti-ultraviolet aging, researchers generally use anatase-type titanium dioxide to modify the surface of wood-based substrates to reduce the degree of photodegradation and moisture absorption and water absorption of the material. The construction of titanium dioxide on the surface of wood substrates is rarely reported

Method used

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  • Hydrophobic and ultraviolet radiation aging-resistant wood-based composite material and preparation method thereof
  • Hydrophobic and ultraviolet radiation aging-resistant wood-based composite material and preparation method thereof
  • Hydrophobic and ultraviolet radiation aging-resistant wood-based composite material and preparation method thereof

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preparation example Construction

[0022] The preparation method of the hydrophobic and anti-ultraviolet aging wood-based composite material of the present invention includes preparation of precursor solution, multi-stage impregnation and drying process, specifically including:

[0023] The preparation of the precursor solution refers to dispersing the water-soluble titanium source in a 5-7mol / L sodium chloride aqueous solution, stirring evenly to obtain solution a, so that the concentration of the water-soluble titanium source in the solution is 0.001-0.500 mol / L; add the alkaline substance into the solution a and stir evenly to obtain solution b, namely the precursor solution, so that the concentration of the alkaline substance in the solution is 0.001-0.500mol / L.

[0024] The first-level impregnation and drying refers to immersing the wood substrate to be treated in the precursor solution, reacting at room temperature for 1-10 days, taking out the treated wood substrate, washing with water, and drying at room...

Embodiment 1

[0041] (1) Preparation of the hydrophobic and anti-ultraviolet aging wood-based composite material of the present invention

[0042] Disperse titanium trichloride in 6 mol / L sodium chloride aqueous solution, and stir evenly with magnetic force to obtain solution a, so that the concentration of titanium trichloride in the solution is 0.500 mol / L. Add sodium hydroxide to solution a, and stir evenly with magnetic force to obtain solution b, namely the precursor solution, so that the concentration of sodium hydroxide in the solution is 0.500 mol / L.

[0043] Cut Yunnan pine wood with a moisture content of 10% into pieces of 0.1 cm x 1.58 cm x 5.13 cm, immerse in the precursor solution, and react at room temperature for 5 days, take out the treated wood chips, and rinse with deionized water Wash and dry at room temperature for 2 days to obtain a wood-based composite material whose surface layer is a titanium dioxide layer with a rutile micro-nano secondary structure.

[0044] I...

Embodiment 2

[0049] (1) Preparation of the hydrophobic and anti-ultraviolet aging wood-based composite material of the present invention

[0050] Disperse titanium tetrachloride in a 5 mol / L sodium chloride aqueous solution, and stir evenly with a magnetic force to obtain solution a, so that the concentration of titanium tetrachloride in the solution is 0.010 mol / L. Add ethylenediamine into solution a, and stir evenly with magnetic force to obtain solution b, that is, the precursor solution, so that the concentration of ethylenediamine in the solution is 0.010 mol / L.

[0051] Cut Yunnan pine wood with a moisture content of 15% into slices of 0.1 cm x 1.58 cm x 5.13 cm, immerse in the precursor solution, and react at room temperature for 1 day, take out the treated wood slices, and rinse with deionized water Wash and dry at room temperature for 1 day to obtain a wood-based composite material whose surface layer is a titanium dioxide layer with a rutile micro-nano secondary structure. ...

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Abstract

The invention discloses a hydrophobic ultraviolet radiation aging-resistant wood-based composite material and a preparation method thereof. The surface layer of the composite material is of a titanium dioxide layer with a micro-nano secondary structure and the crystal structure of the composite material is of a rutile type. The preparation method comprises the processes of precursor solution preparation, multistage dipping and drying: firstly dispersing a water-soluble titanium source in a 5-7mol / L sodium chloride aqueous solution to obtain a solution a, wherein the concentration of the water-soluble titanium source is guaranteed to be 0.001-0.500 mol / L; uniformly adding an alkaline matter into the solution a to obtain a precursor solution, wherein the concentration of the alkaline matter is guaranteed to be 0.001-0.500 mol / L; dipping a wooden base material into the precursor solution, reacting at a room temperature for 1-10 days, cleaning and drying for 1-2 days to obtain a wood-based composite material; dipping the wood-based composite material in 0.8-1.2% of a low-surface energy matter solution, reacting at a room temperature for 0.2-1 day and drying for 1-2 days to obtain the hydrophobic ultraviolet radiation aging-resistant wood-based composite material. According to the preparation method, a titanium dioxide surface layer with a rutile type micro-nano secondary structure can be constructed on the surface of the wooden base material so that the wood-based composite material is excellent in hydrophobicity and ultraviolet radiation aging resistance.

Description

technical field [0001] The invention belongs to the technical field of wood-based composite materials, and in particular relates to a wood-based composite material which is hydrophobic and anti-ultraviolet aging and a preparation method thereof. Background technique [0002] Wood-based materials and their products are the only biological materials among the four most widely used materials (steel, cement, wood and plastic) in daily life and economic construction. They have high strength-to-weight ratio, easy bonding, moderate rigidity and flexibility, and can be recycled Take advantage of other advantages. The cell wall of wood-based materials is mainly composed of three components: cellulose, hemicellulose and lignin, all of which contain hydroxyl functional groups, so wood-based materials are naturally hydrophilic. When it is exposed to the outdoors, natural aging will gradually occur under the synergistic effect of factors such as water, sunlight, and microorganisms. Amo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B27K3/02B27K3/32B27K3/50B27K3/52B27K9/00
CPCB27K3/02B27K3/32B27K3/50B27K3/52B27K5/04B27K9/00B27K9/002B27K2240/70B27K2240/90
Inventor 郑荣波郭雪莲
Owner SOUTHWEST FORESTRY UNIVERSITY
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