The invention relates to a method for enhancing hydrophilic stability of a macromolecular film by using metal ions to complex with polyphenol. The method comprises the following steps of firstly, soaking the macromolecular film or an organic surface into an alcohol solvent or water, or cleaning; fetching out, and soaking by a mixed solution containing a crosslinking agent and hydrophilic moleculesfor the second time; fetching out, soaking into a mixed solution containing a polyphenol compound and a mixed solution containing metal ions, and modifying the surface for the third time and the fourth time; finally, fetching out, cleaning and drying. The method has the advantages that the conditions are mild, the operation is simple and convenient, the cost is lower, and the like; the hydrophilic property, anti-oil dirt property and hydrophilic stability of the obtained modified macromolecular film or the inorganic surface are obviously enhanced, the application range of the raw materials isgreatly broadened, and the popularization and application prospect is better.