The invention discloses a preparation method and application of a layered column three-dimensional MOF enhanced
mixed matrix membrane, and belongs to the technical field of
pervaporation membrane separation. The preparation method comprises the following steps: firstly, dissolving a
copper metal source and 2, 3, 6, 7, 10, 11-hexahydroxytribenzene in a
solvent to obtain Cu < 2 + > and a deprotonated organic ligand, adding a pillar ligand
bipyridine in situ, and co-coordinating the double ligand and Cu < 2 + > to generate a layered column three-dimensional MOF (
Metal Organic Framework); and
doping the layered column three-dimensional MOF into a
polymer matrix to prepare a membrane
casting solution, and
coating the surface of a support body with the membrane
casting solution to prepare the layered column three-dimensional MOF enhanced
mixed matrix membrane. According to the invention, the pillar ligand dipyridyl provides a supporting effect for the three-dimensional MOF and constructs a three-dimensional pore channel at the same time; the affinity site of the three-dimensional MOF has conjugated pi-pi, hydrophobic and
hydrogen bond interaction on the perfume; the three-dimensional MOF and a high-molecular
polymer have excellent compatibility, and the
mixed matrix membrane simultaneously has affinity of the three-dimensional MOF to 2-PE and hydrophobicity of a
polymer matrix; the
pervaporation membrane can be used for
pervaporation membrane perfume separation.