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Water-based soft bio-antifouling paint and preparation method thereof

An antifouling paint, soft biomass technology, applied in antifouling/underwater paints, coatings, paints containing biocides, etc., can solve problems such as toxic and harmful, high VOC emissions, unfavorable environmental protection, etc., to save energy , reduce pollution, prolong the effect of anti-fouling period

Active Publication Date: 2016-06-08
舟山市知识产权促进会
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the existing various antifouling coatings have good antifouling performance, most of them are toxic and harmful, and have high VOC emissions, which is not conducive to environmental protection

Method used

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  • Water-based soft bio-antifouling paint and preparation method thereof
  • Water-based soft bio-antifouling paint and preparation method thereof
  • Water-based soft bio-antifouling paint and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Embodiment 1 Preparation of water-based soft biomass flexible cross-linked antifouling coating

[0020] (1) Synthesis of water-based acrylic resin

[0021] Add 0.2g of benzoyl peroxide and 200g of ethanol to a four-neck flask equipped with a stirrer, reflux condenser, and constant pressure dropping funnel, raise the temperature to 78°C, and then add 12g of acrylic acid, 46g of methyl The mixed solution of methyl acrylate, 71g ethyl acrylate, 63g butyl acrylate, 8g hydroxyethyl acrylate, and 1.6g benzoyl peroxide was added dropwise at a constant speed for 3 hours with a constant pressure dropping funnel, and 0.2g over Oxidize benzoyl, continue the constant temperature reaction (78°C, the same below) for 3 hours, then cool to room temperature, add 25g of ammonia water to adjust the pH to neutral, and complete the reaction after stirring for 2h to obtain a water-based acrylic resin.

[0022] (2) Preparation of water-based soft biomass flexible cross-linked antifouling coa...

Embodiment 2

[0029] Embodiment 2 The preparation of water-based soft biomass self-gelling antifouling paint

[0030] (1) Synthesis of modified water-based acrylic resin

[0031] Add 0.2g of benzoyl peroxide and 200g of ethanol to a four-neck flask equipped with a stirrer, reflux condenser, and constant pressure dropping funnel, raise the temperature to 78°C, and then add 12g of acrylic acid, 46g of methyl Methyl acrylate, 61g ethyl acrylate, 63g butyl acrylate, 10g γ-(methacryloyloxy) propyltrimethoxysilane, 8g hydroxyethyl acrylate, 1.6g benzoyl peroxide mixed solution, use constant After 3 hours of constant-speed dripping into the pressure dropping funnel, add 0.2g of benzoyl peroxide, continue the constant temperature reaction for 3 hours, cool to 60°C, add 20g of hydroxyl silicone oil, react for 12h, cool to room temperature, add 15g of ammonia water to adjust pH and the hydrophilicity of the resin, the reaction is completed after stirring for 2 hours, and the modified water-based acr...

Embodiment 3

[0039] Embodiment 3: Preparation of water-based soft biomass self-repairing antifouling coating

[0040] (1) Synthesis of modified water-based acrylic resin

[0041]Add 0.2g of benzoyl peroxide and 200g of ethanol to a four-necked flask equipped with a stirrer, reflux condenser, and constant pressure dropping funnel, raise the temperature to 78°C, and then add 12g of acrylic acid, 46g of methyl Methyl acrylate, 61g ethyl acrylate, 63g butyl acrylate, 10g γ-(methacryloyloxy) propyltrimethoxysilane, 8g hydroxyethyl acrylate, 1.6g benzoyl peroxide mixed solution, use constant After 3 hours of constant-speed dropwise addition of the pressure dropping funnel, add 0.2g of benzoyl peroxide, continue the constant temperature reaction for 3 hours, cool to 60°C, add 20g of hydroxyl silicone oil, react for 12h, cool to room temperature, add 15g of ammonia water to adjust pH and the hydrophilicity of the resin, the reaction is completed after stirring for 2 hours to obtain a water-based ...

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Abstract

The invention belongs to the technical field of marine protection, and in particular relates to a water-based soft biomass antifouling paint and a preparation method thereof. A water-based soft bio-antifouling paint, the paint comprises A, B two-component, A, B component mass ratio is 8-10:1, wherein A component is the resin base material carrier, the mass fraction ratio is : Water-based acrylic resin 60-66%, red iron oxide 0-6%, zinc oxide 5%, active silica 0-3%, organic bentonite 0-1%, zinc pyrithione 3-4%, pyrithione Copper 3-4%, antifouling agent 9-10%, ethanol 5%, water 6%; B component is a crosslinking agent. The formula adopted in the invention is nontoxic and harmless, and the antifouling paint obtained after mixing has good antifouling effect.

Description

technical field [0001] The invention belongs to the technical field of marine protection, and in particular relates to a water-based soft biomass antifouling paint and a preparation method thereof. Background technique [0002] It is well known that the most effective and economical way to deal with marine biofouling is to use antifouling coatings. The development of antifouling coatings has gone through several generations, and a complete set of coating resin preparation technology represented by self-polishing type and low surface energy type has been formed, which greatly promotes the development of marine coatings. Although the existing various antifouling coatings have good antifouling properties, most of them are toxic and harmful, and have high VOC emissions, which is not conducive to environmental protection. Contents of the invention [0003] The invention provides a water-based soft biomass antifouling paint which not only meets the requirement of environmental ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D133/08C09D5/16C09D7/12C08F220/18C08F220/14C08F220/06C08F220/28C08F230/08C08F220/56C08F283/06
CPCC08F220/06C08F220/14C08F220/18C08F220/1804C08F220/28C08F220/281C08F220/286C08F220/56C08F230/08C08F283/065C09D5/1625C09D7/61C09D133/08C08K13/02C08K2003/2272C08K2003/2296C08K3/36C08K3/346C08K5/36C08K5/3412
Inventor 胡建坤严山李娟陆阿定徐焕志
Owner 舟山市知识产权促进会
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