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Lime sintering treatment method and clinker prepared by the method

A treatment method, lime sintering technology, applied in the direction of alumina/aluminum hydroxide, etc., can solve the problems of large amount of leached slag and large amount of lime added, achieve good economic and social benefits, improve leaching performance, and low cost Effect

Active Publication Date: 2016-01-20
HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when the calcium ratio of the clinker system reaches about 2.0, the amount of lime added is too large, and the amount of leached slag is large.
[0005] At present, there is no sintering method in the prior art that can control the calcium ratio at a low level and improve the leaching performance of alumina in clinker

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] 100kg of low-grade bauxite is crushed and ground, and the chemical composition of the low-grade bauxite in terms of mass percentage is: Al 2 o 3 55.5%, SiO 2 20.8%, Fe 2 o 3 7.5%, and the rest are impurities; after grinding, the particles with a particle size less than 0.074mm account for more than 85%; then add limestone according to the calcium ratio C / A=1.4, the amount of limestone added is 170kg, and the chemical composition of limestone expressed in mass percentage It is: CaO50.9%, MgO2.6%, and the rest are impurities; the amount of calcium sulfate added is 4% of the total mass of bauxite and limestone; the materials are mixed and heated from room temperature to simulate the sintering process of the rotary kiln. Raise the sintering temperature to 1000°C at a heating rate of 10°C / min, and then raise the temperature to 1400°C at a heating rate of 20°C / min, keep it at this temperature for 30 minutes, and then cool naturally in the furnace; the obtained clinker Due...

Embodiment 2

[0024]100kg of low-grade bauxite is crushed and ground, and the chemical composition of the low-grade bauxite in terms of mass percentage is: Al 2 o 3 50.3%, SiO 2 14.7%, Fe 2 o 3 10.2%, the rest are impurities; after grinding, the particles with a particle size less than 0.074mm account for more than 85%; then add limestone according to the calcium ratio C / A=1.2, the amount of limestone added is 117kg, and the chemical composition of limestone expressed in mass percentage It is: CaO57.8%, MgO3.9%, and the rest are impurities; the amount of calcium sulfate added is 10% of the total mass of bauxite and limestone; the materials are mixed and heated from room temperature, first at 10 °C / min The heating rate raises the sintering temperature to 1000°C, then raises the temperature to 1400°C at a rate of 20°C / min, and keeps it at this temperature for 15 minutes, and then cools naturally in the furnace; 2 The existence of clinker, the clinker will be self-pulverized, and the parti...

Embodiment 3

[0029] 100kg of low-grade bauxite is crushed and ground, and the low-grade bauxite is composed of the following components with corresponding mass fractions: Al 2 o 3 41.8%, SiO 2 19.2%, Fe 2 o 3 14.7%, and the rest are impurities; after grinding, the particles with a particle size less than 0.074mm account for more than 85%; then add limestone according to the calcium ratio C / A=1.4, the amount of limestone added is 185kg, and the chemical composition of limestone is calculated by mass percentage It is: CaO42.3%, MgO0.6%, and the rest are impurities; the amount of calcium sulfate added is 4% of the total mass of bauxite and limestone; the materials are mixed and sintered, and the temperature is kept at 1375 ° C for 60 minutes during sintering , and then naturally cooled in the furnace; the obtained clinker has γ-2CaO·SiO 2 The clinker is self-pulverized, and the particles with a particle size of less than 0.074mm in the clinker can reach more than 90%; the clinker contains...

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Abstract

The invention discloses a lime sintering treatment method and clinker prepared by the same and belongs to the technical field of production of aluminum oxide. The method comprises the following steps of mixing bauxite, calcium sulfate, and limestone containing magnesium oxide impurity, sintering, carrying out heat preservation at a temperature of 1300-1400 DEG C for 15-120 minutes during the sintering and then cooling to obtain the clinker which comprises Al2O3, SiO2, Fe2O3, CaO, MgO and other ingredients and the phase mainly comprises 3CaO.3Al2O3.CaSO4, 12CaO.7Al2O3, 2CaO.SiO2 and MgO. The method is low in cost, convenient to implement, simple and effective; by the method, magnesium oxide in the clinker can be precipitated in a form of periclase, the leaching performance of the clinker in aluminum oxide is improved and the method has better economic and social benefits.

Description

technical field [0001] The invention relates to the technical field of alumina production. Background technique [0002] With the rapid development of my country's aluminum industry, the shortage of bauxite resources has become increasingly serious. At present, the soda-lime sintering method is mostly used in alumina factories to process low-grade bauxite. Due to the serious secondary reaction in the alumina leaching process, the alumina leaching rate of clinker is not high. Another method of processing bauxite is lime sintering. The so-called lime sintering method is a method of adding limestone to bauxite for sintering. The main phase composition of the clinker obtained by this method is 12CaO·7Al 2 o 3 (C 12 A 7 ) and γ-2CaO SiO 2 (γ-C 2 S). Compared with the soda-lime sintering method, the lime sintering method can process a variety of low-grade aluminum-containing ores or raw materials, especially the high-iron bauxite and fly ash with very rich reserves, and ha...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01F7/02
CPCC01F7/02
Inventor 王波孙会兰楚维亲于海燕毕诗文
Owner HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY