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A method for measuring co in three-dimensional seepage process 2 Soluble surfactants in co 2 Concentration distribution device and method in water system

A surfactant and concentration distribution technology, applied in the direction of measuring devices, material separation, and analysis of materials, can solve the problems of no measurement and achieve high accuracy and simple operation

Active Publication Date: 2017-05-17
CHINA UNIV OF PETROLEUM (EAST CHINA)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] The patent application number CN201110191927.4 discloses a preparation method and concentration determination of a low-concentration viscoelastic surfactant solution. Some related studies have only measured the distribution coefficient and concentration distribution of the compound in water or oil, but not The three-dimensional seepage process and CO 2 Soluble surfactants in CO 2 / method of concentration distribution in water systems, without the determination of CO in three-dimensional seepage processes 2 Soluble surfactants in CO 2 Method and device for concentration distribution in water system

Method used

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  • A method for measuring co in three-dimensional seepage process  <sub>2</sub> Soluble surfactants in co  <sub>2</sub> Concentration distribution device and method in water system
  • A method for measuring co in three-dimensional seepage process  <sub>2</sub> Soluble surfactants in co  <sub>2</sub> Concentration distribution device and method in water system

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Embodiment 1

[0025] Embodiment 1: as figure 1 , 2 As shown, a method for measuring CO in three-dimensional seepage process 2 Soluble surfactants in CO 2 A device for concentration distribution in a water system, including a square three-dimensional core model 1 filled with quartz sand; the three-dimensional core model 1 includes a square metal shell 9-4, and the length, width, and thickness of the shell 9-4 are respectively 100cm . There are 21 sampling ports 8 on the top surface and one side of the three-dimensional core model 1 respectively, a total of 42 sampling ports 8, and the three-dimensional core model 1 is surrounded by a heating insulation jacket.

[0026] The inlet of the three-dimensional core model 1 is connected to a phase-parallel emulsion generator and a crude oil injection device through a six-way valve 7, and the inlet of the emulsion generator is connected to a phase-parallel CO 2 Gas injection device and surfactant injection device; the outlet end of the three-dime...

Embodiment 2

[0028] Embodiment 2: a kind of method described in embodiment 1 measures CO in the three-dimensional seepage process 2 Soluble surfactants in CO 2 The measuring method that the device of concentration distribution in the / water system carries out, comprises the following steps:

[0029] Step 1, heating the core temperature of the three-dimensional core model 1 to 30°C-90°C, and maintaining the temperature for 10-12 hours, and then setting the back pressure to the back pressure valve 10 through the gas source bottle 11 to add confining pressure to the core ;Set the back pressure to 10MPa, which is the outlet pressure of the sand-packing model, which determines the reservoir conditions where the sand-packing model is located;

[0030] Step 2, vacuumize the core of the three-dimensional core model 1 and saturate it with water, then pump crude oil into the core at a flow rate of 1ml / min until the core is displaced by crude oil to the state of irreducible water;

[0031] Step 3, ado...

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Abstract

A device for measuring the concentration distribution of CO2 soluble surfactant in the CO2 / water system in the three-dimensional seepage process of the present invention comprises a three-dimensional core model; the inlet end of the three-dimensional core model is connected with a phase-parallel emulsion generator and crude oil injection device, the inlet of the emulsion generator is connected to a parallel CO2 gas injection device and a surfactant injection device; the outlet of the three-dimensional core model is connected to a parallel gas source bottle and a liquid storage bottle through a back pressure valve, and the three-dimensional core model A number of equally spaced sampling ports are opened on the top surface and one side, and the sampling ports are connected with the rock core in the three-dimensional core model, and each sampling port is connected with a sampler through a pipeline with a valve. Samples were taken at different parts of the model, the water phase and the CO2 phase were separated, the CO2 phase samples were dissolved in water, and the concentration of the surfactant was detected by high performance liquid chromatography (HPLC). The device and method of the invention are simple to operate and have high measurement accuracy.

Description

technical field [0001] The invention relates to a method for measuring CO in the process of three-dimensional seepage 2 Soluble surfactants in CO 2 A concentration distribution device and method in a water system belong to the technical field of oil and gas field development engineering. Background technique [0002] Due to CO 2 It is a gas with high solubility in oil and water, CO 2 Flooding is low cost, effective, recyclable and reusable, non-toxic and environmentally friendly. When it is dissolved in a large amount of crude oil, it can expand the volume of crude oil and reduce its viscosity. It can also reduce the interfacial tension between oil and water and enhance oil recovery. . It has good application prospects in low permeability reservoirs, high water cut reservoirs and deep reservoirs, and CO injection 2 Gas can reduce CO in the air 2 amount, reduce the greenhouse effect, and is conducive to environmental protection. But under reservoir conditions, CO 2 Ge...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N30/02G01N30/06
Inventor 李兆敏刘己全李松岩王壮壮张习斌丁立苹叶金桥张昀
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)