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Duplex stainless steel material and duplex stainless steel pipe

A technology of duplex stainless steel and steel, applied in the field of duplex stainless steel and duplex stainless steel pipe, can solve problems such as insufficient hot workability, and achieve the effect of good hot workability and good corrosion resistance

Inactive Publication Date: 2015-09-16
KOBE STEEL LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, the increase of Cr and Mo added for the purpose of improving corrosion resistance promotes the precipitation of σ phase, so depending on the application, hot workability may also be insufficient

Method used

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  • Duplex stainless steel material and duplex stainless steel pipe
  • Duplex stainless steel material and duplex stainless steel pipe
  • Duplex stainless steel material and duplex stainless steel pipe

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0109] [Example 1: Example regarding Ta-containing steel]

[0110] (Preparation of sample)

[0111] Steels having the compositions shown in Table 1 (steel symbols A to Z) were melted using a molten steel processing facility equipped with an electrode arc heating function, and cast using a 50 kg circular mold (body: about φ140×320 mm). The solidified steel ingot was heated to 1200°C, hot forged at this temperature, then cut, subjected to solution heat treatment held at 1100°C for 30 minutes, and water-cooled to be processed into a 600 × 120 × 60 mm steel forging product (test). Material No.1~26).

[0112] In addition, PRE=[Cr]+3.3[Mo]+16[N] of each steel was calculated, and Table 1 also shows the result. In addition, the processed steel forgings were embedded with a cross section parallel to the machining direction, mirror-polished, electrolytically etched in an oxalic acid aqueous solution, and then observed with an optical microscope at a magnification of 100 times to confi...

Embodiment 2

[0126] [Example 2: Example concerning Ge-containing steel]

[0127] (Preparation of test materials No. 1 to 17)

[0128] Using the molten steel processing equipment with the electrode electric heating function, the stainless steel with the composition shown in Table 3 (the balance is Fe and unavoidable impurities) was melted separately, and a 50kg rectangular casting mold (body: about 120×450mm) was used. cast. In addition, Table 3 also shows the results of calculating the PRE value for the structure of each steel. In addition, in Table 3, the blank column shows that this component is not contained. The solidified steel ingot was heated to 1200° C., hot forged at this temperature, and processed into a steel forging product of 600×120×60 mm. Then, it cut|disconnected, was hold|maintained at 1100 degreeC for 30 minutes as a heat processing, and performed water cooling.

[0129] (Extraction of test materials No. 1 to 17)

[0130] Next, using a sample (20 mm×30 mm×2 mmt) extr...

Embodiment 3

[0140] [Example 3: Example in the case of controlling sulfur-oxide-based composite inclusions in Ta-containing steel]

[0141] (production of steel)

[0142] Steels (steel grades: A1 to A16, B1 to B9) with the compositions shown in Table 4 were smelted using a molten steel processing facility equipped with an electrode electric arc heating function, and a 50 kg circular casting mold (body: about φ140×320 mm) was used. ) for casting. In addition, Table 4 also shows the calculation results of PRE=[Cr]+3.3[Mo]+16[N] for each steel. In addition, in the column of the component composition of Table 4, the blank column indicates that the component is not contained, and the balance is Fe and inevitable impurities.

[0143] The solidified steel ingot is heated to 1200°C, hot forged at this temperature (forging temperature: 1000 to 1200°C), and then cut. Next, cold rolling and solution heat treatment of holding at 1100° C. for 30 minutes were performed, water-cooled at a cooling rate...

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PUM

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Abstract

This duplex stainless steel material is composed of a ferrite phase and an austenite phase, and has a component composition that contains 0.100% by mass or less of C, 0.10-2.00% by mass of Si, 0.10-2.00% by mass of Mn, 0.050% by mass or less of P, 0.0100% by mass or less of S, 0.001-0.050% by mass of Al, 1.0-10.0% by mass of Ni, 22.0-28.0% by mass of Cr, 2.0-6.0% by mass of Mo and 0.20-0.50% by mass of N, while containing 0.01-0.50% by mass of Ta and / or 0.1-1.0% by mass of Ge, with the balance made up of Fe and unavoidable impurities.

Description

technical field [0001] The present invention relates to a duplex stainless steel material and a duplex stainless steel pipe used in an environment containing corrosive substances such as chloride, hydrogen sulfide, and carbon dioxide (hereinafter referred to as a corrosive environment). Background technique [0002] Stainless steel is a material that naturally forms a stable surface film mainly composed of Cr oxide called a passive film in a corrosive environment, and exhibits corrosion resistance. In particular, the duplex stainless steel consisting of a ferrite phase and an austenite phase is superior in strength properties, pitting corrosion resistance and stress corrosion cracking resistance compared to austenitic stainless steel and ferritic stainless steel . Due to these characteristics, duplex stainless steels are used as structural materials for umbilicals, seawater desalination plants, LNG vaporizers, and other seawater environments, and are used as structural mate...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C38/00C22C38/58
CPCC22C38/44C22C38/52C22C38/02C22C38/48C22C38/46C21D7/13C22C38/42C21D6/004C22C38/04C22C38/58C22C38/001C22C38/00C22C38/50C22C38/002C22C38/06C22C38/004C22C38/40
Inventor 衣笠润一郎西泽夏来二井裕瑛佐藤俊树
Owner KOBE STEEL LTD