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A kind of APT antistatic material and preparation method thereof

An anti-static, polyethylene terephthalate technology, applied in the field of APET anti-static material and its preparation, can solve the problems of difficult molding process, slow crystallization rate, poor impact performance, etc., and achieve good anti-static performance, Good mechanical strength, the effect of meeting the requirements of mechanical properties

Inactive Publication Date: 2016-07-13
JIN BAOLI TECH SUZHOU
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantages of PET are slow crystallization rate, difficult molding and processing, high molding temperature, long production cycle, and poor impact performance. Generally, its processability and physical properties are improved by reinforcement, filling, blending, etc., and the effect of glass fiber reinforcement is obvious. Resin rigidity, heat resistance, chemical resistance, electrical properties and weather resistance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] (1) Weigh 60kg of polyethylene terephthalate, 30kg of polyvinylidene chloride, 15kg of polyvinyl alcohol, 12kg of polyacetylene, 0.5kg of dimethylol acrylic acid, and 0.02kg of dicumyl peroxide, mix Uniform;

[0033] (2) Add the above components into a high-speed mixer and mix evenly at 1800 rpm, add 0.2kg of ground magnesium chloride and 0.2kg of aluminum chloride, remove air bubbles by ultrasonic, add to a twin-screw extruder, Add 3kg of poly-p-phenylene terephthalamide, 3kg of styrene oxide, and 1kg of p-(bischlorodimethylsilyl)benzene to the side feeding port of the machine, melt, extrude, dry, and pelletize to obtain APET antistatic Material.

[0034] The temperature of each section of the twin-screw extruder is as follows: the temperature of the first zone is 190°C, the temperature of the second zone is 220°C, the temperature of the third zone is 250°C, the temperature of the fourth zone is 270°C, and the temperature of the fifth zone is 230°C.

[0035] The perf...

Embodiment 2

[0037] (1) Weigh 60kg of polyethylene terephthalate, 30kg of polyvinylidene chloride, 15kg of polyvinyl alcohol, 12kg of polyacetylene, 0.5kg of dimethylol acrylic acid, 0.02kg of dicumyl peroxide, poly Acrylonitrile fiber 3kg and toner 1kg, mix evenly;

[0038] (2) Add the above components into a high-speed mixer and mix evenly at 1800 rpm, add 0.2kg of ground magnesium chloride and 0.2kg of aluminum chloride, remove air bubbles by ultrasonic, add to a twin-screw extruder, Add 3kg of poly-p-phenylene terephthalamide, 3kg of styrene oxide, and 1kg of p-(bischlorodimethylsilyl)benzene to the side feeding port of the machine, melt, extrude, dry, and pelletize to obtain APET antistatic Material.

[0039] The temperature of each section of the twin-screw extruder is as follows: the temperature of the first zone is 210°C, the temperature of the second zone is 240°C, the temperature of the third zone is 270°C, the temperature of the fourth zone is 285°C, and the temperature of the ...

Embodiment 3

[0042] (1) Weigh 70kg of polyethylene terephthalate, 35kg of polyvinylidene chloride, 18kg of polyvinyl alcohol, 15kg of polyacetylene, 1kg of dimethylol acrylic acid, 0.5kg of dicumyl peroxide, polypropylene 3kg of nitrile fiber and 1kg of toner, mix well;

[0043] (2) Add the above components into a high-speed mixer and mix them evenly at 2400 rpm, add 1kg of ground magnesium chloride and 1kg of aluminum chloride, remove air bubbles by ultrasonic, add to the twin-screw extruder, and in the twin-screw extruder Add 6 kg of poly-p-phenylene terephthalamide, 5 kg of styrene oxide, and 2 kg of p-(bischlorodimethylsilyl) benzene into the side feeding port of the side feeding port, melt, extrude, dry, and pelletize to obtain APET antistatic material.

[0044] The temperature of each section of the twin-screw extruder is as follows: the temperature of the first zone is 210°C, the temperature of the second zone is 240°C, the temperature of the third zone is 270°C, the temperature of ...

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PUM

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Abstract

The invention discloses an APET anti-static material and a manufacturing method thereof. The APET anti-static material comprises, by weight, 60-70 parts of polyethylene glycol terephthalate, 30-35 parts of polyvinylidene chloride, 15-18 parts of polyvinyl alcohol, 12-15 parts of polyacetylene, 3-6 parts of poly-p-phenylene terephthamide, 3-5 parts of styrene oxide, 1-2 parts of bis(bis-chlorin dimethylsilyl)benzene, 0.5-1 part of dimethylol acrylic acid, 0.2-1 part of magnesium chloride, 0.2-1 part of aluminum chloride and 0.02-0.5 part of dicumyl peroxide. The invention further provides the manufacturing method of the APET anti-static material.

Description

technical field [0001] The invention belongs to the field of antistatic materials, in particular to an APET antistatic material and a preparation method thereof. Background technique [0002] Polyethylene terephthalate (PET) is one of the most important varieties of thermoplastic polyester, commonly known as polyester resin. PET is obtained by transesterifying dimethyl terephthalate and ethylene glycol or esterifying terephthalic acid and ethylene glycol to synthesize bishydroxyethyl terephthalate, followed by polycondensation. Polyethylene terephthalate can be divided into APET, RPET and PETG. [0003] PET is a milky white or light yellow, highly crystalline polymer with a smooth and shiny surface. It has excellent physical and mechanical properties in a wide temperature range. The long-term use temperature can reach 120 ° C. It has excellent electrical insulation. Even at high temperature and high frequency, its electrical properties are still good, but its corona resist...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/02C08L27/08C08L29/04C08L49/00C08L77/10C08L33/20C08K13/02C08K5/54C08K5/09C08K3/16B29C47/92B29C48/92
Inventor 李明华
Owner JIN BAOLI TECH SUZHOU
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