Liquid electrophotographic printing ink with charge director system
A technology of liquid electrophotography and charge director, which can be applied in the directions of developer, electrography, instrument, etc., and can solve problems such as printing defects
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Embodiment 1
[0049] Example 1 – Preparation of liquid electrophotographic (LEP) inks
[0050] Several LEP inks use alkaline BariumPetronate (LT); Ba[(C 13 h 27 )-O-C(O)CH 2 CH(SO 3 - )C(O)-O-(C 13 h 27 )] 2 and BaHPO 4( SCD); isopropylamine dodecylbenzenesulfonate (GT); light isoparaffin oil (ISOPAR® L, ExxonMobile); ethylene acrylic acid copolymer, ethylene methacrylic acid copolymer; and Cabotmonarch800 to prepare . The percentages of LT, SCD and GT for different inks are shown in Table 1.
[0051] Table 1
[0052] Charged System No. SCD LT GT 1 0.04 0.1 0.06 2 0.02 0.1 0.06 3 0.01 0.1 0.06 4 0.04 0.08 0.06 5 0.04 0.06 0.04 6 0.04 0.04 0.06 7 0.04 0.1 0.04 8 0.04 0.1 0.02 9 0.04 0.1 0.01 10 0.02 0.08 0.04 11 0.04 0.14 0.06 12 0.03 0.1 0.08 13 0.05 0.08 0.03
[0053] LT – Alkaline BariumPetronate;
[0054] SCD-Ba[(C 13 h 27 )-O-C(O)CH 2 CH(SO 3 - )C(O)-O-(C 1...
Embodiment 2
[0056] Example 2 – Conductivity of LEP ink
[0057] During preparation, the conductivity of the LEP ink of Example 1 was tested after 3 hours and 18 hours of electrophorhetic mobility. The results are shown in Table 2.
[0058]
Embodiment 3
[0059] Example 3 – Evaluation of LEP Ink No.11
[0060] The LEP ink No. 11 of Example 1 was further evaluated for streak performance. The SCD / LT / GT ratio of LEP Ink No. 11 was slightly changed to provide two additional LEP inks (11a and 11b). In addition, a comparative LEP ink without the charge director system of the present invention was used as indicated by the SCD / LT / GT ratio. All inks were formulated according to the composition of LEP Ink No. 11 except for the ratio of SCD / LT / GT shown. Table 3 shows the obtained conductivity before and after printing.
[0061] table 3
[0062]
[0063] LT – Alkaline BariumPetronate;
[0064] SCD-Ba[(C 13 h 27 )-O-C(O)CH 2 CH(SO 3 - )C(O)-O-(C 13 h 27 )] 2 and BaHPO 4 ;
[0065] GT-dodecylbenzenesulfonic acid isopropylamine salt
[0066] As shown in Table 3, LEP inks No. 11, 11a and 11b achieved a low field conductivity of at least 20 pS / cm, while the comparative ink did not. The LEP inks are stable after printing a...
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