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A kind of manganese carbonate ore pretreatment method

A manganese carbonate ore pretreatment technology, which is applied in the field of manganese ore grade improvement, can solve the problems of unavailable, fine-grained particle size, and poor beneficiation effect of fine-grained manganese ore, and achieve the effect of high quality and cost reduction

Active Publication Date: 2017-02-01
贵州铜仁和诚锰合金有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The embedded particle size is fine, and it has the characteristics of high silicon, high phosphorus, high iron, etc. It is difficult to improve the recovery rate and grade of manganese at the same time by traditional beneficiation methods
At present, the magnetic separation method is mainly used to beneficiate manganese ore, and the general grade is increased by about 2%. With the successful development of various high-performance magnetic separators, the grade and recovery rate have been improved, but the beneficiation effect for fine-grained manganese ore is still poor. , largely caused the loss of manganese minerals
[0003] For the above-mentioned technical problems, those skilled in the art have begun to make relevant researches, such as "A Method for Alkali Leach Desiliconization of Manganese Ore" with the patent No. 201410468891. The removal of manganese ore can achieve the purpose of improving the grade of manganese ore; although this method can improve the quality of manganese ore to a certain extent, the increase in the grade of manganese ore is still not high, especially for the improvement of manganese ore such as manganese carbonate ore. At the same time, when the above process is used for desiliconization treatment, due to other impurities remaining in the manganese ore, which will affect the removal of silicon, there are still certain defects in the removal effect of silicon, and other impurities cannot be obtained. Removal, so that the relative content of manganese in the manganese ore is still low, so that the grade of the manganese ore is relatively poor, and still cannot meet the requirements of fine chemical production of manganese products

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A kind of manganese carbonate pretreatment method, comprises the following steps:

[0023] (1) Put the manganese carbonate ore in a pulverizer to pulverize it, pass it through an 80-mesh sieve, take the bottom material, and place the bottom material in a microwave processor for 3 minutes, then mix the bottom material with nitric acid According to the mass ratio of 1:0.6, the stirring speed is 10r / min, and the temperature is adjusted to 35°C, stirred at a constant temperature for 10min, then placed in an ultrasonic processor, and ultrasonically treated for 10s to obtain a pulp;

[0024] (2) ore pulp is placed in reaction tank, and adds sodium hydroxide solution wherein, the sodium hydroxide solution, the mass percent of sodium hydroxide solution is 1%, and the sodium hydroxide add-on is 0.2 times weight of manganese carbonate ore, and then Put it at a temperature of 80°C, use ultrasonic treatment for 1min, then stir it with a stirring speed of 50r / min for desiliconizatio...

Embodiment 2

[0034] A kind of manganese carbonate pretreatment method, comprises the following steps:

[0035] (1) Put the manganese carbonate ore in a pulverizer to pulverize it, pass it through a 100-mesh sieve, take the sieve bottom material, then place the sieve bottom material in a microwave processor for 5 minutes, and then mix the processed sieve bottom material with nitric acid According to the mass ratio of 1:0.7, the stirring speed is 100r / min, and the temperature is adjusted to 45°C, stirred at a constant temperature for 20min, then placed in an ultrasonic processor, and ultrasonically treated for 30s to obtain a pulp;

[0036] (2) ore pulp is placed in reaction tank, and adds sodium hydroxide solution wherein, the sodium hydroxide solution, the mass percent of sodium hydroxide solution is 30%, and the sodium hydroxide add-on is 0.5 times weight of manganese carbonate ore, and then Put it at a temperature of 120°C, use ultrasonic treatment for 3 minutes, and then use a stirring ...

Embodiment 3

[0046] A kind of manganese carbonate pretreatment method, comprises the following steps:

[0047] (1) Put the manganese carbonate ore in a pulverizer to pulverize it, pass it through a 90-mesh sieve, take the sieve bottom material, then place the sieve bottom material in a microwave processor for 4 minutes, and then mix the processed sieve bottom material with nitric acid According to the mass ratio of 1:0.65, the stirring speed is 50r / min, and the temperature is adjusted to 40°C, stirred at a constant temperature for 15min, then placed in an ultrasonic processor, and ultrasonically treated for 20s to obtain a pulp;

[0048](2) the ore pulp is placed in the reaction tank, and sodium hydroxide solution is added thereto, the sodium hydroxide solution, the mass percentage of the sodium hydroxide solution is 20%, and the sodium hydroxide add-on is 0.3 times of weight of manganese carbonate ore, and then Put it at a temperature of 100°C, use ultrasonic treatment for 2 minutes, then...

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PUM

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Abstract

The invention relates to the technical field of manganese ore grade improving, in particular to a pretreatment method for manganese carbonate ore. As the manganese carbonate ore is treated through the combination of nitric acid, a sodium hydroxide solution and carbon powder, and microwave treatment and ultrasonic treatment in the treatment step and high-temperature treatment in the step 4 are combined, carbon elements in the manganese carbonate ore are removed, and meanwhile the content of oxygen elements in the manganese carbonate ore is reduced. In addition, as two leaching treatment steps through the sodium hydroxide solution are combined, and the carbon powder with the reduction function and the adsorbing function is added when the second leaching treatment step is carried out, the manganese grade of treated manganese carbonate ore concentrates is high and is improved by 3% or more compared with the prior art; and in addition, the silicon removal rate can be 97% or more, so that the quality of the manganese carbonate ore concentrates is high, and the follow manganese ore treatment cost is reduced.

Description

technical field [0001] The invention relates to the technical field of manganese ore grade improvement, in particular to a pretreatment method for manganese carbonate ore. Background technique [0002] With the continuous deepening of my country's industrialization, especially the rapid development of the iron and steel industry, the demand for manganese ore is also increasing. However, my country's manganese ore resources are seriously insufficient. It is of great strategic significance to study how to improve the comprehensive utilization of manganese ore resources. Most of the manganese ore in my country is lean ore, which is divided into two types: manganese oxide ore and rhodochrosite. The embedded particle size is fine, and it has the characteristics of high silicon, high phosphorus, and high iron. It is difficult to improve the recovery rate and grade of manganese at the same time by traditional beneficiation methods. At present, the magnetic separation method is mai...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22B47/00C22B1/00C22B3/12
CPCY02P10/20
Inventor 肖军
Owner 贵州铜仁和诚锰合金有限公司