A method for evaluating the storage life of a lithium-ion battery with a full charge

A lithium-ion battery and charge storage technology, which is applied in the direction of measuring electricity, measuring electrical variables, measuring devices, etc., can solve the problems of long evaluation time, increased storage temperature, low accuracy, etc., and achieve the effect of sufficient life evaluation principle

Active Publication Date: 2017-10-27
NAT UNIV OF DEFENSE TECH
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  • Description
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Problems solved by technology

The rule of thumb is based on experience, and it is proposed that on the basis of meeting certain conditions, the storage temperature of the battery increases by 10°C, and the capacity decay rate of the battery increases by about one time. This method can simply estimate the full charge storage of lithium-ion batteries. However, the reliability of the data is not high, and there are shortcomings such as low accuracy and long evaluation time

Method used

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  • A method for evaluating the storage life of a lithium-ion battery with a full charge
  • A method for evaluating the storage life of a lithium-ion battery with a full charge
  • A method for evaluating the storage life of a lithium-ion battery with a full charge

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Embodiment 1

[0059] like figure 1 As shown, the steps of the lithium-ion battery full charge storage life evaluation method in this embodiment include:

[0060] 1) Determine the experimental conditions and conduct experiments to generate experimental data: determine the storage temperature range according to the lowest storage temperature of the lithium-ion battery to be evaluated and the electrolyte decomposition temperature, and select multiple storage temperature values ​​T according to the preset temperature interval within the storage temperature range, Store the battery sample for evaluating the full charge state of the lithium-ion battery for a specified sampling time t under multiple storage temperature values ​​T, and each sampling time t under each storage temperature value T is used as a sampling point, and each sampling point corresponds to For at least one battery sample, obtain the capacity loss rate Q of the battery sample at each sampling point to generate experimental data...

Embodiment 2

[0107] The basic steps of this embodiment are the same as that of Embodiment 1, and its main difference is:

[0108] In step 1) of this embodiment, in view of the fact that the capacity of the battery in this example decays too quickly at 343K at the initial stage of the experiment, the highest acceleration temperature adopted in this example is 333K, the interval temperature interval is 5K, and four interval temperature intervals are taken, so store Set the temperature as 298K, 318K, 323K, 328K, 333K, and set the sampling time as 15 days, 30 days, 45 days, 60 days, 90 days. At the same time, due to the large difference in the capacity of the single cells of the battery in Example 2, the number of samples was increased to 5, and the final test plan for each sampling point was finally obtained as shown in Table 4. In addition, the capacity of the experimental data was also included in this embodiment. The error ranges of loss rate Q, storage temperature value T, and sampling ti...

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Abstract

The invention discloses a lithium-ion battery full-charge storage life evaluation method, the steps include: storing a battery sample for evaluating the full-charge state of the lithium-ion battery at a plurality of storage temperature values ​​T for a specified sampling time t to obtain a capacity loss rate Q and Generate experimental data; establish a capacity decay aging model, determine the value of model parameter ρ and model parameter a; judge the rationality of the selection of storage temperature range based on whether the model parameter a satisfies the Arrhenius formula at each storage temperature value T; Statistically obtain the mean and standard deviation of the model parameters A and B; substitute the value of the model parameter ρ and the mean of the model parameters A and B into the model to judge the goodness of fit; after the goodness of fit is satisfied, the lithium-ion battery to be evaluated is The lifetime at normal temperature is predicted to obtain the lifetime distribution map. The invention has the advantages of sufficient life evaluation principle, high data reliability and high precision, simple operation, easy realization, short evaluation time and wide application range.

Description

technical field [0001] The invention relates to the storage life evaluation technology of lithium-ion batteries, in particular to a method for evaluating the full-charge storage life of lithium-ion batteries using high-temperature acceleration. Background technique [0002] With the development of society and the advancement of science and technology, lithium-ion batteries have been widely used as a new generation of energy systems. As a power source, lithium-ion batteries have the advantages of high safety and no pollution compared with traditional oil-based power sources, making lithium batteries have great application prospects in vehicle power supplies. At present, pure electric vehicles based on lithium batteries have been successfully produced at home and abroad and have widely sold. [0003] However, the lifespan of lithium-ion batteries is one of the biggest constraints limiting their widespread application. Typically, the end of life of a battery is defined as 80%...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01R31/36
Inventor 郑春满刘勇谢凯盘毅王珲韩喻洪晓斌李德湛李宇杰许静
Owner NAT UNIV OF DEFENSE TECH
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