A New Method for Removing Rare Earth Elements from Spent Fuel

A technology for spent fuel and rare earth, applied in the new field of lanthanum actinium phase all-solid-state separation, can solve the problems of reducing the thermal conductivity of uranium dioxide, a large number of acid leaching high-level waste liquids, etc., to achieve risk reduction, high economic benefits, and high environmental protection sexual effect

Active Publication Date: 2018-05-15
INST OF MODERN PHYSICS CHINESE ACADEMY OF SCI +1
View PDF6 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, the presence of rare earth elements will reduce the thermal conductivity of uranium dioxide
At present, the rare earth elements are generally removed from the spent fuel by acid leaching series liquid-liquid extraction through hydrometallurgical recovery technology, but such a separation process will produce a large amount of acid leaching high-level waste liquid, and it is also necessary to provide strict conditions for Pu conversion. Protective measures

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A New Method for Removing Rare Earth Elements from Spent Fuel
  • A New Method for Removing Rare Earth Elements from Spent Fuel
  • A New Method for Removing Rare Earth Elements from Spent Fuel

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0058] Prepare the double organic phase flotation separation system containing ionic liquid of the present invention:

[0059] Select kerosene as the basic solvent phase of the first organic phase, add 100mg / mL CA-12 and PC-88a (rare earth recognition capture reagent and mixed dispersant, the ratio of the two is 1:10) to the kerosene and mix thoroughly Obtain the first organic phase;

[0060] Will [C n mim][Tf 2 N] (n is 4) and [C n Py][PF 6 ] (n is 4) were thoroughly mixed at a volume ratio of 1:1 (mL:mL) to obtain a second organic phase.

[0061] The first step: 300mg simulated spent fuel (mainly composed of U 3 o 8 , where Nd 2 o 3 The content is 16.83%wt)) into 2mL of the above-mentioned second organic phase, and ultrasonically dispersed, so that the spent fuel is uniformly dispersed in the second organic phase.

[0062] The second step: the second organic phase obtained in the first step is directly mixed with the first organic phase (4mL), or a third phase (such...

Embodiment 2

[0069] Adopt the method identical with embodiment 1, just change kerosene into monounsaturated Omega-9 fatty acid (being called for short oleic acid), the result obtained is substantially the same as that of embodiment 1, specifically see image 3 .

Embodiment 3

[0071] Using the same method of operation as in Example 1, it has been verified that U 3 o 8 All solid state separation of La 2 o 3 Effect. In the first phase, oleic acid or sulfonated kerosene was added with 125 mg / mL of P507 and CA-12, and in the second phase, 1:1 [C 4 mim][Tf 2 N] and [C 4 mim][PF 6 ]. U before separation 3 o 8 Middle La 2 o 3 The content of La 2 o 3 The content of La 2 o 3 content down to 1.95%.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The present invention provides a dual-organic phase flotation separation system containing ionic liquid and a method for removing rare earth elements in spent fuel. The system includes: the first organic phase (also called the upper phase or phase 1), including the following The basic solvent phase of one or more compositions in the above material: multi-chain organic alkanes solvent, organic ester solvent, oleic acid fatty acid solvent and naphthenic acid solvent; ), which is a composite phase of the first type of ionic liquid and the second type of ionic liquid, the first type of ionic liquid is an imidazole ionic liquid, and the second type of ionic liquid is selected from the group consisting of pyridines, pyrroles, piperidines, Quaternary ammonium or its functionalized ionic liquid. The direct all-solid-state separation of rare earth elements from spent fuel can be effectively achieved through a multi-stage serial differential flotation process.

Description

technical field [0001] The invention belongs to the technical field of rare earth separation, in particular to a new method for all solid-state separation of lanthanum actinide phases, which is used for effectively removing neutron poison rare earth elements in spent fuel. Background technique [0002] There are some rare earth elements in spent fuel, such as La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, etc., which are called neutron poisons, because these rare earth elements have large neutron cross-sections and are strong neutralizers. Neutron absorbers contribute significantly (approximately 50%) to the neutron accumulation of spent fuel. In addition, the presence of rare earth elements will reduce the thermal conductivity of uranium dioxide. At present, the rare earth elements are generally removed from spent fuel by acid leaching series liquid-liquid extraction through hydrometallurgical recovery technology, but this separation process will produce a large amount of acid leaching h...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): B03D1/00
Inventor 杨帆范芳丽秦芝
Owner INST OF MODERN PHYSICS CHINESE ACADEMY OF SCI
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap